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991.
Mechanical performance and dimensional stability of nano-silver impregnated densified spruce wood 总被引:2,自引:2,他引:0
Ghonche Rassam Mohammad Ghofrani Hamid Reza Taghiyari Behnam Jamnani Mohamad Ali Khajeh 《Holz als Roh- und Werkstoff》2012,70(5):595-600
The aim of this study was to investigate the effect of nano-silver treatment on some physical and mechanical properties of compressed low density wood species. Wood specimens were prepared from spruce (Picea abies), impregnated with water or nano-silver solution by empty cell process and compressed through radial direction in a hot press. The results showed that by nano-silver treatment, the spring back, bending strength (modulus of rupture) and impact load resistance were improved significantly. The best results for spring-back (0.04%) were seen in the nano-silver impregnated specimens that were compressed at 150°C for 4 hours. The modulus of rupture (MOR), modulus of elasticity (MOE) and impact load resistance in nano-silver impregnated densified specimens were gained for 53%, 41.2% and 175.7%, respectively (in comparison with controls). The maximum amounts of impact load resistance belonged to the nano-silver impregnated specimens which were compressed at press conditions of 150°C for 4 hours, showing the high ability of these specimens against high impact loads such as earthquake loads. An upcoming research (consisting of durability tests) will be done for evaluating the suitability of nano-silver impregnated densified spruce wood for exterior uses. 相似文献
992.
Tahergorabi R Sivanandan L Beamer SK Matak KE Jaczynski J 《Journal of the science of food and agriculture》2012,92(12):2534-2542
BACKGROUND: Skin‐on bone‐in chicken drumsticks were processed with isoelectric solubilization/precipitation to recover muscle proteins. The drumsticks were used as a model for dark chicken meat processing by‐products. The main objective of this study was conversion of dark chicken meat processing by‐products to restructured functional food product. An attempt was made to develop functional food product that would resemble respective product made from boneless skinless chicken breast meat. A three‐prong strategy to address diet‐driven cardiovascular disease (CVD)with a functional food was used in this study. The strategy included addition of three ingredients with well‐documented cardiovascular benefits: (i) ω‐3 polyunsaturated fatty acid‐rich oil (flaxseed‐algae, 9:1); (ii) soluble fiber; and (iii) salt substitute. Titanium dioxide, potato starch, polyphosphate, and transglutaminase were also added. The batters were formulated and cooked resulting in heat‐set gels. RESULTS: Color (L*a*b*), texture (torsion test, Kramer shear test, and texture profile analysis), thermal denaturation (differential scanning calorimetry), and gelation (dynamic rheology) of chicken drumstick gels and chicken breast gels were determined and compared. Chicken drumstick gels generally had comparable color and texture properties to the gels made from chicken breast meat. The endothermic transition (thermal denaturation) of myosin was more pronounced and gelation properties were better for the drumstick gels. CONCLUSION: This study demonstrated a feasibility to develop functional food made of muscle proteins recovered with isoelectric solubilization/precipitation from low‐value dark chicken meat processing by‐products. The functional food developed in this study was enriched with CVD‐beneficial nutrients and had comparable instrumental quality attributes to respective products made of chicken breast meat. Although the results of this study point towards the potential for a novel, marketable functional food product, sensory tests and storage stability study are recommended. Copyright © 2012 Society of Chemical Industry 相似文献
993.
A reactive cyclodextrin was synthesised by reacting β‐cyclodextrin with itaconic acid to enable it to fix permanently onto cellulosic materials. Because synthesis is a complicated process that is greatly influenced by many factors, the response surface methodology was applied in this study to optimise production. To investigate the efficiency of the esterification reaction, the amount of carboxyl groups and the double bond content of the end product were measured and employed as the responses. The 3D response surface plots and the contour plots derived from the mathematical models were applied to evaluate the interactive effects of parameters affecting the reaction, such as itaconic acid and catalyst concentrations, material to liquor ratio, temperature and time of reaction. The amount of carboxyl groups and the double bond content of cyclodextrin itaconate (about 175 and 150 meq./100 g CDI, respectively) in the optimum conditions indicated that one to two itaconic acid molecules could react with cyclodextrin according to the esterification reaction. In addition, the presence of the new supplementary groups on cyclodextrin could effect on the aggregation behaviour of this new cyclodextrin derivative as demonstrated by dynamic light scattering and AFM. 相似文献
994.
