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91.
Rachid Essehli Brahim El Bali Ingrid Svoboda Hartmut Fuess 《Materials Research Bulletin》2009,44(4):817-2294
The new titanium oxyphosphate Co0.5TiPO5 has been prepared by solid state reaction. Its structure has been determined by single crystal X-ray diffraction and was further investigated by FT-IR spectroscopy and magnetic measurements. The compound crystallizes in the monoclinic system, S.G: P21/c [a = 7.358(1) Å, b = 7.378(2) Å, c = 7.383(3) Å, β = 119.66(3)°, Z = 4, R1 = 0.0142, wR2 = 0.0429]. The structure can be described as a network of very distorted TiO6 octahedra, in which the Ti4+ ions are displaced from the centres of the octahedra, and slightly distorted PO4 tetrahedra. Half of the octahedral cavities are occupied by Co atoms. The other half of octahedral sites is vacant and favourable for the electrochemical insertion of lithium. The insertion of lithium was studied by galvanostatic charging and discharging between different voltage limits. 相似文献
92.
There are various factors that influence yarn strength. Yarn breaking is due to fiber breakages and fiber’s slippages. In reality, a part of the fibers slip while the other part breaks. In this study, we have shown that fatigue yarn, resulting in a fundamental way impact on the number of breaks on the weaving machine, and sometimes on the physical properties of fabrics. Given the importance of the issue and the very limited directed research number in this direction, a tests series were carried out with the aim to highlight the changes to the physical characteristics of the yarn resulting from mechanical treatment comparable to that which they are subjected on the weaving machine. In the first part of our investigation, the residual deformation, tensile strength, and elongation at break of combed and carded threads were measured. In the second part, the influence of the extensions number, their amplitudes, and frequencies were analyzed. In order to examine the influence of these parameters, carded and combed yarns, with different characteristics were prepared. Therefore, based on the separate treatment results of three test series, it appears that: the warp yarns subjected to repeated extensions undergo the phenomenon of fatigue. Yarns fatigue reduces their elasticity and resistance and it is the cause for break yarn during weaving. The fatigue of wool yarns is very low compared to other textile materials. 相似文献
93.
Dongguang Wei James G. GoodwinJr. Rachid Oukaci Alan H. Singleton 《Applied Catalysis A: General》2001,210(1-2):137-150
There exists much current interest in the use of supported Co catalysts and slurry bubble column reactors (SBCR) for the conversion of natural gas to higher hydrocarbons via the Fischer–Tropsch (F–T) synthesis. Catalyst attrition resistance is extremely important in the operation of slurry-phase reactor systems because of potential problems with plugging of system filters and/or contamination of the liquid products. This paper addresses the effects of different supports, promoters, and preparation methods on the attrition resistance of Co F–T catalysts for SBCR use. Loading of Co onto the supports improved the attrition resistances of both alumina and silica significantly. It has essentially no effect on titania. The resulting catalysts had attrition resistances in the order The addition of small amounts of metal (Ru, Cu) and oxide (La, Zr, K, Cr) promoters had mainly small effects on the attrition resistance of the supported Co catalysts. However, it would appear that the addition of Zr to Co/alumina had a negative impact on its attrition resistance. The different preparation methods used in this study (aqueous impregnation, non-aqueous impregnation, and kneading) did not appear to have a significant effect on catalyst attrition resistance. 相似文献
The calcined supports had attrition resistances (inversely related to % fines <11 μm generated during attrition testing) as follows:
−Al2O3>TiO2(rutile)SiO2
Co/Al2O3>Co/SiO2>Co/TiO2(rutile)>Co/TiO2(anatase)
94.
Marusczak N Larose C Dommergue A Paquet S Beaulne JS Maury-Brachet R Lucotte M Nedjai R Ferrari CP 《The Science of the total environment》2011,409(10):1909-1915
Total mercury (THg) and methylmercury (MeHg) concentrations were measured in the muscle of Arctic charr (Salvelinus alpinus) and in the water column of 4 lakes that are located in the French Alps. Watershed characteristics were determined (6 coverage classes) for each lake in order to evaluate the influence of watershed composition on mercury and methylmercury concentrations in fish muscle and in the water column. THg and MeHg concentrations in surface water were relatively low and similar among lakes and watershed characteristics play a major role in determining water column Hg and MeHg levels. THg muscle concentrations for fish with either a standardized length of 220 mm, a standardized age of 5 years or for individualuals did not exceed the 0.5 mg kg− 1 fish consumption advisory limit established for Hg by the World Health Organization (WHO, 1990). These relatively low THg concentrations can be explained by watershed characteristics, which lead to short Hg residence time in the water column, and also by the short trophic chain that is characteristic of mountain lakes. Growth rate did not seem to influence THg concentrations in fish muscles of these lakes and we observed no relationship between fish Hg concentrations and altitude. This study shows that in the French Alps, high altitude lakes have relatively low THg and MeHg concentrations in both the water column and in Arctic charr populations. Therefore, Hg does not appear to present a danger for local populations and the fishermen of these lakes. 相似文献
95.
