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51.
52.
Application of chemometrics in river water classification 总被引:8,自引:0,他引:8
The main aim of this work is focused on water quality classification of the Brda river (Poland) and evaluation of pollution data obtained by the monitoring measurement during the period 1994-2002. The study presents the application of selected chemometric techniques to the pollution monitoring dataset, namely, cluster analysis, principal component analysis, discriminant analysis and factor analysis. The obtained results allowed to determine natural clusters and groups of monitoring locations with similar pollution character and identify important discriminant variables. Chemometric analysis confirmed the classification of water purity of the Brda river made by the Inspection of Environmental Protection but the results showed more differentiation between monitored locations. This enables better evaluation of the water quality in a monitored region. On the basis of the chemometric approach, it was also found that some locations were under the high influence of municipal contamination, and some others under the influence of agriculture (discharges from fields) within the observed time period. 相似文献
53.
Banaszewski Jacek Pabiszczak Maciej Pastusiak Tomasz Buczkowska Agata Kuczko Wiesław Wichniarek Radosław Górski Filip 《Journal of materials science. Materials in medicine》2018,29(2):23
The aim of the study was to compare two types of mandible reconstructive operations with scapula and fibula free flaps: procedures with 3-D models from thermoplastic materials and conventional planning surgeries. 8 patients were treated due to an advanced oral cavity squamous cell carcinoma. In four patients with a mandibular defect, a physical 3-D model consisting of the reconstructed and unaffected sites was prepared for a reconstruction protocol. The 3-D models were designed based to high resolution CT scans. Assessment of comparative functionality (stability of junction, mobility, mastication ability) and cosmetics was examined in both groups, following a 8 weeks healing period with better results in group with 3D model. 3-D models for mandible and donor bones allow to obtain better functionality of restored mandible in comparison to the traditional method also significantly decreases time of the operation and allows to achieve the desired shape and esthetic effect within the 1/3 of the lower face. 相似文献
54.
Jacek Słupski Zofia Lisiewska Piotr Gębczyński Radosława Skoczeń‐Słupska 《International Journal of Food Science & Technology》2011,46(9):1816-1822
The aim of the investigation was to compare oxalate retention in two types of frozen product prepared for consumption after frozen storage: one obtained using the traditional method (blanching‐freezing‐frozen storage‐cooking) and a convenience food involving cooking‐freezing‐frozen storage‐defrosting and heating in microwave oven. The investigation included three species of legume vegetables: immature (wax‐stage maturity) seeds of broad bean and green pea, and French bean. Fresh broad bean seeds contained 53 mg total oxalates in 100 g fresh matter; pea 38 mg; and French bean 88 mg. Soluble oxalates comprised 53, 58 and 72% of total oxalates. The treatments applied resulted in reduction of the level of total and soluble oxalates, and oxalate to calcium ratio (broad bean and French bean); there was no influence on the level of calcium bound as calcium oxalate; true retention of oxalates was lower than apparent retention (green pea and French bean). 相似文献
55.
Derivatives of 1,4‐naphthoquinone as visible‐light‐absorbing one‐component photoinitiators for radical polymerisation 下载免费PDF全文
Bifunctional visible‐light photoinitiators for free radical polymerisation based on a 1,4‐naphthoquinone skeleton were synthesised and characterised using proton nuclear magnetic resonance spectroscopy and chemical ionisation mass spectrometry. Their basic spectroscopic properties, such as absorption and low‐temperature phosphorescence spectra, and their red‐ox properties were also measured. These initiators contain an appropriate electron/hydrogen donor group in the skeleton and do not require an additional coinitiator for initiation. During irradiation they act both as a triplet photosensitiser and as a hydrogen/electron donor. The ability of each naphthoquinone to act as a photoinitiator strongly depends on its chemical structure. These studies suggest that initiator radicals are generated from the triplet state in an intermolecular electron/hydrogen transfer reaction. 相似文献
56.
57.
Rados?aw Swad?ba Marek Hetmańczyk Maria Sozańska Bartosz Witala Lucjan Swad?ba 《Surface & coatings technology》2011,206(7):1538
The coatings were prepared by the means of Pt and Pt/Pd galvanizing, followed by vapor phase aluminizing at 1050 °C. Microstructural and phase analysis revealed that all the investigated coatings consisted mainly of β-NiAl phase, however the Pt-modified aluminide coating also contained PtAl2 phase and pure platinum precipitates. The cross-sectional microstructure of the coatings was zonal and composed of β-NiAl phase zone and the diffusion zone. The Pt modified aluminide coating's cross-section also incorporated an outermost zone consisting of β-NiAl and PtAl2 phases. The concentration profiles proved that both Pt and Pd contents decrease gradually inwards the modified coatings. Cyclic oxidation tests at 1100 °C proved that Pt/Pd-modified aluminide coatings exhibit the best performance under cyclic conditions. The analysis of oxidation kinetics curves showed that the course of simple aluminide coating's oxidation is slightly different from that of Pt- and Pt/Pd-modified aluminide coatings. 相似文献
58.
An effective remediation method of DDT-contaminated soil was developed. The preliminary results of investigations on a laboratory scale were exploited to scale up the technology into pilot scale. The approach for soil remediation was based on the utilization of hydroxyl radicals that were generated from water aerosol and ozone in a fluidized bed reactor. During the remediation procedure the level of soil contamination was reduced by 80%. The procedure was successfully scaled up; no degradation products were detected and the total organic carbon was preserved. 相似文献
59.
Agnieszka Rudek Rados?aw Rudek 《The International Journal of Advanced Manufacturing Technology》2012,62(1-4):135-145
In this paper, we focus on real-life settings that require the development of new models of flowshop scheduling problems, where job processing times can increase with the number of processed jobs due to the aging effect and decrease by the allocation of additional resource. We analyse the makespan minimization flowshop problem with such model and also with the aging effect only. We prove that the considered problems and their special cases are still polynomially solvable under given conditions, and on their basis, we provide optimal polynomial time solution algorithms. 相似文献
60.
Joanna Pisarska Izabela Czopek Radosław Lisiecki Witold Ryba-Romanowski Tomasz Goryczka Wojciech A. Pisarski 《Ceramics International》2013,39(8):9151-9156
Lead borate glasses were prepared and then heat treated in order to obtain transparent glass-ceramics. Controlled crystallization of precursor lead borate glass at appropriate annealing temperature and time led to formation of the PbWO4 crystallites. The observed broad blue emission band is related to the PbWO4 crystallites. The influence of PbX2 content (X=F, Cl, Br), PbF2 concentration and lanthanide doping (Eu, Dy) on the excitation and emission spectra of lead borate glass-ceramics containing PbWO4 phase was examined. The relationship between Pb–X bond and spectral line width of the blue emission can be successfully observed, when halogen X ions (X=F, Cl or Br) are also present in the distorted PbWO4 crystallites. 相似文献