Distributed light delivery and detection via single optical fiber and tilted grating

A passive fiber-optic-based device is designed and analyzed, capable of delivering and detecting light separately or simultaneously at discrete points of interest along the optical axis of a fiber. This goal is achieved by implementation of multiple finite-length tilted gratings inside the core of a single-mode fiber. Each grating is tuned to function as a leaky electromagnetic resonator that resonates at particular wavelength and partially radiates the optical power to the medium surrounding the fiber. First, the basic element of such radiators is theoretically analyzed and a sequence of justifiable approximations are presented to measure the characteristic parameters of the system. Next, a set of equations are developed to provide a logical procedure for the design. This device has several potential applications in the field of fiber optic sensors. Few practical examples of such applications, particularly for optical stimulation of cells and fluorescence signal recording in sensitive tissues including the brain, are studied.     

Numerical modeling of non-Fourier heat transfer and fluid flow during plasma arc welding of AISI 304 stainless steel

ABSTRACT

This paper is an attempt to study the evolution of temperature profiles and weld pool geometry during plasma arc welding (PAW) by solving the transient Navier–Stokes and Energy equations. The analysis for an AISI 304 stainless steel rectangular plate was carried out using a flexible written program in Fortran. Due to the low accuracy of the Fourier heat transfer equation for short times and large dimensions, a non-Fourier form of heat transfer equation was used. Gaussian heat source is considered as the heat source model. The fluid flow in the molten pool is of interest because it can change the temperature distribution in and around the molten zone. The governing equations for fluid flow were solved by the finite-volume method in which the SIMPLE method was utilized for pressure–velocity coupling. The effects of heat conduction, fluid flow, and force actions at the weld pool were considered. Thermo-physical properties such as thermal conductivity, specific heat, and dynamic viscosity vary as a function of temperature. There are two mechanisms involved which actively cause heat transfer to the surroundings: radiation and convection heat transfer. The numerical results are compared to the experimental data. The results corroborate that the weld pool thickness in the cross section of PAW and the time taken by molten metal to reach the end of thick metal are in good agreement with the experimental measurements. Finally, the results obtained from the assumed Fourier heat transfer are compared for the same study.     

Modeling of mass transfer and thermal cracking during the coking of Athabasca residues

The kinetics of thermal cracking of films of vacuum residue from Athabasca bitumen in the temperature range of was modelled with liquid-phase mass transfer, reaction-dependent fluid properties, and coke formation by reaction of cracked products in the liquid phase. Previous investigations on the thermal cracking of vacuum residue in thin films showed that at low film thickness the coke yield was insensitive to the temperature and heating rate for thin films of bitumen. The coke yield increased with the thickness of the initial film, in the range from 20 to . At the same time, the viscosity of the reacting liquid increased rapidly with time, which would slow down the diffusion of products inside the film. This coupling of transport and reaction would enhance the formation of coke by increasing the rate of recombination reactions. The concept of intrinsic coke is used in a new kinetic model to account for the minimum observed coke formation in thin films. With increasing film thickness, the increasing yield of extrinsic coke is modelled through the change in fluid properties as a function of extent of reaction, which reduces the rate of diffusion in the reacting liquid phase. The model was able to properly account for the insensitivity of coke yield in thin films to reaction temperature and the dependence of coke yield on the thickness of the liquid film.     

Linear and nonlinear vibration analysis of sandwich cylindrical shell with constrained viscoelastic core layer

Damping characteristics of three-layered sandwich cylindrical shell for thin and thick core viscoelastic layers are studied using semi-analytical finite element method. The finite element method is developed based on the linear and nonlinear variations of the displacement distribution through the thickness of the core layer. Transient vibration has been conducted using the developed linear and nonlinear models and shown that the nonlinear formulation exhibits more damping property than the linear model. The effect of geometric nonlinearity due to the large deformation of the shell has also been considered assuming small strain and moderate rotation. Different assumptions based on the continuity and discontinuity in transverse shear stresses and slope of in-plane displacements are considered in the finite element formulation and their effects have been investigated. Considering nonlinearity of eigenvalue problem due to the frequency dependent property of viscoelastic material, an efficient algorithm has been developed to find the natural frequencies and loss factors of the viscoelastic cylindrical shell considering large deformation. The effect of imperfect bonding between the layers has also been investigated in the modeling and it is shown that slippage between layers at the interfaces leads to reduction in loss factor at the majority of modes.     

