Smoke development at different energy flux levels in an NBS smoke density chamber

An automatically controlled high-energy flux heater has been developed and utilized in an NBS Smoke Density Chamber.     

On the potential of combining neutron activation analysis and particle induced X-ray emission (PIXE) for micro- and microdistribution analysis of hard metals in human tissues

Tungsten carbide and cobalt are the main components of hard metal alloy while other metals such as chromium, niobium, tantalum, titanium and vanadium are sometimes added in smaller amounts. Exposure to hard metal dusts can induce a lung fibrosis with cobalt playing a major role. In order to provide information on the role that each metal may have in causing this disease, determination of the total content and the distribution of inhaled metals in lung tissue of hard metal workers is of paramount importance. However, samples such as transbronchial biopsy and bronchoalveolar lavage (BAL), often used in the medical diagnosis of pneumoconiosis, only allow for a small amount of material. This calls for sensitive and accurate analytical procedures for microdetermination and distribution of metals in pulmonary tissue and cellular material, such as macrophages. This work proposes a combination of sophisticated analytical techniques such as neutron activation analysis (NAA), currently applied to the determination of the total concentration of more than 30 elements in biological specimens, and PIXE analysis, particularly microPIXE, which has a great potential for microdistribution analysis in small biological samples. Principles and perspectives for the combined use of these techniques for the analysis of human tissue are outlined and discussed. NAA: determination of hard metals in lung tissue are carried out by neutron irradiation (2 × 10¹⁴ neutrons cm⁻² s⁻¹) in the HFR reactor of Petten. After neutron activation, radiochemical separations of ⁶⁰Co, ¹⁸⁷W, ¹⁸²Ta, ⁵¹Cr followed by computer-based high resolution gamma ray spectrometry allow the measurement of these elements in pulmonary tissues with sensitivities ranging from 10⁻⁴ μg (Cr) to 10⁻⁶ μg (W). PIXE: this technique is multielemental and of relatively high sensitivity (μg/g) even in small total sample masses of from 10 to 100 μg, thus allowing the analysis of parts of needle biopsies. Whereas PIXE has been successfully applied to many medical problems, its usefulness is limited in the total samples analysis for cobalt-related hard metal disease, due to the low levels of cobalt in tissue combined with severe element interferences from the generally more abundant metal, iron. Nevertheless, microPIXE, a special variety of the method scanning over the sample with a focussed ion beam of about 2 × 2 μm², could complement the NAA findings in total samples in the sense of achieving a microdistribution analysis of hard metals (including cobalt) in suitable thin tissue sections.The availability of specialized facilities at the JRC such as the powerful HFR reactor (Petten), the NAA laboratories (Ispra) and the microPIXE facility (Geel) could represent a European ‘reference pole’ for the study of metals in tissues of hard metal diseased subjects.     

The coagulation of a kaolinite suspension with aluminium sulphate

A study has been made of the coagulation of a 50 mg l⁻¹ aqueous suspension of kaolinite for a range of aluminium sulphate and hydrogen ion concentrations. The rate of flocculation was determined from jar tests after stirring for 1 h. The data permitted a stability limit diagram to be drawn from which some indication of the coagulation mechanisms of the system could be ascertained.     

Laboruntersuchungen zur Freisetzung von Unat aus einem Gestein unter oxischen naturnahen Bedingungen

Kurzfassung Im Labor wurden verschiedene Größen (pH-Wert, HCO ₃ —Gehalt, Präsenz von Fe(OH) ₃ ) untersucht, von denen angenommen werden konnte, dass sie die umweltrelevante Freisetzung von Uran aus Gesteinen (z. B. Haufwerken, Halden, Tailings) im neutralen und schwach basischen pH-Bereich (6 bis 9) beeinflussen. Hierzu wurde der Austrag von U _nat aus einem schwach vererzten Urangestein (2,31 %) in Batchversuchen untersucht. Diese Versuche wurden mit 8, 10 oder 40 g/l Gestein und Leitungs- bzw. Mineralwasser durchgeführt. Zum Vergleich wurden parallele Standversuche in deionisiertem Wasser, 0,1 M Na ₂ CO ₃ und 0,1 M H ₂ SO ₄ durchgeführt. Die Ergebnisse zeigen eine Begünstigung der Uranfreisetzung in Anwesenheit von Carbonat (gelöst oder in situ durch Dolomitauflösung entstanden), während die Rolle des Pyrits auf die Freisetzung deutlich komplexer ist. Das Erreichen eines Gleichgewichtszustands kann unter Umständen durch sorptive Einflüsse verzögert werden.

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Investigations for the release of U_nat from ore bearing rock under natural near oxic conditions

Abstract The effects of carbonate concentration and the presence of iron hydroxide phases on uranium release into the environment were investigated under oxic conditions and in the pH range from 6 to 9. For this purpose not-shaken batch experiments were conducted with a constant amount (8, 10 or 40 g/l) of a uranium bearing rock and different types of water (deionised, tap and mineral water). For comparison parallel experiments were conducted with 0.1 M Na ₂ CO ₃ and 0.1 M H ₂ SO ₄ . The use of dolomite confirmed the favourable role of carbonate bearing minerals for U transport while the presence of pyrite on Uranium mobilisation was shown to be considerably more complex. This study shows that the approach of equilibrium conditions can be strongly delayed by sorption processes.

