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21.
Junpeng Xue Zhongkai Yu Hyeon Mi Noh Jung Hyun Jeong Byung Chun Choi Sung Heum Park Bo Ram Lee Peng Du Mingjun Song 《Journal of the American Ceramic Society》2021,104(10):5086-5098
Ce3+/Tb3+ co-doped NaMgBO3 phosphors were successfully synthesized by solid-state method. Under 381 nm excitation, the cyan emission owing to the 5d → 4f of Ce3+ ions and green emissions arising from the 5D4 → 7FJ (J = 6, 5, 4, and 3) transitions of Tb3+ ions were seen in all the phosphors. Through theoretical analysis, one knows that the energy transfer from Ce3+ to Tb3+ ions with high efficiency of 83.74% was contributed by dipole–dipole transition. Furthermore, the internal quantum efficiency of NaMgBO3:0.01Ce3+,0.03Tb3+ phosphor was 54.28%. Compared with that of at 303 K, the emission intensity of the developed products at 423 K still kept 73%, revealing the splendid thermal stability of the studied phosphors. Through utilizing the resultant phosphors as cyan-green components, the fabricated white-LED device exhibited an excellent correlated color temperature of 2785 K, high color-rendering index of 85.73, suitable luminance efficiency of 25.00 lm/W, and appropriate color coordinate of (0.4279, 0.3617). Aside from the superior photoluminescence, the synthesized phosphors also exhibited excellent cathode-luminescence properties which were sensitive to the current and accelerating voltage. Furthermore, the NaMgBO3:0.01Ce3+,0.03Tb3+ phosphors with multi-mode emissions were promising candidates for optical anti-counterfeiting. All the results indicated that the Ce3+/Tb3+ co-doped NaMgBO3 phosphors were potential multi-platforms toward white-LED, field emission displays, and optical anti-counterfeiting applications. 相似文献
22.
Miguel Gallardo-Cervantes Yolanda González-García Aida Alejandra Pérez-Fonseca Martín Esteban González-López Ricardo Manríquez-González Denis Rodrigue Jorge Ramón Robledo-Ortíz 《应用聚合物科学杂志》2021,138(15):50182
In this work, biocomposites made of polyhydroxyalkanoates (PHA) with natural fibers were produced via compression molding. In particular, polyhydroxybutyrate (PHB) and polyhydroxybutyrate-co-hydroxyvalerate (PHBV) were reinforced with 20 wt% of agave fibers. Different compatibilization strategies were investigated to improve the fiber-matrix interaction: fiber surface treatment in PHA solution, fiber surface treatment in maleated PHA solution, fiber propionylation, and extrusion with maleated PHA. The biocomposites were characterized in terms of morphology, mechanical properties, water absorption, and biodegradability by CO2 production tracking. In general, fiber propionylation was the best strategy for mechanical properties enhancement and water uptake decreasing. Biocomposites with propionylated fibers showed improved flexural strength (170% for PHB and 84% for PHBV). The flexural modulus was also enhanced with propionylated fibers up to 19% and 18% compared to uncompatibilized biocomposites (PHB and PHBV, respectively). Tensile strength increased by 16% (PHB) and 14% (PHBV), and the water absorption was reduced using propionylated fibers going from 6.6% to 4.4% compared with biocomposites with untreated fibers. Most importantly, the impact strength was also improved for all biocomposites by up to 96% compared with the neat PHA matrices. Finally, it was found that the compatibilization did not negatively modify the PHA biodegradability. 相似文献
23.
Clark A. Updike M.S. Ram B. Bhagat Ph.D. Martin J. Pechersky Ph.D. Maurice F. Amateau Ph.D. 《JOM Journal of the Minerals, Metals and Materials Society》1990,42(3):42-46
Metal-matrix composites may offer better damping properties than unreinforced alloys. Because damping properties (and metal-matrix composites) are becoming important in airframe design, the damping capabilities of a number of aluminum-matrix composites were measured over a wide range of frequencies at low strain amplitudes, using a new laser vibrometer technique. Silicon carbide and alumina reinforcements resulted in a material with damping properties similar to that of unreinforced aluminum 6061-T6, but unidirectional and planar-random graphite continuous-fiber reinforcements increased the damping by 5 and 14 times, respectively. The increased damping of the continuous fiber composites is attributed to the absence of interfacial reaction resulting from the high-pressure infiltration method used for their manufacture. 相似文献
24.
