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11.
Sunil Pandey Ritu Shah Ashmi Mewada Mukeshchand Thakur Goldie Oza Madhuri Sharon 《Journal of materials science. Materials in medicine》2013,24(7):1671-1681
Use of cysteamine hydrochloride (Cys-HCl) protected gold nanorods (GNRs) as efficient carrier of widely used anti-cancer drug doxorubicin using folic acid as navigational molecule is presented in this work. GNRs were found to have excellent drug loading capacity of >97 %. A detailed comprehension of in vitro drug release profile under ideal physiological condition was found to obey 1st order kinetics at pH 6.8, 5.3 and 7.2, an ideal milieu for drug delivery to solid tumours. 相似文献
12.
Gagan Kumar Ritu Rani Sucheta Sharma Khalid M. Batoo M. Singh 《Ceramics International》2013,39(5):4813-4818
Cobalt substituted Mg–Mn nanoferrites with formulae Mg0.9Mn0.1CoxFe2?xO4, x=0.0, 0.1, 0.2 and 0.3, have been synthesized for the first time by the solution combustion technique. The effects of Co2+ ions on the dc resistivity, dielectric constant and dielectric loss tangent of Mg–Mn nanoferrites at room temperature are presented in this paper. X-ray diffraction confirmed the formation of a single phase spinel structure. Particle size was found to increase, 20.9–23.9 nm, with increasing Co2+ concentration. The dc resistivity was increased by two order of magnitude with substitution of Co2+ ions while the dielectric constant was found to be decreasing with the increasing concentration of cobalt ions. The value of dc resistivity obtained for Mg0.9Mn0.1Fe2O4 nanoferrite in our work is greater than the value obtained for the same composition prepared by the conventional ceramic technique. Further, the dielectric constant and dielectric loss tangent were observed to be decreasing with the increase in frequency. 相似文献
13.
Pramod Chaitanya Ritu Mishra Pradeep Kumar Ahirwal O. P. Thakur Lakshman Pandey 《Integrated ferroelectrics》2015,159(1):121-126
The electrical behavior of strontium titanate borosilicate glass ceramics (SrO.TiO2- 2SiO2.B2O3) with additives K2O, La2O3, CoO and Nb2O5 was studied by using Impedance Spectroscopy as a function of temperature and composition. An equivalent circuit model having three parallel RC's connected in series with a capacitor C4 could represent the data well. By comparing the complex modulus plots with simulated ones and looking at the values of the time constants these RC's were attributed to represent crystalline, glassy and glass-crystal interface regions of the glass- ceramic whereas C4 represented the glass-ceramic sample and contact electrode interface. When the glass ceramic sample contained only SrTiO3 crystalline phase and the remaining glassy matrix, the interface capacitance showed an Arrhenius type of nature with an activation energy (0.11 ± 0.04) eV and when the glass- ceramic sample contained number of crystalline phases no clear cut trend appeared. These findings are useful in selecting suitable electrodes for applications as well as in deciding upon experimental techniques for measurement of dielectric constants of materials. 相似文献
14.
Vijay K. Tomer Surender Duhan Ritu Malik Satya P. Nehra Sunita Devi 《Journal of the American Ceramic Society》2015,98(12):3719-3725
This work deals with the study of hydrothermally synthesized zinc oxide (ZnO) loaded mesoporous SBA‐15 hybrid nanocomposite for relative humidity sensing (RH) at room temperature. The sensor exhibits an excellent ~5 orders impedance change along with excellent linearity, quick response time (17 s), rapid recovery time (18 s), negligible hysteresis (1.2%), good repeatability, and stability (1.8%) in 11%–98% RH range. In addition, complex impedance spectra of the sensor at different RHs were analyzed to understand the humidity sensing mechanism. Our study can open a new way for realizing ZnO/SBA‐15 hybrid nanocomposite for fabrication of high‐performance RH sensors. 相似文献
15.
Molecular Recognition of Parallel DNA Quadruplex d(TTAGGGT)4 by Mitoxantrone: Binding with 1:2 Stoichiometry Leading to Thermal Stabilization and Telomerase Inhibition
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Sweta Tripathi Tarikere Palakshan Pradeep Dr. Ritu Barthwal 《Chembiochem : a European journal of chemical biology》2016,17(7):554-560
The interaction of the anthraquinone derivative mitoxantrone, a semisynthetic anti‐cancer drug with two non‐planar side chains, with heptamer G‐quadruplex d(TTAGGGT)4, which contains the human telomere DNA sequence, was evaluated by differential scanning calorimetry, fluorescence Job plotting, absorption, and NMR and CD spectroscopy. Binding led to thermal stabilization of DNA (ΔTm=13–20 °C). The spectra revealed that two mitoxantrone molecules bind externally at two sites of the DNA quadruplex as monomers, by partial insertion of the chromophore and side‐chain interaction at the grooves. The inhibition of telomerase (IC50=2 μm), as determined by a TRAP assay, can be attributed to thermal stabilization of the DNA quadruplex because of the interactions with mitoxantrone. The studies revealed highly specific molecular recognition between a ligand and a parallel‐stranded G‐quadruplex; this might serve as a platform for the rational design of new drugs. 相似文献
16.