Mostafa Keshavarz Moraveji Mohamad Morovati Pasand Reza Davarnejad Yusuf Chisti 《加拿大化工杂志》2012,90(1):93-99
Effects of various concentrations (0–5 ppm) of anionic (sodium dodecyl sulfate, SDS) and non‐ionic (Tween‐80 and Triton X‐405) surfactants on gas hold‐up and gas–liquid mass transfer in a split‐cylinder airlift reactor are reported for air–water. Surfactants were found to strongly enhance gas hold‐up. Non‐ionic surfactants were more effective in enhancing gas hold‐up compared to the anionic surfactant SDS. An enhanced gas hold‐up and a visually reduced bubble size in the presence of surfactants implied an enhanced gas–liquid interfacial area for mass transfer. Nevertheless, the overall gas–liquid volumetric mass transfer coefficient was reduced in the presence of surfactants, suggesting that surfactants greatly reduced the true liquid film mass transfer coefficient and this reduction outweighed the interfacial area enhancing effect. Presence of surfactants did not substantially affect the induced liquid circulation rate in the airlift vessel. 相似文献
995.
Mehdi Asgari Mohammad Ghannadi Maragheh Reza Davarkhah Elaheh Lohrasbi Ahmad Nozad Golikand 《Electrochimica acta》2012
In this work, Ni–Co alloy coating on the surface of glassy carbon (GC) electrode was performed by cyclic voltammetry. The results showed that the deposition of Ni–Co is an anomalous process. The deposition bath was prepared according to the metal ion Ni/Co ratio of 4:1 using NiSO4·7H2O and CoSO4·8H2O, and the total concentration of all solutions was 40.0 mM. The pH of the bath solution was adjusted at 2.0 using boric acid at room temperature. The modified electrode was conditioned by potential recycling in a potential range of 100–700 mV (vs. Ag/AgCl) by cyclic voltammetric method in an alkaline solution. The Ni–Co modified electrode showed a higher activity towards methanol oxidation in the Ni (III) and Co (IV) oxidation states. Cyclic voltammetry was used for the electrochemical characterization of the Ni–Co modified electrode and the mechanism of methanol oxidation is proposed. The result of double steps chronoamperometry shows that the methanol electrooxidation is an irreversible reaction. Moreover, the effects of various parameters such as mole ratio of Ni–Co in the alloy in modification step, potential scan rate, methanol concentration and solution temperature on the electro-oxidation of methanol have also been investigated. 相似文献
996.
The present study deals with the multi-objective optimization for designing a combined gas turbine and multi stage flash desalination plant. In optimization approach, the exergetic, economic and environmental aspects have been considered, simultaneously. In order to achieve the optimal design, Multi-objective genetic algorithm (MOGA) is applied as a suitable optimization technique. The thermoenvironomic objective function is obtained by integrating the environmental impacts and thermoeconomic objective. By applying the optimization approach, this objective function is minimized, whereas system exergy efficiency is maximized. Moreover, equipment reliability using the state-space and the continuous Markov method is incorporated in optimization results to improve the products' cost values. The optimization results show that the cost of products and environmental cost impact are reduced by 13.4% and 53.4%, respectively, whereas a 14.8% increase happens in total exergy efficiency. Therefore, improvement in all objectives has been achieved using the optimization process, although the power and water productions have not changed much. Additionally, the sensitivity analysis shows the relationship between the fuel cost, pollution damage cost and the objective functions. 相似文献
997.
