Effects of different Mg fertilizer sources on the magnesium availability in soils

Pot experiments with different soils were conducted to determine the effect of different Mg fertilizer sources on magnesium availability. The sources studied included Kieserite (MgSO₄ H₂O), a synthetic magnesium sulphate (SMS) with variable content of crystal water and a calcined magnesite (Mg-oxide). The three magnesium fertilizers vary greatly in their solubility in water, affecting the availability to plants once applied to the soil. Whereas Kieserite dissolved gradually and SMS immediately, Mg-oxide released only insignificant amounts of Mg in cool water (20 °C) after intensive stirring. Due to the fact that these dissolution properties may distinctly affect Mg availability in soils, Kieserite as a standard magnesium source was tested against a slow release Mg-oxide in the fine and the coarse form. Soil extraction of samples taken from 0–10 and 10–20 cm depths at 4, 8 and 12 weeks after applying the fertilizers to the soil surface revealed that the rate at which Mg appeared in the available pool (CaCl₂ extracts) varied significantly between Mg sources. Mg availability from Kieserite was much greater than from Mg-oxide. Nutrient availability from Mg-oxide depended on the fineness of the material, i.e. the coarser the less available. Maize grown as test plant in the pots revealed a 10.6% larger yield and 19.6% larger Mg uptake in Kieserite than in Mg-oxide treated pots. High solubility of a fertilizer under high rainfall conditions, however, may also affect the Mg availability through large losses occurring by Mg leaching. Therefore, in a second experiment, the behaviour of surface applied magnesium fertilizers, Kieserite versus a quickly dissolving synthetic magnesium sulphate (SMS) was studied, using an Ultisol (Serdang Series soil from Malaysia). A simulation of high rainfall by excessive irrigation of 20 mm per day over a period of 16 days to a water saturated soil revealed that the amount of Mg lost by leaching differed between the two Mg sources tested. The lowest amount with 8.7% of the applied Mg was lost in the Kieserite treatment at the low application rate and the highest with 22.3% in the SMS treatment at the high application rate. It is concluded that a gradual but strong release to match plants requirements is the most desired characteristic to maximize crop uptake and minimize losses.     

Travel Reports and Photography in Early Photographically Illustrated Books

Abstract

Abstract A previous article¹ dealt with some of the first books illustrated by tipped-in photographs, or else by early photomechanical procedures, with subject matter drawn from the fields of microscopy, medicine and astronomy. The present essay is concerned with technically similar publications, on topics of a more social nature.     

Restricted Least Squares Estimation of the Spectra and Concentration of Two Unknown Constituents Available in Mixtures

The problem considered is the identification of two unknown chemical compounds and the estimation of their proportions in a set of unknown mixtures of the two compounds, given data that are vectors of measurements on their mixtures. It is assumed that the expected value of a mixture vector is an unknown convex linear combination of two unknown component vectors and least squares estimation is used to obtain a set of possible solutions of the mixing proportions and the component vectors. Obtaining a unique solution requires additional constraints or information. The solution set is interpreted geometrically and examples involving amino acids and light absorbance data are given.     

The Biosynthesis of the Aroma Volatile 2‐Methyltetrahydrothiophen‐3‐one in the Bacterium Chitinophaga Fx7914

2‐Methyltetrahydrothiophen‐3‐one ( 3 ) is a volatile compound that plays an important role especially in food and flavour chemistry because it contributes to the aroma of several foodstuffs including wine. Although 3 can be formed by chemical reactions during food preparation, it is also produced by microorganisms. Recent studies with yeasts showed that methionine ( 1 ) is a potential precursor of 3 , but the mechanism of the transformation is unknown. The biosynthetic pathway leading to 3 in the bacterium Chitinophaga Fx7914 was probed. Extensive feeding experiments with differently labelled precursors by using liquid cultures of Chitinophaga Fx7914 were performed. The volatiles released by the bacterium were collected by using a closed loop stripping apparatus (CLSA) and analysed by GC–MS. The observed incorporation pattern of the precursors into 3 led to the elucidation of the biosynthetic pathway. One part of the compound 2 originates from homocysteine ( 15 ), which is transformed into 3‐mercaptopropanal ( 17 ). The second biosynthetic building block is pyruvate ( 14 ). An acyloin‐forming reaction furnishes the key intermediate 21 , which cyclises intramolecularly to a diol. Dehydration followed by tautomerisation lead to the cyclic ketone 3 , which is produced by the bacterium in racemic form.     

