Electrochemical Study on Formation of Dy-Ni Alloy in Molten Chlorides

ＥｌｅｃｔｒｏｃｈｅｍｉｃａｌＳｔｕｄｙｏｎＦｏｒｍａｔｉｏｎｏｆＤｙ－ＮｉＡｌｌｏｙｉｎＭｏｌｔｅｎＣｈｌｏｒｉｄｅｓＴｏｎｇＹｅｘｉａｎｇ；ＬｉｕＧｕａｎｋｕｎ；ＹａｎｇＱｉｑｉｎ；ＨｏｎｇＨｕｉｃｈａｎ，（童叶翔）（刘冠昆）（杨绮琴）（洪惠婵）...     

锆及锆合金中微量铝的测定

本文介绍在硫酸介质中,先用钽试剂-氯仿萃取分离除去锆以及钛、铁、铪等;再在pH=8.5左右,用苯萃取铝-钽试剂配合物,用稀盐酸反萃取;最后在pH=5.5—6时用铬天青S比色以测定铝的方法,确定了其测定条件。本方法准确性好,灵敏度高,测定范围为0.0025%—0.035%。     

Predicting phase equilibrium,phase transformation,and microstructure evolution in titanium alloys

Phase transformation and microstructural evolution in commercial titanium alloys are extremely complex. Traditional models that characterize microstructural features by average values without capturing the anisotropy and spatially varying aspects may not be sufficient to quantitatively define the microstructure and hence to allow for establishing a robust microstructure-property relationship. This article discusses recent efforts in integrating thermodynamic modeling and phase-field simulation to develop computational tools for quantitative prediction of phase equilibrium and spatiotemporal evolution of microstructures during thermal processing that account explicitly for precipitate morphology, spatial arrangement, and anisotropy. The rendering of the predictive capabilities of the phase-field models as fast-acting design tools through the development of constitutive equations is also demonstrated. For more information, contact Y.-Z. Wang, Department of Materials Science & Engineering, Ohio State University, 2041 College Road, Columbus, OH 43221, USA; (614) 292-0682; fax (614) 292-1537; e-mail wang.363@osu.edu.     

电动车制动能量再生反馈控制研究

研究了电动汽车制动过程中的能量回馈，设计了混合励磁无刷电动机在汽车制动过程的能量再生反馈控制系统。以脉宽调制调压调速系统为例，研究各种制动态下的能量回馈过程。并将其安装在EV6600电动汽车上进行试验，结果表明：该控制系统可达到10%左右的能量回收效率。     

汽车喷烤漆自动控制系统

本文通过研究目前汽车烤漆房的实际运行情况，提出了一种汽车烤漆房喷漆自动控制系统，阐述了系统喷漆装置的构成、配合与运行原理，并构成了实际试验系统。     

NH4F及燃烧温度对燃烧合成长柱状Yb α-Sialon粉体的影响

采用SHS法合成了Yb α-Sialon粉体，采用XRD和SEM分析和研究了添加剂NH4F及燃烧温度对燃烧合成长柱状Yb α-Sialon相组成和形貌的影响。实验发现，在不同条件下，添加剂NH4F对燃烧合成长柱状α-Sialon的晶体形貌可以起到抑制和促进两个相反的作用。温度越高，晶体生长速率越大，反应降温越慢，晶体生长时间越长，长柱状晶体生长越完整。燃烧合成得到的长柱状α-Sialon粉体，在室温下，以酒精为介质经过30min以上的超声分散，可以达到较好的分散效果。     

基于危险理论的人工免疫原理与应用*

侧重以危险理论的基本机制为线索,对危险理论的研究现状加以系统论述.首先以危险理论的免疫模型入手,归纳提炼出仿真机理并建立起隐喻算法;介绍其中具有代表性领域中的应用情况;最后对基于危险理论的人工免疫研究的下一步工作进行展望.     

The dynamic evolution of aggregated lithium dendrites in lithium metal batteries

Lithium (Li) metal anodes promise an ultrahigh theoretical energy density and low redox potential,thus being the critical energy material for next-generation batteries.Unfortunately,the formation of Li den-drites in Li metal anodes remarkably hinders the practical applications of Li metal anodes.Herein,the dynamic evolution of discrete Li dendrites and aggregated Li dendrites with increasing current densities is visualized by in-situ optical microscopy in conjunction with ex-situ scanning electron microscopy.As revealed by the phase field simulations,the formation of aggregated Li dendrites under high current den-sity is attributed to the locally concentrated electric field rather than the depletion of Li ions.More specif-ically,the locally concentrated electric field stems from the spatial inhomogeneity on the Li metal surface and will be further enhanced with increasing current densities.Adjusting the above two factors with the help of the constructed phase field model is able to regulate the electrodeposited morphology from aggregated Li dendrites to discrete Li dendrites,and ultimately columnar Li morphology.The methodol-ogy and mechanistic understanding established herein give a significant step toward the practical appli-cations of Li metal anodes.     

A panoramic view of Li7P3S11 solid electrolytes synthesis,structural aspects and practical challenges for all-solid-state lithium batteries

The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm^-1, and deformability, the sulfide-based Li₇P₃S₁₁ solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li₇P₃S₁₁ could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li₇P₃S₁₁-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries.     

风电叶片大梁用碳纤维拉挤板材组合式加载压缩(CLC)测试浅析

依据ASTM D6641/D6641M-16《采用组合加载方式(CLC)测定聚合物基复合材料层压板压缩性能试验方法》标准,对风电叶片大梁用碳纤维拉挤板材进行压缩性能测试,通过采用不同类型的加强片制备压缩试样,对所测得的压缩强度、压缩模量和压缩应变的试验结果与失效模式进行分析.结果 表明,采用文中C型加强片制备的压缩试样,测得的压缩强度、压缩模量、压缩应变以及失效模式均较为理想,试验结果重复性较好.