     

Reliability of corrosion-damaged steel structures using interval probability theory

Engineering decisions concerning the performance of existing structures must be made in the presence of uncertainties. The remaining capacity of corroded steel structures provides a good example of different aspects of uncertainty. These include: an unknown or partially known extent of damage; a variability in loading and an uncertain reserve of structural capacity depending on the mode of failure. The theory of structural reliability has been developed to provide a method of analysis for structural safety. In this paper, methods are proposed to compute the component reliability of corrosion-damaged steel members. The application of a recently developed theory called interval probability theory for system reliability is illustrated using the data obtained from actual samples of corroded beams.     

Gravity driven counterflow through an open door in a sealed room

Flow measurements using tracer gas techniques were made on the exterior doorway of a test house for indoor-outdoor temperature differences of 0.5–45 K. The time for door opening and closing was constant at 3.75 s, and fully open hold time varied from 0.5 s to 120 s. Predictions of a variable density steady flow model were in good agreement with the measurements when adjustments were made for the time-varying size of the opening and for the effect of cross-stream mixing between the incoming and outgoing air streams. The flow rate is shown to be governed by an effective density very close to the average of inflow and outflow densities, and the control condition at the doorway is fixed by the jet-like behavior of the inflow stream. Dependence of cross-stream mixing on interfacial stability caused the orifice and coefficient to increase from 0.4 to 0.6 as temperature difference increased. This varying orifice coefficient is well represented by the combination of a discharge coefficient for streamline contraction combined with a mixing coefficient which accounts for mixing between the inflow and outflow.     

Separation of physical loading from photosynthesis/respiration processes in rivers by mass balance

Diurnal variations in physical and chemical concentrations, including nutrients, are observed in river ecosystems. Understanding these cycles and separating the effects of physical loading (from point and non-point sources) and biogeochemical processes are necessary for water management and the TMDL process. A chloride mass balance approach is used to separate the relative influences of physical loading and biogeochemical processes in the Bow River through Calgary, Canada, which has a significant influence on the river water chemistry. Sampling campaigns were conducted in December 2005, when minimal photosynthesis and respiration occur, and in July 2006, when river discharge is high and some photosynthesis and respiration activity is present. Samples in each campaign were collected at point source input and output along the river reach through the city every hour for a 24-hour period, allowing for time of travel. The two wastewater treatment facilities within the city contributed the majority of physical mass loading to the river, with temporal variations in effluent discharge, chloride, and nutrient concentrations. Wastewater effluent chloride to nutrient (as well as other parameter relationships) concentrations also varied diurnally. An hourly chloride mass balance was achieved, within 0.5% (average, S.D.=4.4) for December and 7.7% (average, S.D.=4.2) for July, between estimated cumulative sum values from all inputs and measured values at the river output downgradient of the city, allowing for the investigation of other parameter conservativeness. Some slight diurnal variations associated with photosynthesis and respiration were observed even with limited productivity in the river. Nitrate mass fluxes appeared to be most strongly influenced by photosynthesis and respiration processes, with phosphate being less influenced. Ammonia mass fluxes appeared to be most strongly influenced by wastewater effluent loading. Physical loading can mask or enhance biogeochemical diurnal fluctuations, creating errors in river process interpretations. Chloride was a useful tracer in the mass balance to distinguish between and assist in separating physical loading and biogeochemical processes in the river.     

Lead contamination in tap water of households with children in Lower Saxony, Germany

Lead has numerous acute and chronic adverse effects on human beings. This is especially true for infants and children. The main path of lead ingestion in children can be different according to housing and living situation. The intake of lead through drinking water is commonly due to metal corrosion. The users plumbing can be an important factor. In recent years, many lead pipes in Germany have been replaced by pipes made of an alternative material. The aim of this study is to assess the present state of drinking water contamination and the resulting exposure of infants to lead. For this purpose mothers of new-born babies were offered a free examination of their drinking water. After a written declaration of consent had been obtained and after the infant in question had reached an age of 3 months, a stagnation sample of cold tap-water after overnight stagnation together with a random daytime sample was obtained from the family. The collected samples were analysed by atomic absorption spectrometry for their lead concentration. In total, 1485 samples from households were collected. Of the 1434 stagnation samples, 3.1% had lead concentrations greater than 0.01 mg/l (recommended limit of the WHO) and 0.6% had concentrations above the limit of the German drinking water regulation (0.04 mg/l). The values for the 1474 random daytime samples were 2.1% above 0.01 mg/l and 0.2% greater than 0.04 mg/l, respectively. By region, the areas Bovenden, Friedland, Duderstadt, Northeim and Rosdorf were particularly affected. The highest measured concentrations of lead in the stagnation samples were 0.11 mg/l and 0.15 mg/l in the random daytime samples, respectively.