Effect of chlorine ion concentration on morphology and optical properties of Cl-doped ZnO nanostructures

Effect of Cl^?1 concentration on morphology and optical properties of Cl-doped ZnO nanostructures was studied. The Cl-doped ZnO nanostructures and undoped ZnO microstructures were grown on Si(1 1 1) substrates using a physical vapor deposition method. The ZnO nanostructures have been doped with different concentrations of chlorine. The Cl-doped ZnO nanostructures with 6% atom Cl, showed a nanodisk morphology with a hexagonal shape, while the Cl-doped ZnO nanostructures with 9% atom Cl, exhibited a stacked nanoplate morphology with smaller thickness in comparison to the Cl-doped ZnO nanodisks. In addition, with increasing Cl content to 13%, morphology of the products changed to more stacked nanoplates with nanoflakes morphology. X-ray diffraction results clearly showed a hexagonal structure for the all samples. Raman spectroscopy results showed a strong crystalline quality for the undoped ZnO microdisks and Cl-doped ZnO nanodisks; while these results indicated a weak crystalline quality for the Cl-doped ZnO nanoplates and nanoflakes. Photoluminescence (PL) studies also confirmed the Raman results and it exhibited a lower optical property for the Cl-doped ZnO nanoplates and nanoflakes in comparison to the undoped ZnO microdisks and Cl-doped ZnO nanodisks. Furthermore, the UV peak of the Cl-doped ZnO nanostructures was blue-shifted with respect to that of the undoped ZnO.     

Ultralow-voltage field-ionization discharge on whiskered silicon nanowires for gas-sensing applications

Several hundred million volts per centimetre of electric-field strength are required to field-ionize gas species. Such fields are produced on sharp metallic tips under a bias of a few kilovolts. Here, we show that field ionization is possible at dramatically lower fields on semiconductor nanomaterials containing surface states, particularly with metal-catalysed whiskers grown on silicon nanowires. The low-voltage field-ionization phenomena observed here cannot be explained solely on the basis of the large field-amplification effect of suspended gold nanoparticles present on the whisker tips. We postulate that field penetration causes upward band-bending at the surface of exposed silicon containing surface states in the vicinity of the catalyst. Band-bending enables the valence electron to tunnel into the surface states at reduced fields. This work provides a basis for development of low-voltage ionization sensors. Although demonstrated on silicon, low-voltage field ionization can be detected on any sharp semiconductor tip containing proper surface states.     

Effect of annealing process on the growth and surface properties of Au–ZnO nanowire films grown by chemical routes

Au–ZnO nanowire films have been synthesized by chemical routes, electrochemical deposition (ECD) and chemical bath deposition (CBD) techniques, on zinc foil followed by annealing in air at 400 °C. X-ray diffraction patterns reveal formation of the ZnO wurtzite structure along with binary phases Au₃Zn and AuZn₃. Scanning electron microscopy shows the presence of ZnO nanowires having several micrometers in length and less than 120 nm in diameter synthesized by ECD and in the range of 70–400 nm using the CBD technique. During the annealing process, different surface morphologies originating from different catalytic effects of Au atoms/layers were observed. In addition, the effect of synthesis routes on crystalline quality and optical properties were studied by Raman and photoluminescence spectrometers indicating varying concentration of defects on the films. The Raman results indicate that Au–ZnO nanowire film prepared by chemical bath deposition route had better crystalline quality.     

Growth and optical properties of ZnO–In2O3 heterostructure nanowires

ZnO–In₂O₃ heterostructure nanowires were grown on a Si (111) substrate using the thermal evaporation method. Scanning electron microscopy results showed that the ZnO nanowires had spherical caps. The X-ray diffraction (XRD) pattern and energy-dispersive X-ray (EDX) spectrum indicated that these caps were In₂O₃. An analysis of the early growth process revealed that indium oxide might have played a self-catalytic role. Therefore, it was plausible that the vapor–liquid–solid mechanism (VLS) was responsible for the growth of the ZnO–In₂O₃ heterostructure nanowires. The optical properties of the products were characterized using a photoluminescence (PL) technique. The PL results for the ZnO–In₂O₃ heterostructure nanowires showed a strong peak in the ultraviolet region as a result of the near band emission and a negligible peak for the visible emissions that occurred as a result of the defects. Based on these PL results, it was found that the In₂O₃ nanostructures not only introduced the caps at the tips of the ZnO nanowires but also partially passivated the nanowire surfaces, leading to an improved near band edge emission and the suppression of the defect luminescence.     

Structural modeling of petroleum fractions based on mixture viscosity and Watson K factor

Two procedures have been developed for structural modeling of petroleum fractions based on mixture viscosity and Watson K factor. The representative molecules of paraffinic, naphthenic and aromatic hydrocarbons, based upon Ruzicka’s structural model, have been determined for lube-oil cut SAE 10 from Tehran oil refinery. Unlike previous methods, the newly developed procedures do not require time-consuming and costly laboratory data such as true boiling point profile. Good agreement between predictions of the new models and experimental results has been observed. Moreover, the proposed methods take less run-time than previous models due to less experimental and computational complexities. The results indicate that Ruzicka’s procedure, based on vapor pressure, is only applicable for light hydrocarbon mixtures, while the new methods can be applied for structural modeling of a wide range of petroleum fractions. Furthermore, as a result of this study, the application of a vapor pressure constraint leads to a higher degree of accuracy than the earlier suggested constraint, partial pressure, by Ruzicka.