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31.
The simultaneous heat and moisture transfer in the building envelope has an important influence on the indoor environment and the overall performance of buildings. In this paper, a model for predicting whole building heat and moisture transfer was presented. Both heat and moisture transfer in the building envelope and indoor air were simultaneously considered; their interactions were modeled. The coupled model takes into account most of the main hygrothermal effects in buildings. The coupled system model was implemented in MATLAB-Simulink, and validated by using a series of published testing tools. The new program was applied to investigate the moisture transfer effect on indoor air humidity and building energy consumption under different climates. The results show that the use of more detailed simulation routines can result in improvements to the building's design for energy optimisation through the choice of proper hygroscopic materials, which would not be indicated by simpler calculation techniques.  相似文献   
32.
    
Biodiesel remains one of the most promising alternatives to replace fossil fuel-derived petrodiesel. Nonetheless, conventional biodiesel synthesis relies on homogeneous alkali-based catalysts that involve long and tedious purification steps , increasing biodiesel production costs. Heterogeneous catalysts have emerged as promising alternatives to circumvent these drawbacks, as they can easily be recovered and reused. Herein, polymeric carbon nitride dots and nanosheets are synthesized through a solid-phase reaction between urea and sodium citrate. Their morphology and surface chemistry are tuned by varying the precursor's ratio, and the materials are investigated as catalysts in the transesterification reaction of canola oil to biodiesel. A conversion of > 98% is achieved using a 5 wt% catalyst loading, oil to methanol ratio of 1:36 at 90 °C for 4 h, with the performance maintained over at least five reuse cycles. In addition, the effect of the transesterification reaction parameters on the reaction kinetics is evaluated, which follows a pseudo-first-order (PFO) regime. Combined with a deep understanding of the catalyst's surface, these results have allowed us to propose a reaction mechanism similar to the one observed for homogenous alkali catalysts. These carbon nitride-based nanoparticles offer a metal-free and cost-effective alternative to conventional homogeneous and metal-based heterogeneous catalysts.  相似文献   
33.
    
The transfer‐free direct growth of high‐performance materials and devices can enable transformative new technologies. Here, room‐temperature field‐effect hole mobilities as high as 707 cm2 V?1 s?1 are reported, achieved using transfer‐free, low‐temperature (≤120 °C) direct growth of helical tellurium (Te) nanostructure devices on SiO2/Si. The Te nanostructures exhibit significantly higher device performance than other low‐temperature grown semiconductors, and it is demonstrated that through careful control of the growth process, high‐performance Te can be grown on other technologically relevant substrates including flexible plastics like polyethylene terephthalate and graphene in addition to amorphous oxides like SiO2/Si and HfO2. The morphology of the Te films can be tailored by the growth temperature, and different carrier scattering mechanisms are identified for films with different morphologies. The transfer‐free direct growth of high‐mobility Te devices can enable major technological breakthroughs, as the low‐temperature growth and fabrication is compatible with the severe thermal budget constraints of emerging applications. For example, vertical integration of novel devices atop a silicon complementary metal oxide semiconductor platform (thermal budget <450 °C) has been theoretically shown to provide a 10× systems level performance improvement, while flexible and wearable electronics (thermal budget <200 °C) can revolutionize defense and medical applications.  相似文献   
34.
The effects of germination, cooking and roasting on the phytic acid content, total phosphorus, water soluble inorganic phosphorus and mineral content of fenugreek seeds have been estimated. After 96 h germination, the dry weight of fenugreek seeds decreased while total ash content increased. Phytase and phosphatase activity of the ungerminated and germinated seeds have been assayed. It is observed that during germination the phytic acid values diminish and the water soluble inorganic phosphorus values increase. Phytase activity which is absent in the ungerminated seeds originates after germination and the phosphatase activity is increased in the germinated seeds. Heat treatment practised in cooking and roasting fenugreek seeds has less effect on phytate elimination than does germination. Changes in calcium, magnesium, iron, manganese, copper and zinc are found to be dependent on the loss of dry weight which occurs during processing of fenugreek seeds.  相似文献   
35.