Rekha Agrawal Jyoti Shah Govind Gupta Ritu Srivastava Chhemendra Sharma Ravinder Kotnala 《应用聚合物科学杂志》2020,137(48):49566
A facile and eco-friendly synthesis of polypyrrole from monomer pyrrole using nominal amount of ferric chloride hexahydrate (FeCl3.6H2O) oxidant in aqueous solution by chemically oxidative polymerization method has been reported. The use of aqueous solvent and ferric chloride hexahydrate salt in polypyrrole synthesis have an eco-friendly route favorable for the production of polypyrrole in large quantities. The synthesized polypyrrole samples exhibit good electrical conductivity (2 S/cm) and yield of 80% for reaction time of 8 hr at 5°C. Quality and properties of polypyrrole samples have been thoroughly investigated with varying reaction time and temperature while other synthesis parameters like molar ratio of oxidant to monomer, oxidant concentration, and solvent were kept constant. X-ray diffraction analysis of polypyrrole with a shorter reaction time shows the presence of iron oxide (Fe2O3) peaks. The complete reaction may not occur at shorter reaction times due to which residual ferric ions converted into Fe2O3. X-ray photoelectron spectroscopy measurement of polypyrrole also confirms the formation of Fe2O3. Appropriate selection of reaction time and temperature produced pure phase polypyrrole with high yield and good conductivity. Synthesized polypyrrole by our eco-friendly and cost-effective technique exhibits prominent electromagnetic shielding effectiveness value of 30 dB in the X-band (8–12 GHz). 相似文献
17.
18.
Pooja Sarotra Gayatri Sharma Shevali Kansal Anjana Kumari Negi Ritu Aggarwal Rajat Sandhir Navneet Agnihotri 《Lipids》2010,45(9):785-798
n-3 Polyunsaturated fatty acids (PUFA) have a chemopreventive effect while n-6 PUFA promote carcinogenesis. The effect of
these essential fatty acids may be related to oxidative stress. Therefore, the study was designed to evaluate the effect of
different ratios of fish oil (FO) and corn oil (CO) in the prevention of colon cancer. Male Wistar rats were divided into
control, dimethylhydrazine dihydrochloride (DMH) treated, FO + CO (1:1) and FO + CO (2.5:1). All the groups, except the control
received a weekly injection of DMH for 4 weeks. The animals were sacrificed either 48 h later (initiation phase) or kept for
16 weeks (post initiation phase). DMH treatment in the initiation phase animals showed mild to moderate inflammation, decreased
ROS and TrxR activity, increased antioxidants, apoptosis and ACF multiplicity. The post initiation study showed severe inflammation
with hyperplasia, increased ACF multiplicity and ROS levels, a decrease in antioxidants and apoptosis. The FO + CO (1:1) treated
animals showed severe inflammation, a decrease in ROS, an increase in antioxidants and apoptosis in the initiation phase.
FO + CO (1:1) in the post initiation phase and FO + CO (2.5:1) in the initiation showed mild inflammation, increased ROS,
apoptosis and decreased antioxidants. There was a decrease in ACF multiplicity and ROS levels, increased antioxidants and
apoptosis in the post initiation phase study. The present study suggests that FO has a dose- and time-dependent chemopreventive
effect in colon cancer mediated through oxidative stress and apoptosis. 相似文献
19.
Micellar Properties of Surface Active Ionic Liquid Lauryl Isoquinolinium Bromide and Anionic Polyelectrolyte Poly(Acrylic Acid Sodium Salt) in Aqueous Solution
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The complex formation between anionic polyelectrolyte poly(acrylic acid sodium salt) [NaPAA] and surface active ionic liquid (SAIL) lauryl isoquinolinium bromide [C12iQuin][Br] in aqueous media has been investigated by surface tension, isothermal titration calorimetry (ITC), and conductance. The self‐assembled structures have been characterized using dynamic light scattering (DLS) and turbidity measurements. A range of surface parameters have been calculated from tensiometric measurements including critical micelle concentration (CMC), surface excess concentration (Γcmc), surface pressure at the interface (Πcmc), minimum area occupied at air–solvent interface (Amin), adsorption efficiency (pC20), and surface tension at the CMC (γcmc). The thermodynamic parameters, i.e., standard enthalpy of micellization , standard free energy of micellization (), and standard entropy of micellization () have also been evaluated. Four different stages of transitions, corresponding to the progressive formation of NaPAA–[C12iQuin][Br] complex (C1), critical aggregation concentration (CAC), critical saturation concentration (C3) and CMC have been observed owing to strong electrostatic and hydrophobic interactions. The results obtained from DLS and turbidity measurements show that size of the aggregates first decreases and then increases in the presence of polyelectrolyte. The binding isotherms obtained using isothermal titration calorimetry (ITC) show the concentration dependence as well as the highly cooperative nature of interactions corresponding to formation of polyelectrolyte–SAIL complexes. 相似文献
20.
In the present study, pressure drop-flow rate behavior for the flow of viscoelastic fluid through porous media has been investigated. Aqueous solutions of polyacrylamide (PAM) and water in the concentration range of 0.02 to 0.1% wt/vol were used to elucidate the effect of fluid elasticity on bed pressure drop. Based on the observed data, the existing pore model was extended to predict the bed pressure drop for viscoelastic fluid flowing through a porous media. A statistical comparison between the existing models and the present model was made. The proposed correlation based on modified pore model predicts the data well to within a reasonable accuracy of ±10% with arithmetic relative error (%ARE) and mean relative quadratic error (MRQE) of 8.3% and 0.122, respectively. 相似文献