Blends of poly(2-hydroxyethyl methacrylate)/ (styrene-co-dialkyl itaconates) and poly(N-vinyl-2-pyrrolidone)/(styrene-co-dialkyl itaconates)

Summary Blends containing poly(N-vinyl-2-pyrrolidone) (PVP) and poly(hydroxyethyl methacrylate) (PHEMA) with (styrene-co-dimethyl itaconate) (Sty-co-DMI) and (styrene-co-diethylitaconate) (Sty-co-DEI) copolymers of three different compositions were studied. One Tg value over the whole range of compositions is observed for the majority of the blends, what is indicative of compatibility. The Gordon-Taylor k_GT and the Couchman k_C parameters were determined for all the blends in order to compare the strength of the interactions. The effect of the side chain structure of the copolymer on the miscibility of these blends is analyzed.     

Thermal Stress Analysis in Particulate Composite Components

Abstract: Thermal stresses resulting from flow of hot and cold water were obtained in sinks manufactured with acrylic casting dispersions by both experimental and numerical analysis. The experimental work was performed in two poly(methyl methacrylate) (PMMA) -silica based particulate composites, compositions of which are different by the volume fraction of filler and the particle size. The thermal stresses in sinks were obtained using strain gauges. The alternate flow of cold and hot water using a mixed tap, results in the formation of thermal gradients, leading to the occurrence of thermal stresses . The experimental results were compared with the numerical results obtained with a commercial finite element software. For this analysis, some thermal parameters such as the convective heat transfer coefficient, the density, the thermal conductivity and the specific heat were experimentally obtained. In general, a good agreement between experimental and numerical results was observed. The results of this study, together with the results of fatigue and fracture tests, will be used in a tolerance analysis of defects in the products manufactured with these composites.     

Addition of cashew tree gum to maltodextrin-based carriers for spray drying of cashew apple juice

This study involved an attempt to totally or partially replace maltodextrin DE10 (MD10) by cashew tree gum (CTG) as a drying aid agent in spray drying of cashew apple juice. The objective was to evaluate the impact of drying aid/cashew apple juice dry weight ratio (D/C, ranging from 3 to 5) and degree of replacement of MD10 with CTG (CTG_R, ranging from 0% to 100%) on ascorbic acid retention (AAR), hygroscopicity, flowability and water solubility of spray dried cashew apple juice powder. AAR was increased from 72.90% to 95.46% by increasing D/C from 3 to 5. CTG was shown as a promising maltodextrin replacer, being more effective than the latter to decrease powder hygroscopicity. The most adequate drying conditions (D/C = 5, CTG_R≥50%) resulted in more than 90% of AAR, and produced a powder with good flowing properties and water solubility.     

Solution properties of poly(thiocarbonates)

Poly(thiocarbonates) with alkyl side chains have been prepared, and the solution properties of these polymers were studied in different solvents. Comparison with other poly(thiocarbonate) analogues and poly(carbonates) shows that the conformational parameter (K_θ) and rigidity factor increase as the volume of the side chain increases. The effect of the side-chain structure on the solution properties is analyzed.     

Polymer cosolvent system

Summary The preferential adsorption parameter of poly(phenyl methacrylate), poly[4-(1,1,3,3- tetramethylbutyl) phenyl methacrylate] and poly(4-tert-butyl styrene) in the mixture THF/water has been determined by exclusion chromatography (GPC) and differential refractometry and dialysis equilibrium (DR). The general behaviour of the polymers studied in this mixture is very similar, water is preferentially adsorbed by the polymer at low water content. The results are discussed in relation to the rigidity of the macromolecular chains and the hydrophobic degree of the substituent group in the aromatic ring.     

Miscibility of poly(2,6-dimethyl-1,4-phenylene oxide)/poly(vinyl pyrrolidone) blends

The miscibility of blends of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and poly(vinylpyrrolidone) (PVP) was studied by differential scanning calorimetry (DSC) through the analysis of the glass transition temperature Tg. The dependence of Tg with the annealing temperature was determined for PPO and PVP samples of different molecular weights. The phase diagrams for blends containing three different PVP samples were established. Blends of PPO and PVP were found to be miscible for composition lower than 30% and higher than 65% of PVP. A inmiscibility window between 30 and 65% of PVP is also described.     

Megalanthine,a Bioactive Sesquiterpenoid from <Emphasis Type="Italic">Heliotropium megalanthum</Emphasis>, its Degradation Products and their Bioactivities

The new bioactive sesquiterpenoid (3R,6E)-2,6,10-trimethyl-3-(3-p-hydroxyphenylpropanoyloxy)-dodeca-6,11-diene-2,10-diol, named megalanthine, was isolated from the resinous exudates of Heliotropium megalanthum. The degradation products of this compound were identified. Several plant-defensive properties (insecticidal, antifungal, and phytotoxic) were evaluated after obtaining positive results in a preliminary etiolated wheat coleoptile bioassay. This bioassay showed the need to have both the phenolic and sesquiterpene moieties of the natural product present to achieve a biological effect. This result was confirmed in phytotoxicity bioassays. Megalanthine was ruled out as a significant plant–plant defense agent because of its lack of stability. The positive results recorded in the antifungal and antifeedant tests suggest, however, that this chemical is relevant in several ecological interactions involving H. megalanthum.     

A time Petri net-based method for embedded hard real-time software synthesis

Over the last few years, embedded software synthesis has drawn much attention. However, few works deal with software synthesis for hard real-time systems considering arbitrary inter-tasks precedence and exclusion relations. Code generation for meeting all timing and resource constraints is not a trivial task. Thus, this research area has several open issues, mainly related to generation of predictable-guaranteed scheduled code. The method proposed in this paper starts from a high-level specification, and automatically translates such specification into a time Petri net model; this model is adopted for finding a feasible static schedule meeting all constraints. If found, the approach generates a scheduled code, based on the found feasible schedule. Therefore, the user just enter the specification and receives, as result, the scheduled code. Thus, all intermediary phases are hidden from the users.     

Compact Bioinspired Antenna for WLAN 5 GHz Application

Wireless Personal Communications - This paper presents the development of a compact monopole antenna bioinspired in the Opuntia ficus-indica plant-shape, generated by Gielis formula, built in...