Magnetic resonance imaging of the effect of zeolite on lithium uptake in poplar

The use of a zeolite (clinoptilolite) to protect poplar plants from lithium-contaminated soil has been studied using magnetic resonance imaging. Lithium was used as a model contaminant as it could be tracked directly using specific nuclear magnetic resonance probes, rather than relying on relaxation time effects on protons due to paramagnetic solutes. The sorption of lithium to the zeolite was investigated both in static and dynamic systems; lithium was found to sorb readily to the zeolite over time. Poplar plants were grown in soil microcosms consisting of either sand or sand and zeolite with nutrients provided through the use of Hoagland's solution as the pore fluid. Both one-dimensional profiles of lithium concentration along poplar stems and direct lithium imaging of stem cross-sections were employed to reveal the uptake of the contaminant into the plant structure, showing significantly less lithium present in plants grown in sand and zeolite than those grown in sand alone. Evidence of structural features involved in the uptake of lithium was also obtained.     

Reduction of polyhalogenated methanes by surface-bound Fe(II) in aqueous suspensions of iron oxides

Uptake of ferrous iron from aqueous solution by iron oxides results in the formation of a variety of reactive surface species capable of reducing polyhalogenated methanes (PHMs). Pseudo-first-order reaction rate constants, k(obs), of PHMs increased in the order CHBrCl2 < CHBr2Cl < CHBr3 < CCl4 < CFBr3 < CBrCl3 < CBr2Cl2. The k(obs) values increased with the exposure time, teq, of Fe(II) to suspended iron oxides which was attributed to the rearrangement of initially sorbed Fe(II) species to more reactive surface species with time. At pH 7.2, the k(obs) values of PHMs also increased with the concentration of surface-bound ferrous iron, Fe(II)sorb, particularly when Fe(II)tot was increased to concentrations where surface precipitation becomes likely. At fixed total Fe(II) concentrations, k(obs) values increased exponentially with pH. The highest reactivities were associated with pH conditions where surface precipitation of Fe(II) is expected. Fe(II)sorb and pH, however, had opposite effects on the product formation of PHMs. At pH 7.2, the formation of formate from CX4 (X = CI, Br) increased with Fe(II)sorb, whereas increasing pH favored the formation of CHX3. The ratio of halogenated products and formate formed is indicative of the relative importance of initial one- or two-electron-transfer processes, respectively, and was found to depend on the type of iron oxide mineral also. Our data form a basis to assess the importance of chemical reactions in natural attenuation processes of PHMs in environmental systems under iron-reducing conditions.     

Thermal analysis and measurement of a solar pond prototype to study the non-convective zone salt gradient stability

Solar ponds combine solar energy collection with long-term storage and can provide reliable thermal energy at temperature ranges from 50 to 90 °C. A solar pond consists of three distinct zones. The first zone, which is located at the top of the pond and contains the less dense saltwater mixture, is the absorption and transmission region, also known as the upper convective zone (UCZ). The second zone, which contains a variation of saltwater densities increasing with depth, is the gradient zone or non-convective zone (NCZ). The last zone is the storage zone or lower convective zone (LCZ). In this region, the density is uniform and near saturation. The stability of a solar pond prototype was experimentally performed. The setup is composed of an acrylic tube with a hot plate emulating the solar thermal energy input. A study of various salinity gradients was performed based on the Stability Margin Number (SMN) criterion, which is used to satisfy the dynamic stability criterion. It was observed that erosion of the NCZ was accelerated due to mass diffusion and convection in the LCZ. It can be determined that for this prototype the density of the NCZ is greatly affected as the SMN reaches 1.5.     

Influence of ionic pretreatment on the performance of solid electrolyte dye-sensitized solar cells

Dye-sensitized solar cells (DSSCs) were manufactured with liquid iodine/iodide electrolyte solution in acetonitrile and a solid electrolyte based on plasticized poly(ethylene oxide) (PEO). Two types of titania electrodes manufactured from two-ingredient precursors were used to assess the efficacy of the solid electrolyte and the improvement produced by two chemical treatments. Solid electrolyte devices with a liquid electrolyte pretreatment applied to the electrolyte-oxide interface demonstrated improved photovoltaic performance compared to untreated solid electrolyte devices and solid electrolyte devices given an electrode-bulking sol treatment. Devices using electrodes made from hydrothermally synthesized titanate nanotubes resulted in lower performance than those made from the typically-used titania nanopowder, with significant performance loss resulting from the substitution of solid for liquid electrolyte, indicating the critical dependence of performance on electrolyte infiltration into the oxide layer.     

An objective validation of factual interview data.

How valid is information obtained from interviews? 91 physically handicapped individuals were interviewed by 5 female interviewers, each having a 3-hour training period. The information for some was obtained by talking directly to the handicapped person; for others, it was obtained from an adult relative. These data were checked against agency records and employer questionnaires. "It is indefensible to assume the validity of purportedly factual data obtained by interview." (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

光电能及其效益

南非目前正开展一项崭新而雄心勃勃的计划－改善偏远农村地区的能源供应状况。该计划的一个重要组成就是授予７家私营协营体特许权,分别在不同地区安装３５万台家用太阳能光电系统。该项计划对于农村地区能源发展具有突破性的意义。     

Nanoforest Nb2O5 photoanodes for dye-sensitized solar cells by pulsed laser deposition

Vertically aligned bundles of Nb(2)O(5) nanocrystals were fabricated by pulsed laser deposition (PLD) and tested as a photoanode material in dye-sensitized solar cells (DSSC). They were characterized using scanning and transmission electron microscopies, optical absorption spectroscopy (UV-vis), and incident-photon-to-current efficiency (IPCE) experiments. The background gas composition and the thickness of the films were varied to determine the influence of those parameters in the photoanode behavior. An optimal background pressure of oxygen during deposition was found to produce a photoanode structure that both achieves high dye loading and enhanced photoelectrochemical performance. For optimal structures, IPCE values up to 40% and APCE values around 90% were obtained with the N(3) dye and I(3)(-)/I(-) couple in acetonitrile with open circuit voltage of 0.71 V and 2.41% power conversion efficiency.     

Risky intensity peaks resulting from nonlinear holographic imaging

A study of the maximal intensity peaks due to nonlinear holographic images of obstacles such as obscurations or phase defects in a high-power laser system is presented. It is shown that the interference of the high-power plane wave and the converging image wave results in the formation of intensity maximums in the vicinity of the image plane, the values of which significantly exceed the intensity in the image plane itself. For round obstacles, analytical expressions that describe magnitudes and locations of the maxima depending on the radius and the type of obstacle are given. A procedure of numerical modeling that allows estimation of the influence of beam size, medium thickness, type, size, and shape of obstacles onto the properties of nonlinear images is described. It is demonstrated that for a given combination of the nonlinear medium and the high-power beam parameters, there is an intrinsic size of obstacles that is most harmful for the laser system components.