José Hernández-Orallo Cèsar Ferri Nicolas Lachiche Adolfo Martínez-Usó M. José Ramírez-Quintana 《Data mining and knowledge discovery》2016,30(4):848-890
Some supervised tasks are presented with a numerical output but decisions have to be made in a discrete, binarised, way, according to a particular cutoff. This binarised regression task is a very common situation that requires its own analysis, different from regression and classification—and ordinal regression. We first investigate the application cases in terms of the information about the distribution and range of the cutoffs and distinguish six possible scenarios, some of which are more common than others. Next, we study two basic approaches: the retraining approach, which discretises the training set whenever the cutoff is available and learns a new classifier from it, and the reframing approach, which learns a regression model and sets the cutoff when this is available during deployment. In order to assess the binarised regression task, we introduce context plots featuring error against cutoff. Two special cases are of interest, the \( UCE \) and \( OCE \) curves, showing that the area under the former is the mean absolute error and the latter is a new metric that is in between a ranking measure and a residual-based measure. A comprehensive evaluation of the retraining and reframing approaches is performed using a repository of binarised regression problems created on purpose, concluding that no method is clearly better than the other, except when the size of the training data is small. 相似文献
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26.
The effect of alkaline pretreatment of waste-activated sludge, using two models to study the sequential hydrolysis rates of suspended (Sanders' surface model) and dissolved (Goel's saturation model) solids, on the mesophilic and thermophilic anaerobic digestion rate is evaluated. The pretreatment, which reduces the size of the solids, increases the reaction rate by increasing the surface area and the specific surface hydrolysis constant (K(SBK)); at thermophilic conditions from 0.45 x 10(-3) kg m(-2) d(-1) for the fresh sludge to 0.74 x 10(-3) kg m(-2) d(-1) for the pretreated sludge and at mesophilic conditions these values are 0.28 x 10(-3) kg m(-2) d(-1) and 0.47 x 10(-3) kg m(-2) d(-1) confirming the usefulness of a pretreatment for solids reduction. But for soluble solids, the thermoalkaline pretreatment decreases the reaction rates by inducing a competitive inhibition on the thermophilic anaerobic digestion rate while in the mesophilic range, a non-competitive inhibition is observed. A mathematical simulation of the consecutive reactions, suspended solids to dissolved solids and to methane in staged anaerobic thermophilic-mesophilic digestion, shows that with 4% suspended solids concentration it is better not to use a thermoalkaline pretreatment because overall solids reduction and total methane production are not as good as without pretreatment. 相似文献
27.
Roberto R. Expósito Guillermo L. Taboada Sabela Ramos Juan Touriño Ramón Doallo 《Personal and Ubiquitous Computing》2013,17(8):1709-1719
Cloud computing is posing several challenges, such as security, fault tolerance, access interface singularity, and network constraints, both in terms of latency and bandwidth. In this scenario, the performance of communications depends both on the network fabric and its efficient support in virtualized environments, which ultimately determines the overall system performance. To solve the current network constraints in cloud services, their providers are deploying high-speed networks, such as 10 Gigabit Ethernet. This paper presents an evaluation of high-performance computing message-passing middleware on a cloud computing infrastructure, Amazon EC2 cluster compute instances, equipped with 10 Gigabit Ethernet. The analysis of the experimental results, confronted with a similar testbed, has shown the significant impact that virtualized environments still have on communication performance, which demands more efficient communication middleware support to get over the current cloud network limitations. 相似文献
28.
Nanocrystalline gamma iron oxide (γ-Fe2O3) has been synthesized at room temperature through sonication-assisted precipitation technique. The key in obtaining γ-Fe2O3 at room temperature lies in exploiting high-power ultrasound (600 W). The gas-sensing properties to n-butane of pure γ-Fe2O3 were investigated by studying the electrical properties of the sensor elements fabricated from the synthesized powder. The maximum response (90%) of the sensor to 1000 ppm n-butane at 300 °C can be explained on the basis of catalytic activity of the nanocrystallites. The response and recovery time of the sensor to 1000 ppm n-butane were less than 12 s and 120 s, respectively. 相似文献
29.
M. Adam Khan N. Ram Prasad S. Navaneetha Krishnan S. Karthic Raja J. T. Winowlin Jappes Muthukannan Duraiselvam 《Materials and Manufacturing Processes》2017,32(14):1635-1641
The recent research in biocompatible materials has been useful in replacing and supporting the fractured natural human bones/joints. Under some condition, negative reaction like release of ions from the bare metal toward the human body fluid leads to corrosion. In this proposed research paper, the biocompatibility of the laser surface-modified austenitic stainless steel (SS316L) and nickel-based superalloy (Inconel 718) was studied. The investigation on laser-modified surfaces is evaluated through electrochemical polarization analysis using simulated body fluid (SBF). The samples subjected to electrochemical polarization analysis were characterized by optical image analysis, SEM, EDS, and XRD analysis. It was inferred that laser surface-modified materials provided enhanced corrosion resistance and bare nickel alloy is more susceptible to corrosion by SBF. 相似文献
30.