Synthesis of molybdenum carbide nanoparticles using pulsed wire discharge in mixed atmosphere of kerosene and argon

Pulsed wire discharge was used to prepare nanoparticles of molybdenum and its carbides from Mo wires in a gas mixture of argon and kerosene at pressures of 100, 50, and 25 kPa. The different pressures affected the carburization process and particle formation. The most effective pressure was 25 kPa, where the volume fraction of MoC was identified by Rietveld refinement of X-ray diffraction data to be 98.4%. The particle size distribution was also obtained from transmission electron microscopy measurements, and the smallest geometric mean diameter was determined tobe 24.3 nm for the sample prepared at 25 kPa.     

Gas holdup and overall volumetric mass transfer coefficient in a modified reversed flow jet loop reactor

Experiments were conducted in a modified reversed flow jet loop reactor having the liquid outlet at the top of the reactor to determine the gas holdup and overall volumetric mass transfer coefficient in the air-water system. The influence of gas and liquid flow rates, and the draft tube to reactor diameter ratio were studied. It was observed that both gas holdup and volumetric mass transfer coefficient increased with increased gas and liquid flow rates and were found to be significantly higher in the modified reactor compared to the conventional one. The optimum draft tube to reactor diameter ratio was found to be in the range of 0.4 to 0.5. Empirical correlations are presented to predict gas holdup and overall volumetric mass transfer coefficient in terms of operational and geometrical variables.     

Photoinduced anisotropy measurements in liquid-crystalline azobenzene side-chain polyesters

Reversible photoinduced anisotropy in a series of liquid-crystalline azobenzene side-chain polyesters is investigated as a function of intensity of the write beam and the sample temperature. Measurements reveal that the erasing takes place at a temperature much higher than the glass transition temperature. Induced anisotropy can be erased by heating the polyesters to approximately 80 °C.     

A unified framework for optimizing locality, parallelism, andcommunication in out-of-core computations

This paper presents a unified framework that optimizes out-of-core programs by exploiting locality and parallelism, and reducing communication overhead. For out-of-core problems where the data set sizes far exceed the size of the available in-core memory, it is particularly important to exploit the memory hierarchy by optimizing the I/O accesses. We present algorithms that consider both iteration space (loop) and data space (file layout) transformations in a unified framework. We show that the performance of an out-of-core loop nest containing references to out-of-core arrays can be improved by using a suitable combination of file layout choices and loop restructuring transformations. Our approach considers array references one-by-one and attempts to optimize each reference for parallelism and locality. When there are references for which parallelism optimizations do not work, communication is vectorized so that data transfer can be performed before the innermost loop. Results from hand-compiles on IBM SP-2 and Inter Paragon distributed-memory message-passing architectures show that this approach reduces the execution times and improves the overall speedups. In addition, we extend the base algorithm to work with file layout constraints and show how it is useful for optimizing programs that consist of multiple loop nests     

Machinability studies on Al 7075/BN/Al2O3 squeeze cast hybrid nanocomposite under different machining environments

Enforcement of stricter environmental policies demands alternative methods that could reduce the usage of cutting fluid during machining. Thus, dry machining and minimum quantity lubrication (MQL) machining are gaining practical importance. Due to enhanced mechanical and thermal properties, aluminium based nanocomposites have wide application in aerospace and automobile industries. In this work, asqueeze cast hybrid nanocomposite is developed with the reinforcement of 0.5?wt% hexagonal boron nitride and 1?wt% alumina particles in the base matrix of Al 7075 that is subjected to a squeezing pressure of 150?MPa. During the turning of this hybrid nanocomposite, thefeed rate is varied (0.1, 0.2, and 0.3?mm/rev)and its influence on the generated forces, tool wear and surface roughness under dry and MQL environments is performed. The results are compared with squeeze cast unreinforced aluminium alloy and presented.     

