Reaction processes effecting the analysis of chloroform by direct aqueous injection gas chromatography

Several important reaction processes which influence the analysis of chloroform by direct aqueous injection (DAI) gas chromatography have been identified through an investigation of the chlorination reactions of humic acid and a series of simple polyhydroxyaromatic and diketone model compounds in dilute solution. The reaction of chlorine with each substrate system was studied over the pH range 2–12. Gas chromatographic analysis by the DAI and organic solvent liquid-liquid extraction (LLE) procedures gave different measurements for the yield of CHCl₃ depending on the pH of the reaction solution and the chemical structure of the substrate. Under acidic and neutral conditions, a variety of trichloromethyl-substituted intermediates were identified at high concentrations in addition to chloroform by GC/MS. Chloral hydrate, trichloroacetic acid, pentachloroacetone and hexachloroacetone undergo hydrolysis and/or decarboxylation to form CHCl₃ at the high injection port temperatures employed in aqueous injection GC analysis. The results obtained in the current study indicate that the decomposition of these and structurally-related species accounts for differences previously observed upon application of the DAI and either the LLE or purge-and-trap techniques for the determination of CHCl₃ in chlorinated natural waters.     

Radon and 'King Solomon's Miners': Faynan Orefield, Jordanian Desert

Concentrations of 222Rn were measured in ancient copper mines which exploited the Faynan Orefield in the South-Western Jordanian Desert. The concentrations of radon gas detected indicate that the ancient metal workers would have been exposed to a significant health risk and indicate that any future attempt to exploit the copper ores must deal with the hazard identified. Seasonal variations in radon concentrations are noted and these are linked to the ventilation of the mines. These modern data are used to explore the differential exposure to radon and the health of ancient mining communities.     

Analysis of Methods for Parallel Operation of Frequency Converters

Consideration is given to methods for the parallel operation of frequency converters by applying the active load division. The simulation model of the converter is presented. It consists of three parallel independent modules. A new principle of constructing individual modules of a frequency converter and the principle of their communication interface exhibiting resistance to destabilizing effects and allowing safe operation under nominal conditions even with a 5- to 10% range in time and amplitude values of pilot signals are developed.     

Test facility for investigation of heat transfer of promising coolants for the nuclear power industry

The results are presented of experimental investigations into liquid metal heat transfer performed by the joint research group consisting of specialist in heat transfer and hydrodynamics from NIU MPEI and JIHT RAS. The program of experiments has been prepared considering the concept of development of the nuclear power industry in Russia. This concept calls for, in addition to extensive application of water-cooled, water-moderated (VVER-type) power reactors and BN-type sodium cooled fast reactors, development of the new generation of BREST-type reactors, fusion power reactors, and thermonuclear neutron sources. The basic coolants for these nuclear power installations will be heavy liquid metals, such as lead and lithium-lead alloy. The team of specialists from NRU MPEI and JIHT RAS commissioned a new RK-3 mercury MHD-test facility. The major components of this test facility are a unique electrical magnet constructed at Budker Nuclear Physics Institute and a pressurized liquid metal circuit. The test facility is designed for investigating upward and downward liquid metal flows in channels of various cross-sections in a transverse magnetic field. A probe procedure will be used for experimental investigation into heat transfer and hydrodynamics as well as for measuring temperature, velocity, and flow parameter fluctuations. It is generally adopted that liquid metals are the best coolants for the Tokamak reactors. However, alternative coolants should be sought for. As an alternative to liquid metal coolants, molten salts, such as fluorides of lithium and beryllium (so-called FLiBes) or fluorides of alkali metals (so-called FLiNaK) doped with uranium fluoride, can be used. That is why the team of specialists from NRU MPEI and JIHT RAS, in parallel with development of a mercury MHD test facility, is designing a test facility for simulating molten salt heat transfer and hydrodynamics. Since development of this test facility requires numerical predictions and verification of numerical codes, all examined configurations of the MHD flow are also investigated numerically.     

Fitting interrelated datasets: metabolite diffusion and general lineshapes

Objective

Simultaneous modeling of true 2-D spectroscopy data, or more generally, interrelated spectral datasets has been described previously and is useful for quantitative magnetic resonance spectroscopy applications. In this study, a combined method of reference-lineshape enhanced model fitting and two-dimensional prior-knowledge fitting for the case of diffusion weighted MR spectroscopy is presented.

Materials and methods

Time-dependent field distortions determined from a water reference are applied to the spectral bases used in linear-combination modeling of interrelated spectra. This was implemented together with a simultaneous spectral and diffusion model fitting in the previously described Fitting Tool for Arrays of Interrelated Datasets (FiTAID), where prior knowledge conditions and restraints can be enforced in two dimensions.

Results

The benefit in terms of increased accuracy and precision of parameters is illustrated with examples from Monte Carlo simulations, in vitro and in vivo human brain scans for one- and two-dimensional datasets from 2-D separation, inversion recovery and diffusion-weighted spectroscopy (DWS). For DWS, it was found that acquisitions could be substantially shortened.

Conclusion

It is shown that inclusion of a measured lineshape into modeling of interrelated MR spectra is beneficial and can be combined also with simultaneous spectral and diffusion modeling.

     

Response to “On the Radicality of New York’s Reforming the Energy Vision” by Ross Astoria

Dr. Jeff D. Makholm responds to Professor Ross Astoria’s criticms of Dr. Makholm’s submission: “The REVolution yields to a more familiar path: New York’s Reforming the Energy Visition (REV), Electricity Journal 29 (2016), 48–55 as follows.     

Mathematical simulations of the electromagnetic system of a subminiature magnetoelectric engine

This paper is devoted to simulations of a valve electric engine with excitation from high-energy permanent rare-earth magnets. A feature of the design of the engine under consideration is that a stator is manufactured using the polycapillary glass-fiber technique. The conductors of the distributed stator winding are placed in holes pm the tube wall. The cylindrical bipolar rotor is made of iron–neodymium–boron. The assumption accepted in the work during the solving the Laplace equation has made it possible to obtain analytical solutions for the magnetic flux, emf, current, electromagnetic torque, and electromagnetic power.     

A Gas-Recirculation Control System in a Battery of Fuel Cells

Currently, power plants based on hydrogen—oxygen fuel cells are widely used. The advantages of such electrochemical generators are environmental friendliness, efficiency, and a wide power-output range. Some components of such engines are still being developed. One of these components is the working gasrecirculation system, which increases the efficiency of an installation. In addition, this system helps support the water balance in a fuel-cell stack by removing the water that occurs in the cavities of the membrane—electrode block as a result of the electrochemical reaction. With consideration of the complexity of the reactions that occur in an installation, an automatic control system (ACS) is necessary for the gas recirculation system. This article deals with the organization of an automatic control system based on a microprocessor controller, sensors, and actuators, which implements control algorithms for the components of the gas recirculation system.