Single string planning problem arising in liner shipping industries: A heuristic approach

We propose an efficient heuristic approach for solving instances of the Single String Planning Problem (SSPP) arising in the liner shipping industry. In the SSPP a Liner Service Provider (LSP) only revises one of its many operational strings, and it is assumed that the other strings are unchangeable. A string is a service route composed of a sequence of port calls—a call is a visit to a port followed by loading/unloading operations made by a vessel. In a string the vessel's round trip terminates at the same port that it started from, and the port calls follow a published itinerary. The SSPP is regularly encountered by all LSPs, and a major part of their seasonal network planning process is devoted to repeatedly solving SSPP for different regions using experts' knowledge. Despite the practical importance of the problem, very little has been written about it in the literature. A revision is carried out in the form of a controlled re-sequencing, insertion and elimination of ports from along the current string, given a set of ports limited to those that exist on the string and a set of potential ones. The outcome determines the required capacity, service level (frequency), call sequence, etc., corresponding to the LSP's seasonal strategy. Exact decomposition methods are limited and can solve only very small size instances—small in terms of the number of ports, vessel classes, vessel number and commodities. In contrast, the proposed heuristic method is an efficient approach for obtaining high quality and practical solutions to real-size instances in significantly less computational time.     

Effect of particle morphology on mechanical properties of liquid marbles

In order to better understand the influence of the shape of solid particles on the stability of liquid marbles, we investigated liquid marbles stabilized by hydrophobized calcium carbonate particles with spherical and rod-shaped morphologies. Static properties, such as the effective surface tension, and the dynamic behavior i.e. the compression-decompression features for several cycles of the liquid marbles were investigated. Liquid marbles stabilized with spherical CaCO₃ particles show an elastic response to mechanical deformation almost up to collapse. In contrast, liquid marbles prepared with rod-like particles exhibit a more plastic response to compression. It is concluded that the main differences in behavior of the prepared liquid marbles arise from how the solid particles can arrange/orient at the air/water interface.     

A Review of Thermal Conductivity Models for Nanofluids

Nanofluids, as new heat transfer fluids, are at the center of attention of researchers, while their measured thermal conductivities are more than for conventional heat transfer fluids. Unfortunately, conventional theoretical and empirical models cannot explain the enhancement of the thermal conductivity of nanofluids. Therefore, it is important to understand the fundamental mechanisms as well as the important parameters that influence the heat transfer in nanofluids. Nanofluids’ thermal conductivity enhancement consists of four major mechanisms: Brownian motion of the nanoparticle, nanolayer, clustering, and the nature of heat transport in the nanoparticles. Important factors that affect the thermal conductivity modeling of nanofluids are particle volume fraction, temperature, particles size, pH, and the size and property of nanolayer. In this paper, each mechanism is explained and proposed models are critically reviewed. It is concluded that there is a lack of a reliable hybrid model that includes all mechanisms and influenced parameters for thermal conductivity of nanofluids. Furthermore, more work needs to be conducted on the nature of heat transfer in nanofluids. A reliable database and experimental data are also needed on the properties of nanoparticles.     

Experimental study on natural ventilation performance of one-sided wind catcher

Hydrodynamic performance of a one-sided wind catcher was investigated by experimental wind tunnel and smoke visualization testing. Wind catchers or what is called Baud-Geers in Persian language was a main component of buildings in central region of Iran and the neighboring countries. A Baud-Geer is a tower used to capture wind from external air stream and induce it into the building in order to provide natural ventilation and passive cooling. Due to geographical coordinates of the region, wind power and the direction of blowing wind, wind catchers are employed in different heights, cross sections of the air passages and the places and the number of the openings. The one-sided wind catcher has only one channel as a passage of induced air and is often related to the areas where there is prevailing wind. These Baud-Geers are employed to catch the wind blowing at higher elevations and direct it to the building, causing it to leave through windows, doors or other exhausted segments. In this study a 1:40 scale model of Kharmani's School Baud-Geer was employed and the induced air flow rate into the test room and the pressure coefficients around all surfaces of its channel were measured for different values of approaching air incident angles. Using measured pressure coefficients, the theoretical values of ventilation air flow were estimated to evaluate ability of simplified models in natural ventilation studies. Due to placing of urban full-scale wind catchers in the boundary layer of atmospheric winds, the effect of this phenomenon was also examined. The experiments were conducted when the wind catcher model with adjoining house was placed in the wake of upstream objects, resembling neighboring buildings. It was found that for an isolated wind catcher model, the maximum efficiency is achieved at zero air incident angle. Also it was concluded that the angle of incidence of the wind, the presence of an upstream building around the structure and blowing of atmospheric wind influence the pressure coefficients, the rate and the direction of ventilation air flow.     

