A highly stable, efficient visible-light driven water photoelectrolysis system using a nanocrystalline WO3 photoanode and a methane sulfonic acid electrolyte

Nanostructuring of semiconductor films offers the potential means for producing photoelectrodes with improved minority charge carrier collection. Crucial to the effective operation of the photoelectrode is also the choice of a suitable electrolyte. The behaviour of the nanostructured WO(3) photoanodes in methane sulfonic acid solutions, which allow one to obtain large, perfectly stable visible-light driven water splitting photocurrents, is discussed. The important effect of the electrolyte concentration upon the current distribution and the related photocurrent losses within the nanoporous photoelectrodes is pointed out.     

Flexural Strengthening of RC Beams with Externally Bonded CFRP Systems: Test Results and 3D Nonlinear FE Analysis

This paper presents experimental results and a numerical analysis of the reinforced concrete (RC) beams strengthened in flexure with various externally bonded carbon fiber-reinforced polymer (CFRP) configurations. The aim of the experimental work was to investigate the parameters that may delay the intermediate crack debonding of the bottom CFRP laminate, and increase the load carrying capacity and CFRP strength utilization ratio. Ten rectangular RC specimens with a clear span of 4.2?m, categorized in two series, were tested to evaluate the effect of using the additional U-shaped CFRP systems on the intermediate crack debonding of the bottom laminate. Two different configurations of the additional systems were proposed, namely, continuous U-shaped wet layup sheets and spaced side-bonded CFRP L-shaped laminates. The fiber orientation effect of the side-bonded sheets was also investigated. A numerical analysis using an incremental nonlinear displacement-controlled 3D finite-element (FE) model was developed to investigate the flexural and CFRP/concrete interfacial responses of the tested beams. The finite-element model accounts for the orthotropic behavior of the CFRP laminates. An appropriate bond-slip model was adopted to characterize the behavior of the CFRP/concrete interface. Comparisons between the FE predictions and experimental results show very good agreement in terms of the load-deflection and load-strain relationships, ultimate capacities, and failure modes of the beams.     

Fundamental investigations on di-methyl ether (DME) as LPG substitute or make-up for domestic uses

The paper reports a series of experimental and model studies performed to assess the potential application of di-methyl ether (DME) as a substitute fuel in domestic appliances, commonly fed with LPG. Results are presented about combustion tests performed with pure DME and mixtures with propane and butane in variable concentrations, along with endurance and stability experiments, carried out to evaluate safety and compatibility of this fuel. The major conclusion is that a mixture of DME/LPG (DME: 15–20 vol.%) brings significant further improvement compared to pure DME.     

Distribution of Listeria monocytogenes molecular subtypes among human and food isolates from New York State shows persistence of human disease--associated Listeria monocytogenes strains in retail environments

While there is considerable information available regarding Listeria monocytogenes contamination patterns in food processing plants, our understanding of L. monocytogenes contamination and transmission in retail operations is limited. We characterized 125 food, 40 environmental, and 342 human clinical L. monocytogenes isolates collected in New York State from 1997 to 2002 using automated ribotyping and hly allelic variation. All environmental isolates were obtained from retail establishments and the majority of food isolates (98 isolates) were obtained from foods that were prepared or handled at retail. Overall, food and/or environmental isolates from 50 different retail establishments were characterized. The 125 food and 40 environmental isolates were differentiated into 29 and 10 ribotypes, respectively. For 16 retail establishments, we found evidence for persistence of one or more specific L. monocytogenes strains as indicated by isolation of the same EcoRI ribotype from food or environmental samples collected in a given establishment on different days. The human isolates were differentiated into 48 ribotypes. Statistical analyses showed that two ribotypes were significantly (P < 0.0001) more common among food isolates as compared with human isolates. However, a total of 17 ribotypes found among the human clinical isolates were also found among the food and environmental isolates. We conclude that L. monocytogenes, including subtypes that have been linked to human disease, can persist in retail environments. Implementation of Listeria control procedures in retail operations, which process and handle products that permit the growth of L. monocytogenes, are thus a critical component of a farm-to-table L. monocytogenes control program.     

Effects of aerobic training,resistance training,or combined resistance‐aerobic training on the left ventricular myocardium in a rat model

This study follows the left ventricular (LV) hypertrophy in rats undergoing aerobic training alone (A), resistance training alone (R), or combined resistance and aerobic training (RA) (usually referred as concurrent training) program. A sedentary control group (C) was included. LV remodeling was evaluated using electron and light microscopy. The LV weight to body weight (LVW: BW) increased 11.4% in A group, 35% in the R group, and 18% in the RA group compared to the C group. The LV thickness increased 6% in the A group, 17% in the R group, and 10% in the RA group. The LV internal diameter increased 19% in the A group, 3% in the R group, and 8% in the RA group compared with the C group. The cross‐sectional area of cardiomyocyte increased by 1% with the A group, 27% with R group, and 12% with RA training. The capillary density increased by 5.4% with A training, 11.0% with R training, and 7.7% with RA training compared with the C group. The volume fraction of interstitial collagen increased by 0.4% with training A, increased by 2.8% with R training, and 0.9% with RA training. In conclusion, except for the LV internal diameter, which increased more in the A group, the cardiac parameters increased more in the R group than in the other groups and in RA group than in A group. Collagen density increased from 5.4 ± 0.8% in the C group to 5.8 ± 0.6% in the A group (n. s.) (P > 0.05), to 8.2 ± 0.7% in the R group (P < 0.05), and to 6.3 ± 0.4% in the RA group (P < 0.05). These results demonstrate a significant increase for collagen content in the LV with R and RA exercise, but the increase was higher with R training alone than with RA training. Microsc. Res. Tech. 77:727–734, 2014. © 2014 Wiley Periodicals, Inc.     

Methylxanthines,phenolic composition,and antioxidant activity of bark from residues from mate tree harvesting (Ilex paraguariensis A. St. Hil.)

Leaves and products made from them are the major focus of research on bioactive compounds of mate (Ilex paraguariensis). However, studies on other parts of the plant, are scarce. The aim of this study was to determine the methylxanthines, phenolic compounds, and antioxidant activity of mate bark (residual biomass) and compare with those of mate leaves. The high antioxidant activity of mate bark and its high concentration of total polyphenols were apparent in both the aqueous and the methanolic extracts, the values of which were greater than those detected in the leaves. Of the phenolic acids identified, the levels of chlorogenic acid and 4,5-dicaffeoylquinic acid in the samples were significantly higher in the methanolic bark extract. With regard to methylxanthines, considerable concentrations were detected in the samples. The results obtained contribute to the viability of exploiting this residue, broadening the use of the mate plant.     

Impact of Sunflower (Helianthus annuus L.) Extracts Upon Reserve Mobilization and Energy Metabolism in Germinating Mustard (Sinapis alba L.) Seeds

One commonly observed effect of phytotoxic compounds is the inhibition or delay of germination of sensitive seeds. Mustard (Sinapis alba L.) seeds were incubated with aqueous extracts of sunflower (Helianthus annuus L.) leaves. Although sunflower phytotoxins did not influence seed viability, extracts completely inhibited seed germination. Inhibition of germination was associated with alterations in reserve mobilization and generation of energy in the catabolic phase of germination. Degradation of lipids was suppressed by sunflower foliar extracts resulting in insufficient carbohydrate supply. The lack of respiratory substrates and decrease in energy (ATP) generation resulted in suppression of the anabolic phase of seed germination and ultimately growth inhibition.Ewa Kupidłowska and Agnieszka Gniazdowska contributed equally to this work.