Optimizing the mechanical and physical properties of thermoplastic starch via tuning the molecular microstructure through co‐plasticization by sorbitol and glycerol

Nowadays, environmental hazards caused by plastic wastes are a major concern in academia and industry. Utilization of biodegradable polymers derived from renewable sources for replacing common petroleum‐based plastics is a potential solution for reducing the problem. In this regard, starch has become one of the most promising alternatives to non‐biodegradable polymers for depleting plastic waste thanks to its low expense, abundance, renewability and biodegradability. However, the main drawbacks of starch are its poor processability, weak mechanical properties and severe hydrophilicity. In this work, thermoplastic starch (TPS) samples have been prepared using glycerol and sorbitol as co‐plasticizers in a laboratory co‐rotating twin screw extruder. Based on the mechanical test results, glycerol caused higher elongation to break but had lower tensile strength and elastic modulus compared to sorbitol plasticized starch. Fourier transform infrared spectroscopy and DSC results indicated that the hydrogen bond interaction between starch chains and plasticizers could be improved by replacing glycerol by sorbitol, which resulted in higher resistance against retrogradation proved by XRD results. TGA illustrated that the higher the sorbitol to glycerol ratio was, the more stable was the TPS. Using a proper amount of plasticizers (42 wt% total plasticizer, sorbitol to glycerol ratio 2:1) led to the preparation of a TPS sample with optimized properties including enhanced mechanical properties, high thermal stability, strong hydrogen bond formation and high resistance against retrogradation. © 2017 Society of Chemical Industry     

Proximity effects of a layered periodic structure on miniaturization of patch antennas

A miniaturized microstrip antenna on a planar layered periodic structure is proposed, designed and fabricated. The proposed structure miniaturizes patch antennas in the microwave band. With varying the parameters of the proposed structure, the achieved miniaturization factor can be adjusted in the range 2.6–4.2. Numerical and experimental results are presented. © 2012 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2013.     

Lattice-based certificateless public-key encryption in the standard model

The notion of certificateless public-key encryption (CL-PKE) was introduced by Al-Riyami and Paterson in 2003 that avoids the drawbacks of both traditional PKI-based public-key encryption (i.e., establishing public-key infrastructure) and identity-based encryption (i.e., key escrow). So CL-PKE like identity-based encryption is certificate-free, and unlike identity-based encryption is key escrow-free. In this paper, we introduce simple and efficient CCA-secure CL-PKE based on (hierarchical) identity-based encryption. Our construction has both theoretical and practical interests. First, our generic transformation gives a new way of constructing CCA-secure CL-PKE. Second, instantiating our transformation using lattice-based primitives results in a more efficient CCA-secure CL-PKE than its counterpart introduced by Dent in 2008.     

Mitigation of Crystallization Fouling in a Single Heated Tube Using Projectiles of Different Sizes and Hardness

Fouling of heat exchangers is a prevalent operating drawback in many process industries. Efficient chemical inhibitors have predominantly been used for many years to combat deposit formation. Nevertheless, new stringent environmental legislations limit their utilization. On-line mitigation techniques, such as propulsion of projectiles at different injection rates, can also be utilized, which can, in turn, minimize the need for chemical inhibitors. Nevertheless, the experimental data are scarce and nonconclusive. In this experimental study, two spherical-type projectiles of different sizes and hardness have been used to clean the inner surface of a single heated tube that was subjected to the deposition of calcium sulfate. Projectiles were then introduced at different injection rate of every 2, 5, 10, 15, and 30 min. The experimental results show that (i) the projectiles would expedite initial nucleation of crystals even if they are soft and easy to propel inside the tube; (ii) fouling can only be mitigated if the projectiles exert a shear force such that the corresponding removal rate is greater than the net rate of the deposition; and finally (iii) harder projectiles with larger surface contact area are more efficient in cleaning the surface compared to those that are softer.     

Adsorptive desulfurization and denitrogenation of model fuel by mesoporous adsorbents (MSU-S and CoO-MSU-S)

Adsorption of heterocyclic sulfur- and nitrogen-containing compounds by mesostructure adsorbent (MSU-S) and its modified form with cobalt oxide is studied using model fuel. The results of characteristic tests (XRD, N₂ adsorption–desorption, FTIR, and SEM) indicate that CoO impregnation causes a negative impact on mesoporous structure, crystalline phase, and particle shape along with a positive effect on surface ion exchange. CoO modification increased the adsorption loadings of DBT and BT to about 33.6% and 45.7%, respectively. For nitrogen compounds adsorption with the model fuel, adsorption loadings of quinoline and carbazole increase by 6.7% and 8.6%, respectively. Data fitting for carbazole, DBT, and BT is achieved better by the Langmuir model than the Freundlich model, and the data of quinoline fitted very well to the Freundlich model for CoO-MSU-S.