Interference of Saturated Fats in the Determination of Low Levels of <Emphasis Type="Italic">trans</Emphasis> Fats (below 0.5%) by Infrared Spectroscopy

The mandate to label food products with the content of total trans fatty acids has led to an increase in demand for sensitive and accurate methodologies for the rapid quantitation of trans fats. Unfortunately, the latest official infrared (IR) spectroscopic method lacks the required sensitivity. A more sensitive IR procedure that requires the measurement of the height of the second derivative (2D) of the trans absorption band at 966 cm⁻¹ was recently proposed; however, a reported inconsistency at low trans levels between GC (0% of total fat) and IR (1.2% of total fat) results for a fully hydrogenated vegetable oil could not be reconciled, and triggered further investigations. For the first time, we recognize and report the presence of weak interference bands (962–956 cm⁻¹) attributed to saturated fats in the IR spectra of trans fats; these interference bands have an adverse impact on the sensitivity and accuracy of the IR determination at low trans levels (≤0.5% of total fat). Therefore, weak spectral features observed at energies below the one expected for trans bands (966 cm⁻¹) in test samples high in saturated fat (coconut oil and cocoa butter) must not be mistaken for trans bands.     

Fabrication of g-C3N4/Au nanocomposite using laser ablation and its application as an effective catalyst in the reduction of organic pollutants in water

Gold nanoparticles (Au NPs) were fabricated by laser ablation in liquid (LAL) as a green method and decorated on graphitic carbon nitride (g-C₃N₄) by a facile ultrasonication method. g-C₃N₄ was prepared via urea pyrolysis. The prepared g-C₃N₄/Au (denoted as CN/Au) nanocomposite was characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM) and energy dispersive X-ray spectrometry (EDS). The synthesized CN/Au nanocomposite was applied as an efficient catalyst in the reduction of 4-nitrophenol (4-NP) and methyl orange (MO) using NaBH₄ at room temperature. The recyclability of CN/Au catalyst was examined.     

Simulation of Shiraz solar power plant for optimal assessment

Design of a solar power plant consists of two cycles, oil and steam is simulated to study its control philosophy and thermal performance, using an entropy generation minimization method. Plant highest thermal cycle efficiency is determined for mean day of each month during a year and new operating conditions are proposed.     

Fourier Transform Near Infrared Spectroscopy: A Newly Developed,Non-Invasive Method To Measure Body Fat

An FT-NIR technique is reported to provide a fast, accurate and low cost method of determining in-vivo human body fat content. The body fat content of 353 healthy subjects (154 males and 199 females) of various height, weight, and age were measured by FT-NIR and compared to 420 subjects investigated by magnetic resonance imaging (MRI). The procedure involved scanning each subject's upper ear that provided a necessary reflectance surface and proved representative of the subject's subcutaneous fat content. The average FT-NIR spectrum was compared to a reference mixture with known and similar fat content and composition to that of humans. The FT-NIR response was incorporated into an empirical equation using the ratio of subcutaneous to total body fat from MRI data, taking into account the subject's gender, height, weight and age. The results on the two data sets were similar and demonstrated that the FT-NIR technique can be used to obtain a measure of the body fat content of individuals, similar to that using MRI. In addition, the FT-NIR was used to more accurately monitor the fat content of sleep apnea patients.     

Clarifications of the Carbonyl and Water Absorptions in Fourier Transform Near Infrared Spectra from Extra Virgin Olive Oil

The Fourier transform near infrared (FT-NIR) spectrum of extra virgin olive oils (EVOO) shows two minor carbonyl absorptions at 5280 and 5180 cm^–1 that has been used to assess their authenticity. To establish components absorbing at 5280 cm^–1, volatile aldehydes and ketones, triacylglycerol (TAG), diacylglycerols (DAG), free fatty acids (FFA), phenolics, and water are investigated and sometimes added to refined olive oil (ROO). Except TAG, the remaining carbonyls contribute to 5280 cm^–1 by broadening peak. Water absorption is demonstrated by its removal using Na₂SO₄ or deuterium oxide addition; FT-NIR spectral changes are reconstituted by water addition. Water absorption depends on being free or complexed with polar compounds in oil. The size of absorption is not related to abundance, but on unique absorption specificity of components; water shows the strongest absorption. Heat removes water and volatiles, leaving behind DAG, FFA, and phenolics, and makes it possible to differentiate absorption of water, volatile and non-volatile carbonyls. Cloudy olive oils are analyzed using FT-NIR methodology after warming for 3 min at 50 °C. FT-NIR index values are replaced by a new calibration model based on correlating gravimetric mass loss of water plus volatiles with spectral changes. The FT-NIR methodology is expanded to include EVOOs with 15.5% to 21% linoleic acid. Practical Applications: Testing for authenticity of EVOOs remains a challenge because adulterations continue to be a problem due to economic gains. Spectroscopy methods, specifically FT-NIR, are much preferred to targeted chemical methods because they measure all constituents in products and are non-destructive and fast. The current universal FT-NIR methodology assesses 13 different parameters: five major FAs, and the DAG and FFA contents. The FT-NIR index value measuring the content of moisture plus volatiles is now replaced by a gravimetric determination. The methodology identifies four major types of adulterants, high in oleic acid, linoleic acid, palm olein or ROO. The composition of olive oils makes it necessary to develop five oil-specific groups, but cloudy samples still need to be clarified by slight warming before measuring. The value of this universal FT-NIR methodology will increase after being adopted by commercial and in regulatory settings.