A High-Throughput Distributed Shared-Buffer NoC Router

Microarchitectural configurations of buffers in routers have a significant impact on the overall performance of an on-chip network (NoC). This buffering can be at the inputs or the outputs of a router, corresponding to an input-buffered router (IBR) or an output-buffered router (OBR). OBRs are attractive because they have higher throughput and lower queuing delays under high loads than IBRs. However, a direct implementation of OBRs requires a router speedup equal to the number of ports, making such a design prohibitive given the aggressive clocking and power budgets of most NoC applications. In this letter, we propose a new router design that aims to emulate an OBR practically based on a distributed shared-buffer (DSB) router architecture. We introduce innovations to address the unique constraints of NoCs, including efficient pipelining and novel flow control. Our DSB design can achieve significantly higher bandwidth at saturation, with an improvement of up to 20% when compared to a state-of-the-art pipelined IBR with the same amount of buffering, and our proposed microarchitecture can achieve up to 94% of the ideal saturation throughput.     

Suppression of Red Luminescence in Wire Explosion Derived Eu:ZnO

Europium oxide (Eu₂O₃) is coated on zinc (Zn) wire using the electrophoretic deposition process. The coated Zn wire is subjected to the wire explosion process (WEP) which is rapid (< 15 min), and chimie douce (soft chemical, low temperature), in nature; this results in the formation of Eu doped ZnO. The explosion chamber contains oxygen (99.9%) at atmospheric pressure. Electron micrographs indicate that the particle sizes are ～ 80 nm. Diffractogram-based analysis suggests that the crystallite size is ~ 18–20 nm in the as-prepared doped ZnO nanoparticles. Electron paramagnetic resonance shows the presence of Zn vacancies and the cryo-photoluminescence spectrum indicates that Eu exists in the + 3 state. A combined Williamson–Hall plot and Kisielowski’s model based analysis indicates that Eu is a substitutional dopant in WEP derived Eu:ZnO particles. It is estimated that this material has ～ 0.24 at.% doping. This analysis also shows that, unlike another popular material GaN, in the case of ZnO, Eu³⁺ strictly substitutes for Zn²⁺ (i.e., dopant replacing a cation–anion pair does not seem possible). It may be noted that Eu³⁺ in a suitable host is oftentimes reported to be an efficient luminophore. The IR spectra show a band shift from 486 cm^?1 to 493 cm^?1; with peak shifts from 436 cm^?1 to 430 cm^?1 in Raman spectra. These too indicate the presence of Eu in the samples. However, at room temperature, only green luminescence (centered at 534 nm) is observed from the sample indicating (1) high concentrations of O_Zn anti-site defects and Zn vacancies, and (2) concomitant quenching of the luminescence at room temperature. Our results suggest that WEP is viable for synthesizing rare earth doped ceramic materials. However, obtaining efficient phosphors using this approach will likely require, (1) reduction of defect densities, and (2) appropriate passivation using post-processing.     

Rapid synthesis of nanocrystalline YAG via microwave‐assisted solvothermal process

A rapid synthesis procedure for the preparation of nanocrystalline yttrium aluminium garnet (nYAG) particles has been developed, for the first time, using the combination of subcritical conditions and microwave irradiation. It is believed that the use of butanediol delayed the onset of pressure rise due to its low partial pressure, while the microwaves facilitated a selective crystallization of nanocrystalline YAG particles in the solvent medium. This methodology was found to encourage rapid bulk nucleation with minimal particle growth or agglomeration of nYAG particles. The resultant powder characteristics, examined using XRD and TEM analyses, revealed that a narrow window of pressure and temperature conditions needed to be maintained to achieve spherical particles in the size range 60‐80 nm without any intermediate phases being formed. The STEM/EDX and FTIR results obtained suggested that the nucleated YAG particles were masked by carbon clouds until they were completely crystallized into single phase YAG particles; this allowed them to be dispersed in water with little agglomeration.