An Engineering Design Curriculum for the Elementary Grades

The United States has historically excelled in the design of products, processes and new technologies. Capitalizing on this historical strength to teach applied mathematics and science has many positive implications on education. First, engineering design can be used as a vehicle for addressing deficiencies in mathematics and science education. Second, as achievement in mathematics and science is enhanced, a greater number of students at an earlier age will be exposed to technical career opportunities. Third, enhancing elementary and secondary curricula with engineering design can attract underrepresented populations, such as minorities and females, to engineering as a profession. This paper describes a new and innovative engineering design curriculum, under development in the Austin Independent School District (AISD) in Austin, TX. The philosophic goals upon which the curriculum is based include: integrating the design problem-solving process into elementary schools, demonstrating the relationship of technical concepts to daily life, availing teachers with instructional strategies for teaching applied (as opposed to purely theoretical) science and mathematics, and teaching teamwork skills that are so greatly needed in industry and everyday life. Based on these goals, kindergarten, first grade, and second grade engineering design lessons have been piloted in AISD, in conjunction with a University of Texas program for teacher enhancement and preparation.     

High quality gate dielectrics formed by rapid thermal chemical vapor deposition of silane and nitrous oxide

In the present study, we have performed electrical characterization of oxides deposited via rapid thermal chemical vapor deposition using SiH₄ and N₂O. We have investigated the effect of temperature, pressure, and SiH₄ to N₂O ratio on the electrical and material properties of as-deposited films. We have found that as-deposited oxides deposited at low temperatures, low pressures, and with a low silane to nitrous oxide ratio of ～0.5% give good material and electrical properties. The as-deposited films are stoichiometric in nature and have high deposition rates. As-deposited films had very low D_it values, high breakdown fields, and excellent subthreshold swing. The leakage currents and metal oxide semiconductor field effect transistor current drive, although lower than thermal oxides, were found to be quite acceptable. We have also investigated the thickness dependence of the films and found that as the film thickness is reduced below 50Å, the reliability improves for all oxides including the silicon-rich deposited oxides.     

Real-time NMR investigations of triple-helix folding and collagen folding diseases

Folding of the collagen triple helix provides an opportunity to look at multichain molecular assembly. This triple helix also offers unique advantages for the study of folding because the process is very slow compared to globular proteins, and the kinetics of folding can be obtained in real time by NMR. Studies on triple-helical peptides illustrate the ability to observe kinetic folding intermediates directly and the ability to propose detailed mechanisms of folding through the use of real-time NMR methods. Defective collagen folding has been implicated in various connective tissue diseases and the capacity of NMR to look at the folding of specific sites provides a tool for obtaining information about altered folding mechanisms. Comparison of folding in peptides that model normal and diseased collagens could shed light on the molecular perturbation and the etiology of disease.     

A hierarchical distributed control model for coordinating intelligent systems

This paper describes a hierarchical distributed control (HDC) model for coordinating cooperative problem-solving among intelligent systems. The model was implemented using SOCIAL^TM, an innovative object-oriented tool for integrating heterogeneous, distributed software systems. SOCIAL embeds applications in “wrapper” objects called Agents, which supply predefined capabilities for distributed communication, control, data specification and translation. The HDC model is realized in SOCIAL as a “Manager” Agent that coordinates interactions among application Agents. The HDC-Manager indexes the capabilities of application Agents; routes request messages to suitable server Agents; and stores results in a commonly accessible “bulletin board.” This centralized control model is illustrated in a fault-diagnosis application for launch operations support of the Space Shuttle fleet at the NASA Kennedy Space Center.     

Lead-Ion Stability in Soda–Lime Lead Silicate Glasses

Sodium-calcium-lead silicate glass compositions were prepared over a wide compositional range by conventional glass-melting methods. The acid chemical stability of the glass structure was studied by corroding samples of glass in 4% acetic acid solution at 22°C for periods up to 24 h. Lead corrosion stability was evaluated by measuring lead concentrations in the corrosion solution. At short times, parabolic time dependence was observed and the parabolic time coefficients were regressed against composition, yielding a simple additive relationship. A similar model was fitted to 24-h release data, which showed compositional effects similar to the 2-h data. Of the oxides studied, sodium was the most detrimental to durability, and the coefficients of the oxides decreased in the series: Na₂O, PbO, CaO, SiO₂. The effects of the oxides could be partially explained by the number of nonbridging oxygens expected in the glass structure, and the residual effect was attributed to cation characteristics. Small phosphate additions to the glass greatly increased the lead-ion stability under nearly all experimental conditions examined.     

Combined-Stage Sintering Model

By focusing on the similarities between the three stages of sintering, a single equation is derived that quantifies sintering as a continuous process from beginning to end. The microstructure is characterized by two separate parameters representing geometry and scale. The dimensionless geometry parameter, denoted T, comprises five scaling factors that relate specific microstructural featuers (e.g., surface curvature) to the scale (grain diameter). Calculations of T from experimental data show (a) agreement with computer simulations of initial-stage sintering, (b) the effect of surface diffusion on T, and (c) changes in T with microstructural evolution during sintering. Application of the model to the design of firing schedules and the study of microstructural geometry effects on sintering is discussed.