Okra fruits, Taro tubers, Jew's mellow leaves and Fenugreek seeds are commonly used in Egypt to prepare popular diets with desired slimy consistency.The mucilages were extracted and preliminary studies conducted to characterise them physically. The pH values of a 1% solution of the mucilages varied from 6·9-7·5 for Okra and Taro, 7·1–7·8 for Jew's mellow, and 5·9-6 for Fenugreek, depending upon extraction conditions. The highest viscosity was observed in Okra solutions, followed by Fenugreek, Jew's mellow and Taro mucilages. Okra and Jew's mellow mucilages are acidic polysaccharides which contain higher amounts of ash than the Taro and Fenugreek mucilages which are neutral polysaccharides. All mucilages are associated with protein. Gel chromatography indicated strong interaction of protein with the polysaccharide. The acid hydrolysis of the mucilages followed by paper chromatography revealed that all mucilages contain methyl pentose, glucose, galactose, and fructose, in different proportions. Taro and Fenugreek mucilages are free of rhamnose. All mucilages are devoid of arabinose and mannose except Fenugreek which contained these two sugars.  相似文献   
36.
High levels of humidity in buildings lead to building pathologies. Moisture also has an impact on the indoor air quality and the hygrothermal comfort of the building’s occupants. To better assess these pathologies, it is necessary to take into account the heat and moisture transfer between the building envelope and its indoor ambience. In this work, a new methodology was developed to predict the overall behavior of buildings, which combines two simulation tools: COMSOL Multiphysics© and TRNSYS. The first software is used for the modeling of heat, air and moisture transfer in multilayer porous walls (HAM model: Heat, Air and Moisture transfer), and the second is used to simulate the hygrothermal behavior of the building (BES model: Building Energy Simulation). The combined software applications dynamically solve the mass and energy conservation equations of the two physical models. The HAM-BES coupling efficiency was verified. In this paper, the use of a coupled (HAM-BES) co-simulation for the prediction of the hygrothermal behavior of building envelopes is discussed. Furthermore, the effect of the 2D HAM modeling on relative humidity variations within the building ambience is shown. The results confirm the importance of the HAM modeling in the envelope on the hygrothermal behavior and energy demand of buildings.  相似文献   
37.
The objective of this paper is to describe moisture transfer through porous material due to temperature gradient. For that purpose, an experimental device was set up to assess moisture flux under isothermal and non-isothermal conditions. This involves placing samples between two compartments with controlled air conditions and monitoring relative humidity and temperature profiles inside the samples over the time. To interpret these results, we proposed to express the mass flux in terms of two driving potentials: water vapor content gradient and temperature gradient. Accordingly, thermogradient coefficient was calculated and discussed. It represents the difference between the moisture fluxes under isothermal and non-isothermal conditions. The impact of temperature gradient on the moisture buffer value (MBV) was also considered through a numerical experiment taking into account thermogradient coefficient. Results show that temperature gradient implies a relative variation of the MBV for about 14%. Thus, it would be better to consider non-isothermal conditions for its assessment.  相似文献   
38.
The use of water droplet evaporation in shower towers and passive downdraft evaporative cooling needs the estimation of the time needed to completely evaporate the drops. To solve this problem, a cellular approach is proposed in which the spray is considered as a pile of rigid spheres of equal size; each sphere has multiple layers and contains a drop in its center. The evaporation takes place gradually from the superficial layer towards the internal layers. Parametric studies show the influence of each variable on the evaporation time of the droplets. The model may be used for sizing passive evaporative cooling systems and towers for buildings using the passive evaporative down draught effect. A building equipped with a shower tower has been tested in the framework of the European project PDEC/JOULE in Catania (Italy). The spraying system was successfully sized by using the model proposed in this paper.  相似文献   
39.
40.
Extracts of mature green, dry and germinated Vicia faba beans depressed the trypsin activity of casein. Germination of Vicia faba beans (for 60 h) lowered the trypsin inhibitor (TI) activity. 0.171M Saline was the most efficient extractant for the TI. Minimal amounts of the TI were extracted in the pH range 4 to 5. The TI of Vicia faba beans was undialysable. The inhibitor activity originated in the seeds at the beginning of pod formation and increased with development of maturity. TI was active only towards trypsin and inactive towards papain, rennin and pepsin. Chromatographing Vicia faba bean proteins, possessing antitryptic activity, on a column of DEAE-cellulose yielded six peaks, all of which possessed antitryptic activity.  相似文献   
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