Silicon - In this work, we emphasis on the Bismuth induced crystallization of hydrogenated amorphous silicon (a-Si) thin films. 50 nm of bismuth thin films are deposited by vapor... 相似文献
96.
We conducted a series of spectral extinction measurements on a variety of aerosolized chemical and biological simulants over the spectral range 3-13 microm using conventional Fourier-transform IR (FTIR) aerosol spectroscopy. Samples consist of both aerosolized particulates and atomized liquids. Materials considered include Bacillus subtilis endospores, lyophilized ovalbumin, polyethylene glycol, dimethicone (SF-96), and three common background materials: kaolin clay (hydrated aluminum silicate), Arizona road dust (primarily SiO2), and diesel soot. Aerosol size distributions and mass density were measured simultaneously with the FTIR spectra. As a result, all optical parameters presented here are mass normalized, i.e., in square meters per gram. In an effort to establish the utility of using Mie theory to predict such parameters, we conducted a series of calculations. For materials in which the complex indices of refraction are known, e.g., silicone oil (SF-96) and kaolin, measured size distributions were convolved with Mie theory and the resultant spectral extinction calculated. Where there was good agreement between measured and calculated extinction spectra, absorption, total scattering, and backscatter were also calculated. 相似文献
97.
Wireless Personal Communications - This paper proposes a new energy management function intended to be integrated in the Hierarchical Smart Routing Protocol (HSRP) mainly proposed for Wireless... 相似文献
98.
Abba Bala Namata Idouhli Rachid Ilagouma Amadou Tidjani Abouelfida Abdesselam Khadiri MohyEddine Romane Abderrahmane 《Protection of Metals and Physical Chemistry of Surfaces》2021,57(3):619-633
Protection of Metals and Physical Chemistry of Surfaces - In the present study, we evaluated the effect of corrosion inhibition of ethanol extracts from Endostemon tereticaulis and Hyptis spicigera... 相似文献
99.
Abderrahim Titi Mouslim Messali Rachid Touzani Mohammed Fettouhi Abdelkader Zarrouk Nabil Al-Zaqri Ali Alsalme Fahad A. Alharthi Amjad Alsyahi Ismail Warad 《International journal of molecular sciences》2020,21(22)
A new double-open-cubane core Cd(II)-O-Cu(II) bimetallic ligand mixed cluster of type [Cl2Cu4Cd2(NNO)6(NN)2(NO3)2].CH3CN was made available in EtOH/CH3CN solution. The 1-hydroxymethyl-3,5-dimethylpyrazole (NNOH) and 3,5-dimethylpyrazole (NNH) act as N,O-polydentate anion ligands in coordinating the Cu(II) and Cd(II) centers. The structure of the cluster in the solid state was proved by XRD study and confirmed in the liquid state by UV-vis analysis. The XRD result supported the construction of two octahedral and one square pyramid geometries types around the four Cu(II) centers and only octahedral geometry around Cd(II) two centers. Interestingly, NNOH ligand acts as a tetra-µ3-oxo and tri-µ2-oxo ligand; meanwhile, the N-N in NNH acts as classical bidentate anion/neutral ligands. The interactions in the lattice were detected experimentally by the XRD-packing result and computed via Hirschfeld surface analysis (HSA). The UV-vis., FT-IR and Energy Dispersive X-ray (EDX), supported the desired double-open cubane cluster composition. The oxidation potential of the desired cluster was evaluated using a 3,5-DTB-catechol 3,5-DTB-quinone as a catecholase model reaction. 相似文献
100.
Dr. Tom Baladi Dr. Nedra Hamouda-Tekaya Dr. Leticia Christina Pires Gonçalves Dr. Stéphane Rocchi Dr. Cyril Ronco Dr. Rachid Benhida 《ChemMedChem》2020,15(13):1113-1117
Sulfonylguanidines are interesting bioactive compounds with a broad range of applications in the treatment of different pathologies. 2-Aminobenzazole-based structures are well employed in the development of new anticancer drugs. Two series of novel N-benzazol-2-yl-N′-sulfonyl guanidine derivatives were synthesized with the sulfonylguanidine in either an extra- or intracyclic frame. They were evaluated for their antiproliferative activity against malignant melanoma tumor cells, thus allowing structure-activity relationships to be defined. Additionally, NCI-60 screening was performed for the best analogue to study its efficiency against a panel of other cancer cell lines. The stability profile of this promising compound was then validated. During the synthetic process, an unexpected new deamidination of the sulfonylguanidine towards sulfonamide function was also identified. 相似文献