Structures and Images of Novel Derivatives of Carbon Nanotubes, Fullerenes and Related New Carbon Forms

In the light of the finding that carbon nanotubes get functionalized on reaction with acid and other oxidizing agents, the structures and shapes of nanotube derivatives resulting from possible reaction between functionalized nanotubes, are obtained by an energy minimization procedure and the structures, so obtained, are compared with the observed microscopic images. The shapes of fullerene -like and nanotupe - like structures containing seven - membered rings, in addition to six and five - membered rings, are depicted along with the structures of bent nanotubes containing similar ring systems. Diamond - graphite hybrid structures which constitute an important class of carbon materials are also investigated.     

Influence of scattering and two-photon absorption on the optical loss in GaAs-Al/sub 2/O/sub 3/ nonlinear waveguides measured using femtosecond pulses

The influence of scattering and two-photon absorption on the optical loss in GaAs-Al/sub 2/O/sub 3/ semiconductor nonlinear waveguides has been studied using femtosecond pulses. By deploying a scattering technique, loss coefficients were evaluated over an extended wavelength range of 1.3-2.1 /spl mu/m in the near-infrared. A systematic study involving intensity and wavelength dependence of the loss revealed the presence of two-photon absorption for wavelengths below 1.6 /spl mu/m. A simple nonlinear transmission study enabled the separation of the two-photon absorption coefficient from scattering and linear absorption. The calculated two-photon absorption coefficients were /spl sim/9-20 cm/GW.     

Fatty Acid Composition of Newer Seed Oils

In the course of our search for new sources of oil, fatty acid compositions of the seed oils of 18 species belonging to three families are reported. Five species from Sterculiaceae, one species from Cucurbitaceae and twelve species from Sapindaceae were analysed. Linoleic acid predominated (43.4–76.2%) in the component fatty acids of all the oils followed by oleic (9.7–23.3%) and palmitic (8.4–14.7%) acids.     

Comprehensive microstructural characterization in modified 9Cr-1Mo ferritic steel by ultrasonic measurements

Modified 9Cr-1Mo ferritic steel (T91/P91) has been subjected to a series of heat treatments consisting of soaking for 5 minutes at the selected temperatures, starting from the α-phase region (1073 K) to the γ + δ-phase region (1623 K), followed by oil quenching. Hardness measurements, microstructural features, and grain-size measurements by the linear-intercept method have been used for correlating them with the ultrasonic parameters. Ultrasonic velocity and attenuation measurements, and spectral analysis of the first backwall echo have been used for characterization of the microstructures obtained by various heat treatments. As the soaking temperature increased above Ac ₁, the ultrasonic velocity decreased because of the increase in the volume fraction of martensite in the structure. There were sharp changes in the ultrasonic velocities corresponding to the two critical temperatures, Ac ₁ and Ac ₃. Ultrasonic longitudinal- and shear-wave velocities were found to be useful in identifying the Ac ₁ and Ac ₃ temperatures and for the determination of hardness in the intercritical region. However, ultrasonic attenuation and spectral analysis of the first backwall echo were found to be useful to characterize the variation in the prior-austenitic grain size and formation of δ ferrite above the Ac ₄ temperature. The scattering coefficients have been experimentally determined for various microstructures and compared with the theoretically calculated value of the scattering coefficients for iron reported in literature.     

Analysis of arbitrarily shaped microstrip patch antennas using the Sommerfeld formulation

Triangular patch modeling is used for analysis of arbitrarily shaped microstrip patch antennas over a single lossy dielectric medium. Since the Sommerfeld formulation is used, both the single dielectric layer (over which the microstrip patch is located) and the ground plane are considered to be infinitely wide. Typical numerical results are presented for rectangular, circular, semicircular, pentagonal, and triangular patch antennas. © 1992 John Wiley & Sons, Inc.     

Damage and its growth in laminated composite circular/rectangular plates undergoing large deformations

A nonlinear finite element static analysis is used to predict the damage in rectangular/circular plates due to large deformation simulating low-velocity impact. The impact due to the ball impactor is modelled by an equivalent static load and load distribution is taken according to Hertzian law. Tsai-Wu criterion is used to predict the failure of each ply at Gauss points. The failure mode (fibre breakage or matrix cracking) is identified using maximum stress criterion. The material properties at each failed Gauss point is degraded appropriately and the stress analysis is carried out again. This iterative process is repeated until no further damage condition occurs. Numerical examples for both circular and rectangular composite plates are presented.     

Probabilistic fracture mechanics by Galerkin meshless methods – part II: reliability analysis

 This is the second in a series of two papers generated from a study on probabilistic meshless analysis of cracks. In this paper, a stochastic meshless method is presented for probabilistic fracture-mechanics analysis of linear-elastic cracked structures. The method involves an element-free Galerkin method for calculating fracture response characteristics; statistical models of uncertainties in load, material properties, and crack geometry; and the first-order reliability method for predicting probabilistic fracture response and reliability of cracked structures. The sensitivity of fracture parameters with respect to crack size, required for probabilistic analysis, is calculated using a virtual crack extension technique described in the companion paper [1]. Numerical examples based on mode-I and mixed-mode problems are presented to illustrate the proposed method. The results show that the predicted probability of fracture initiation based on the proposed formulation of the sensitivity of fracture parameter is accurate in comparison with the Monte Carlo simulation results. Since all gradients are calculated analytically, reliability analysis of cracks can be performed efficiently using meshless methods. Received 20 February 2001 / Accepted 19 December 2001     

Cystoscopic staging of carcinoma uterine cervix, revisited

Of the 378 cases of stage 3 carcinoma uterine cervix, only 10 showed vesical invasion, while 19 of 24 cases of stage 4 disease had vesical invasion. Results of this procedure did not alter the management of the disease in any of these cases. From the whole series it was concluded that cysto-urethroscopy is an unnecessary, cost ineffective, invasive procedure which has no role in either diagnosis or in planning the definitive treatment of carcinoma uterine cervix.     

原位红外光谱法研究聚碳酸酯的热稳定性和分解机理

采用原位红外光谱法研究PC的热稳定性。实验表明:同为光气法制备的PC,G—1比G—2热分解温度高;同为酯交换法生产PC,Z-1比Z-2热分解温度高。PC在升温过程中,首先断裂的是酯基中醚键,在较高温度,发生异丙基断裂,400℃后,主链才断裂。