The preparation of thiophenes. I. From C4-molecules and carbon disulphide

Thiophene has been prepared by passing C₄-molecules and carbon disulphide in the vapour phase, over a promoted chromium-aluminium oxide catalyst. A 42 and 78% yield of thiophene were obtained from the reaction of n-butanol or crotonaldehyde with carbon disulphide, respectively. A possible scheme for these reactions has been proposed. In addition a number of catalysts for the reaction between n-butanol and carbon disulphide has been used and their efficiency determined. A number of substituted thiophenes was also obtained from the reaction between n-butanol and carbon disulphide; their yields and structures were determined.     

Geometrically nonlinear analysis of rectangular mindlin plates using the finite strip method

A general finite strip method of analysis is presented for the geometrically nonlinear analysis of laterally loaded, rectangular, isotropic plates. The analysis is based on the use of Mindlin plate theory and therefore includes the effects of transverse shear deformation. The nonlinearity is introduced via the strain-displacement equations and correspondingly the analysis pertains to problems involving moderate displacements but small rotations. The principle of minimum potential energy is used in the development of the strip and the complete plate stiffness equations and the latter equations are solved using the Newton-Raphson method. In numerical applications a particular type of finite strip is used in which all five reference quantities (three displacements and two rotations) are represented by cubic polynomial interpolation across the strip whilst the ends of the strip are simply supported for bending/shearing behaviour and immovable for membrane behaviour. These applications are concerned with uniformly loaded plates of both thin and moderately-thick geometry and detailed presentation is given of both displacement- and force-type quantities.     

Analysis of Temperature Distribution in Cast-resin Dry-type Transformers

Non-flammable characteristic of dry-type cast- resin transformers make them suitable for residential and hospital usages. However, because of resin’s property, thermal behavior of these transformers is undesirable, so it is important to analyze their thermal behavior. Temperature distribution of cast-resin transformers is mathematically modeled in this paper. The solution of the model was carried out successfully by finite difference method. In order to validate the model, the simulation results were compared with the experimental data measured from an 800 kVA transformer. Finally, the influences of some construction parameters and environmental conditions on temperature distribution of cast-resin transformers were discussed.     

The use of biodegradable polymers for the stabilization of copper nanoparticles synthesized by chemical reduction method

Copper nanoparticles were synthesized by a convenient and rapid chemical reduction method in ambient condition using \(\hbox {Cu}(\hbox {NO}_{3})_{2}{\cdot } 3\hbox {H}_{2}\hbox {O}\) as a precursor, hydrazine hydrate as reducing agent and deionized water as solvent. The product was characterized by X-ray diffraction (XRD) patterns, field emission scanning electron microscopy, Fourier transform infrared spectroscopy and UV–Vis spectroscopy. However, agglomerated copper nanoparticles were obtained by this chemical reduction method. Hence, the effects of three polymers of polyvinyl pyrrolidone, polyethylene glycol (PEG) and starch as stabilizers on the size and size distribution of Cu nanoparticles were investigated. According to the results, smallest copper nanoparticles (30–50 nm) with a narrow size distribution were obtained using PEG as the stabilizing polymer. Zero-valent copper nanoparticles with high purity were obtained by this method and there was no peak related to the oxidized impurities such as CuO and \(\hbox {Cu}_{2}\hbox {O}\) in the XRD and UV–Vis studies, both in the presence and in the absence of stabilizer. On the other hand, by this method, zero-valent copper nanoparticles were obtained in the absence of any anti-oxidant agent and any inert gas flow. The effects of synthesis parameters including initial concentration of precursor, polymer concentration and the reaction temperature on the size and size distribution of copper nanoparticles were investigated using the UV–Vis analysis to determine the optimum synthesis conditions.     

Clarifications of the Carbonyl and Water Absorptions in Fourier Transform Near Infrared Spectra from Extra Virgin Olive Oil

