常压等离子射流表面改性超高模量聚乙烯纤维

利用常压等离子射流(APPJ)方法对超高模量聚乙烯(UHMPE)纤维进行表面改性处理。研究了处理前后UHMPE纤维的力学性能、表面形貌、化学成分、表面粘结性能的变化。结果表明,常压等离子射流处理后,UHMPE纤维的强度未发生显著变化,纤维表面粗糙度增加,表面氧元素的含量增加,表面极性基团增加,纤维与环氧树脂之间的粘结性能得到显著的改善。     

建设化学与环境精品课程

从我国高等教育实情出发,北京工业大学把基础化学和环境科学的主要内容紧密结合,融会贯通,整合优化为化学与环境这样一门新兴的学科交叉课程.在工科普通化学和环境保护相关课程的改革与建设方面,特色鲜明.我院在课程体系与内容、配套教材、教学方法、教学手段和师资队伍等诸多方面,积极进取,精心建设.2001年以来曾多次获学校和北京市教学成果奖,2004年被评为北京市精品课程.     

无机化学教学中的"指导——探究"模式

本文报道了无机化学的教学改革与实践.论述了"指导--探究"教学模式的实施与效果.对比实验表明:该模式在化学原理教学中的效果比在元素化学教学中的好,并对无机化学教学时数提出了修改意见.     

炼油厂固体废物填埋场的工程设计

介绍某固体废物填埋场工程设计,确定关键的设计参数,验证给定的各种经验式的相互关系和固体废物的处理方法。     

玄武岩长丝/涤纶交织物阻燃性能测试与研究

为系统地了解和应用阻燃性能较好的玄武岩长丝/涤纶交织物,对玄武岩纤维的结构、性能与应用情况进行简要介绍,设计研发3种织物组织的玄武岩长丝/涤纶短纤纱交织物与玄武岩长丝/涤纶长丝交织物,并对其织物厚度和阻燃性能进行测试与分析。结果表明：平纹交织物最薄,3/1斜纹交织物最厚,相同条件下玄武岩长丝/涤纶短纤纱交织物的厚度大于玄武岩长丝/涤纶长丝交织物;交织物垂直燃烧时,阴燃时间为0 s,续燃时间均不超过2 s,损毁长度为0～5 mm,交织物水平燃烧时,火焰蔓延速率和蔓延距离均为0,织物不燃,可应用于阻燃服装。     

Insights into the confinement effect on isobutane alkylation with C4 olefin catalyzed by zeolite catalyst: A combined theoretical and experimental study

Elucidating the confinement effect harbours tremendous significance for isobutane alkylation with C₄ olefin. Herein, the confinement effect over zeolite catalysts was elucidated by combining DFT calculations, experiments(using the novel Beta zeolite exposing only external surfaces(Beta-E) and conventional Beta-I zeolite with both external and internal surfaces) and multi-techniques(e.g., TGA-DTG,HRTEM, SEM and XRD). It is found that the main active sites for C₄ alkylation r...     

Characterization of four diol dehydrogenases for enantioselective synthesis of chiral vicinal diols

Enantiopure vicinal diols are important building blocks used in the synthesis of fine chemicals and pharmaceutical compounds. Diol dehydrogenase(DDH) mediated stereoselective oxidation of racemic vicinal is an efficient way to prepare enantiopure vicinal diols. In this study, four new bacterial DDHs(AnDDH from Anoxybacillus sp. P3 H1 B, HcDDH from Hazenella coriacea, GzDDH from Geobacillus zalihae and LwDDH from Leptotrichia wadei) were mined from the GenBank database and expressed in E. coli T7...     

Assessment of the binding of hydroxylated polybrominated diphenyl ethers to thyroid hormone transport proteins using a site-specific fluorescence probe

Polybrominated diphenyl ethers (PBDEs) have been shown to disrupt thyroid hormone (TH) functions on experimental animals, and one of the proposed disruption mechanisms is the competitive binding of PBDE metabolites to TH transport proteins. In this report, a nonradioactive, site-specific fluorescein-thyroxine (F-T4) conjugate was designed and synthesized as a fluorescence probe to study the binding interaction of hydroxylated PBDEs to thyroxine-binding globulin (TBG) and transthyretin (TTR), two major TH transport proteins in human plasma. Compared with free F-T4, the fluorescence intensity of TTR-bound conjugate was enhanced by as much as 2-fold, and the fluorescence polarization value of TBG-bound conjugate increased by more than 20-fold. These changes provide signal modulation mechanisms for F-T4 as a fluorescence probe. Based on fluorescence quantum yield and lifetime measurements, the fluorescence intensity enhancement was likely due to the elimination of intramolecular fluorescence quenching of fluorescein by T4 after F-T4 was bound to TTR. In circular dichroism and intrinsic tryptophan fluorescence measurements, F-T4 induced similar spectroscopic changes of the proteins as T4 did, suggesting that F-T4 bound to the proteins at the T4 binding site. By using F-T4 as the fluorescence probe in competitive binding assays, 11 OH-PBDEs with different levels of bromination and different hydroxylation positions were assessed for their binding affinity with TBG and TTR, respectively. The results indicate that the binding affinity generally increased with bromine number and OH position also played an important role. 3-OH-BDE-47 and 3'-OH-BDE-154 bound to TTR and TBG even stronger, respectively, than T4. With rising environmental level and high bioaccumulation capability, PBDEs have the potential to disrupt thyroid homeostasis by competitive binding with TH transport proteins.     

PPS针刺过滤毡常温下拉伸特点研究

结合PPS基布和PTFE基布的经、纬向拉伸性能及其经、纬纱拉伸性能的测试结果,研究分析了PPS基布针刺过滤毡与PTFE基布针刺过滤毡经、纬向所表现的不同拉伸特性。建议针对清灰机理,对除尘滤料的经向、纬向结构进行优化设计。