POLARIZATION BEHAVIOR OF PACKED-BED ELECTRODES: A COMPARATIVE STUDY OF EXPERIMENTAL AND MODELING RESULTS

The current distribution and overall polarization behavior of electrodeposition at a flow-through (packed bed or fluidized bed) electrode are modeled by means of a one-dimensional model involving a primary reacting species and a simultaneous side reaction. The model equations are solved by orthogonal collocation; the time and storage requirements compare favorably to those of finite-difference methods. Experimental data obtained using a packed-bed electrode are compared with the model predictions and various methods of fitting the data are compared.     

Geometric criteria of hydrogen bonds in proteins and identification of `bifurcated' hydrogen bonds

Empirical criteria for identification of hydrogen bonds wereanalyzed to produce a set of geometrically consistent criteria.For a data set of 30 structures, application of a set of purelygeometrical criteria, along with exclusion of abnormal backboneconformations, also excluded a common interaction of Ser/Thrside chains with Asp/Glu side chains ([ST]/[DE] pairs). Theseinteractions were termed `bifurcated hydrogen bonds/', whichimplies delocalization of a positively charged hydrogen of hydroxylbetween the two acceptor atoms of the carboxylic group. These`bifurcated/' interactions are among the most common packingpatterns for [ST]/[DE] pairs of side chains. Therefore, theidentification of hydrogen bonds cannot be based on geometricalcriteria only and requires introduction of some physico-chemicalcriteria.     

Risk factors associated with recidivism among extrafamilial child molesters.

This study examined the predictive efficacy of 10 rationally derived, archivally coded variables for assessing reoffense risk among extrafamilial child molesters. Follow-up data on 111 child molesters who were discharged from the Massachusetts Treatment Center between 1960 and 1984 were used. Degree of sexual preoccupation with children, paraphilias, and number of prior sexual offenses predicted sexual recidivism. Juvenile and adult antisocial behavior, paraphilias, and low amount of contact with children predicted nonsexual victim-involved and violent recidivism. Area under the receiver-operating characteristic curves in all three analyses indicated discrimination that was substantially better than chance, ranging from .73 to .79. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

NONDESTRUCTIVE EXAMINATION OF EPOXY ADHESIVE-BONDED STRUCTURES EXPOSED TO A HUMID ENVIRONMENT: A COMPARISONOF LOW- AND HIGH-FREQUENCY DIELECTRIC MEASUREMENTS

Broadband dielectric measurements (10 -2 to 3 GHz) are reported on the effects of exposure of thick film adhesive-bonded structures to moisture. Measurement of the dielectric properties over a broad frequency range allows identification of water both in voids and as a molecular dispersion in the matrix. Changes in the low frequency region of the dielectric spectrum can be attributed to a combination of processes associated with plasticisation of the adhesive, interfacial polarisation effects, and hydration of the surface oxide layer. The data obtained are complemented by mechanical testing and failure analysis of the bond structure measured as a function of the time of exposure. This study indicates that for thick film adhesives the ageing characteristics are apparently independent of the surface treatment. In one of the joints studied an additional feature is identified which appears to correlate with the premature aging of the joint structure.     

Influence of regular aerobic exercise on psychological health: A randomized, controlled trial of healthy middle-aged adults.

Evaluated 120 healthy, sedentary, middle-aged adults randomly assigned to either a 6-mo home-based aerobic exercise training program or to an assessment-only control condition. Adherence across the 6-mo period by the exercise group was demonstrated by self-report and heart rate microprocessor methods to exceed 75%. A 14-item Likert rating scale was used to measure a variety of psychological variables. Significant between-groups differences favoring the exercise group were found on scale items closely associated with actual physical changes that occurred with exercise (satisfaction with shape/appearance, perceived fitness). (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

On Woolfolk and Richardson.

Comments on R. L. Woolfolk and F. C. Richardson's (see record 1985-12614-001) discussion of the ideology of behavior therapy and their argument that behavior therapy cannot develop a conception of what might be appropriate goals of treatment. The present author contends that goals are as much a scientific question as are questions of technique. A scientific approach to the study of goal selection is presented that can be applied to any type of adjustment problem. (8 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Relation between depressive symptoms and stressful life events in a sample of disadvantaged mothers.

The bidirectional relation between life events and self-reported depression was examined across a 1-year period. With Time 1 depression controlled, Time 2 stress accounted for an additional 10% of Time 2 depressive symptoms. Health-related stress, family violence, and financial stress at Time 2 predicted Time 2 depression after control for Time 1 depression. With Time 1 stress controlled, Time 2 depression accounted for 8% of the variance in Time 2 stress. Time 2 depression predicted Time 2 health-related stress, financial stress, household changes, spouse–partner stress, family violence stress, and substance abuse stress, controlling for each of these stressors at Time 1. The results describe a complex relation between stress and depression and suggest that the relation between stress and depression is moderated by the type of stress. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Child custody mediation and litigation: Parents' satisfaction and functioning one year after settlement.

A 1-yr follow-up study was conducted on families randomly assigned to settle custody disputes either in mediation or through adversary procedures. Consistent with Time 1 reports, at Time 2 fathers who mediated were substantially more satisfied than were fathers who litigated. Fathers who mediated also complied more with child support orders. Contrary to prediction, the greater satisfaction and compliance of fathers did not lead to increased satisfaction among mothers who mediated. In contrast to Time 1, at follow-up mothers who mediated were significantly less satisfied than were mothers who litigated, but selective attrition may account for these differences. The psychological adjustment of mothers and fathers was not significantly different between settlement groups at Time 2, but mothers in both groups reported less satisfaction with dispute settlement and less dysphoria at Time 2 than they had reported at Time 1. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Psychological adjustment of children with sickle cell disease: Stability and change over a 10-month period.

Rates of poor psychological adjustment of children with sickle cell disease remained relatively constant over initial and follow-up assessment points. 50 children (aged 7–12 yrs) and their mothers completed the initial protocol. 30 children completed the follow-up plus 5 additional children and their mothers. These Ss were aged 7–24 yrs at follow-up. With initial levels of adjustment controlled, children's strategies for coping with pain accounted for a significant increment in child-reported symptoms and mother-reported internalizing behavior problems at follow-up beyond the contribution of illness and demographic parameters and follow-up interval. (PsycINFO Database Record (c) 2010 APA, all rights reserved)