The Fourier transform near infrared (FT-NIR) spectrum of extra virgin olive oils (EVOO) shows two minor carbonyl absorptions at 5280 and 5180 cm^–1 that has been used to assess their authenticity. To establish components absorbing at 5280 cm^–1, volatile aldehydes and ketones, triacylglycerol (TAG), diacylglycerols (DAG), free fatty acids (FFA), phenolics, and water are investigated and sometimes added to refined olive oil (ROO). Except TAG, the remaining carbonyls contribute to 5280 cm^–1 by broadening peak. Water absorption is demonstrated by its removal using Na₂SO₄ or deuterium oxide addition; FT-NIR spectral changes are reconstituted by water addition. Water absorption depends on being free or complexed with polar compounds in oil. The size of absorption is not related to abundance, but on unique absorption specificity of components; water shows the strongest absorption. Heat removes water and volatiles, leaving behind DAG, FFA, and phenolics, and makes it possible to differentiate absorption of water, volatile and non-volatile carbonyls. Cloudy olive oils are analyzed using FT-NIR methodology after warming for 3 min at 50 °C. FT-NIR index values are replaced by a new calibration model based on correlating gravimetric mass loss of water plus volatiles with spectral changes. The FT-NIR methodology is expanded to include EVOOs with 15.5% to 21% linoleic acid. Practical Applications: Testing for authenticity of EVOOs remains a challenge because adulterations continue to be a problem due to economic gains. Spectroscopy methods, specifically FT-NIR, are much preferred to targeted chemical methods because they measure all constituents in products and are non-destructive and fast. The current universal FT-NIR methodology assesses 13 different parameters: five major FAs, and the DAG and FFA contents. The FT-NIR index value measuring the content of moisture plus volatiles is now replaced by a gravimetric determination. The methodology identifies four major types of adulterants, high in oleic acid, linoleic acid, palm olein or ROO. The composition of olive oils makes it necessary to develop five oil-specific groups, but cloudy samples still need to be clarified by slight warming before measuring. The value of this universal FT-NIR methodology will increase after being adopted by commercial and in regulatory settings.     

Rapid FT-NIR Analysis of Edible Oils for Total SFA, MUFA, PUFA, and Trans FA with Comparison to GC

Declarations of the total content of trans fatty acids (FA) and saturated FA (SFA) are mandatory on food labels in the US and Canada. Gas chromatography (GC) has been the method of choice for the determination of FA composition. However, GC is time consuming and requires conversion of fats and oils to their FA methyl esters. In the present study, a recently published Fourier transform near-infrared (FT-NIR) spectroscopic procedure was applied to the rapid (<5 min) determination of total SFA, monounsaturated FA (MUFA), polyunsaturated FA (PUFA), and trans FA contents of 30 commercially available edible fats and oils. Good agreement was obtained between the GC and FT-NIR methods for the determination of total SFA, MUFA, and PUFA contents. Differences between the two methods were apparent for the determination of trans fat at trans fat levels <2 % of total fat. The analytical determinations of total SFA, MUFA, and PUFA contents for many of the oils examined differed from the respective values declared on the product labels. Our findings demonstrate that the FT-NIR procedure serves as a suitable alternative method for the rapid determination of total SFA, MUFA, PUFA and trans FA contents of neat vegetable oils.     

Preparation and corrosion resistance of nanostructured PVC/ZnO–polyaniline hybrid coating

ZnO–polyaniline nanocomposite with core–shell nanostructure was prepared by in situ polymerization of aniline monomer in the presence of ZnO nanoparticles. Fourier transform infrared spectroscopy, X-ray diffraction patterns, field emission scanning electron microscopy and transmission electron microscopy techniques were used to characterize the composition and structure of ZnO–polyaniline nanocomposite. d.c. electrical conductivity measurement showed that the electrical conductivity of ZnO–polyaniline nanocomposite pellets is higher than that of pristine polyaniline and ZnO nanoparticles pellets. The addition of ZnO nanoparticles causes to the increasing of polyaniline electrical conductivity. ZnO–polyaniline nanocomposite was mixed with polyvinyl chloride (PVC) through a solution mixing method and the three components PVC/ZnO–polyaniline hybrid material was applied as coating on iron coupon by the solution casting method. Corrosion protection efficiency of PVC/ZnO–polyaniline hybrid coating on iron coupons was studied by open circuit potential and Tafel techniques in 3.5% NaCl solution as corrosive environment. According to the results, PVC/ZnO–polyaniline hybrid nanocomposite coating showed dramatically increased corrosion protection effect on iron samples compared to that of uncoated iron coupon and pure polyaniline anticorrosive coating. It was found that ZnO nanoparticles improve the barrier and electrochemical anticorrosive properties of polyaniline and the addition of polyvinyl chloride increases the barrier effect of polyaniline coating.     

A novel controlling method for the superconducting magnetic energy storage system as a distributed generation source; full modelling,design and simulation

In this article, a novel controlling method applied on the superconducting magnetic energy storage (SMES) system, as a distributed generation source, has been proposed. The structure comprises an SMES coil, a three-level bi-directional chopper, a three-level inverter, fuzzy logic-based controlling units, and appropriate interfacing filter and circuitry components. The system can operate both in connected and disconnected cases. In the former, power exchange occurs between the distributed generation source and the power grid; and in the latter, the system will supply the local load independently. Hence, active and reactive power in the connected case, and load voltage in the disconnected case are controlled by three individual fuzzy logic-based controllers. Effectiveness and efficiency of the proposed structure have been verified by a series of relevant simulations.