In this study, Fe2O3.Al2O3/polyethylene composites were prepared using a two‐step process. In the first step, PE is synthesized using titanium based metallocene catalyst system. While the synthesized PE was subsequently purified, hydrated alumina filled PE (MHFP) composites was formed by the hydrolysis of methylaluminoxane (MAO). In the second step, Fe2O3.Al2O3/PE was prepared via thermal decomposition of ferric formate in a high temperature solution of MHFP composite. The structure, morphology, and thermal properties of the composites were characterized using the XRD, FTIR, SEM‐EDX, TGA, and DSC analytical techniques. Results showed that the incorporation of a suitable amount of Fe2O3.Al2O3 into the composites enhances the thermal stability. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
998.
Different polydimethylsiloxane (PDMS) nanocomposite membranes were synthesized by incorporating various contents of nanosized silica particles to improve the PDMS pervaporation (PV) performance. A uniform dispersion of silica nanoparticles in the PDMS membranes was obtained. The nanocomposite membranes were characterized morphologically by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The results showed that surface roughness increases by incorporating silica, and this decreases absorption of penetrants on the membrane. Swelling studies showed that the presence of silica nanoparticles into the PDMS membranes decreases degree of swelling, which can be attributed to rigidification of the PDMS matrix. Additionally, the results revealed that helium permeability decreases through the nanocomposite membranes, due to the more polymer chains packing. Effects of silica on recovery of isopropanol (IPA) from water mixtures were also investigated. Based on the results, incorporating silica nanoparticles promotes significantly the PDMS membrane selectivity because the polymer chains are rigidified and also the polymer free volume decreases. However, permeation flux decreases as diffusion of the penetrants reduces in the presence of silica nanoparticles within the PDMS membranes. As PV performance depends on operating conditions, effects of feed composition, and temperature were also studied. Moreover, recoveries of IPA, ethanol, and methanol from water mixtures were compared using the PDMS‐silica nanocomposite membranes. The results demonstrated that polarity and solubility of alcohols affect permeation flux and selectivity resulting in the higher permeation flux and selectivity for IPA. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
999.
Vahideh Shahedifar Hamid Reza Tajik Amir Masoud Rezadoust 《Propellants, Explosives, Pyrotechnics》2012,37(5):569-574
The inhibitory effect of double‐base solid propellants is used to control and prevent the burning degree of exposed areas, induced by longer burning time. In recent years, inhibition with cellulose derivatives including cellulose acetate and ethyl cellulose has become popular, but these monolithic systems usually suffer from the drawback of a high erosion rate and demand high thickness and low burning time. A composite inhibitor based on cotton fibers/epoxy resin containing some chlorinated flame retardants (CFR), which were added in inhibitor composition to control its burning process, is described in this article. The thermal properties of the composite inhibitor were studied by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), thermomechanical analysis (TMA), and flame retardancy. Finally, the inhibited propellant charge, statically fired at ambient temperature, was found to display a smooth and flat pressure‐time profile, confirming the successful performance of the composite inhibition system without the application of any barrier coat. 相似文献
1000.
Mohammad Reza Vakili Saeed Zahmatkesh Tahereh Jafarizadeh Mohammad Javad Panahiyan 《Polymer Bulletin》2012,68(1):85-94
N-trimelliticimido-l-aspartic acid (1) was prepared from the reaction of trimellitic anhydride with l-aspartic acid in a mixture of glacial acetic acid and pyridine solution (3/2 ratio) under refluxing conditions. The solution
polycondensation of the corresponding activated monomer with eight aromatic diamines were carried out in DMAc. The resulting
poly(amide-imide)s were obtained in quantitative yields, showed admirable inherent viscosities (0.20–0.36 dl g−1), good optical activity (+7.32o to +15.24o), and were readily soluble in polar aprotic solvents. They start to decompose
(T
10%) above 170 °C and display glass-transition temperatures at 120–237 °C. All of the above polymers were fully characterized
by UV, FT–IR, and 1HNMR spectroscopy, elemental analysis, thermogravimetric analyses, DSC, inherent viscosity measurement, and specific rotation. 相似文献