Mechanically activated minerals as a sink for CO2

CO₂ removal from exhaust gasses from burning of fossil fuels is a political issue. If undertaken on a large scale, enormous amounts of carbon dioxide will have to be taken care of. This paper investigates how mechanical activation of olivine and other Ca or Mg containing silicates can increase the mineral’s reactivity. Tests by grinding in a planetary mill have been done to investigate the effects of mechanical activation and other surface changes. The reactivity towards HCl and CO₂ has been determined as a function of grinding variables. Prolonged dry milling of olivine resulted in highly aggregated products, which were more reactive with respect to dissolution in acid than their respective BET surface areas would suggest. The initial breaking of bonds appears to give more reactivity on an energy usage basis than longer time activation. Most mechanical activation testwork so far has been carried out in batch mode. The result is diminishing effect of activation with increased grinding time. Continuous grinding and simultaneous reaction with some sort of classification may offer a chance of removing reaction products as soon as they are formed, giving a more energy effective process.     

Morphology of the transparent IPN‐like system PE: (BMA‐co‐S)

In the study of interpenetrating polymer networks (IPN)‐like systems consisting of polyethylene (PE) and butyl methacrylate (BMA)–styrene (S) copolymer PE/(BMA‐co‐S), the effect of the crosslinker on the morphology of IPN by using electron microscopy and atomic force microscopy (AFM) was investigated. The IPN‐like system PE/(BMA‐co‐S) represents a two‐phase system with finely dispersed domains of crosslinked PE matrix. The interphase between dispersed domains and PE matrix is inhomogeneous and is considered the most interpenetrated part of this IPN‐like system. The size of the domains decreases with the content of crosslinker used. The AFM micrographs allowed the observation of PE lamellae with lengths of about 25 nm. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 2615–2620, 2001     

NOx adsorption on MnO2/NaY composite: an in situ FTIR and EPR study

The NO, NO/O₂, and NO/O₂/H₂O adsorption on MnO₂/NaY (5 and 15 wt.% MnO₂) composite catalyst and NaY has been studied by means of in situ FTIR and EPR spectroscopy at elevated temperatures and during heating under reaction-like conditions. NO adsorption and co-adsorption of NO and O₂ on NaY and MnO₂/NaY proceeds via oxidation of NO forming NO₂⁻ and NO₃⁻ species. Whereas the manganese dioxide preferably acts as oxidising agent, the zeolite stores the NO_x species as nitrite and nitrate ions in the solid. In the presence of oxygen, the nitrate formation is enhanced due to additional oxidation of NO through gaseous oxygen leading to NO₂. Dimerisation of NO₂ to N₂O₄ and following disproportionation of the latter causes the formation of NO⁺ and NO₃⁻ species which are associated with nucleophilic zeolitic oxygen and especially alkali cations of the zeolite, respectively. The presence of oxygen facilitates reoxidation of Mn²⁺ which keeps more Mn ions in the active state. Pre-adsorbed water and higher amounts of water vapour in the feed hinder the NO adsorption by blocking the adsorption sites and shift the nitrate formation to higher temperatures. The quantities and thermal stability of the nitrates formed during NO and NO/O₂ adsorption differs which points to a different mechanism of nitrate formation. In the absence of gaseous oxygen, nitrates are formed by participation of only lattice oxygen. In the presence of oxygen, nitrate formation by dimerisation and disproportionation reactions of NO₂ dominates. The manganese component of the composite catalyst supports the oxidation of NO to nitrite and subsequently to nitrate. During this process Mn⁴⁺ is reduced to Mn²⁺ as evidenced by in situ EPR measurements.     

Neue Berechnungsformel für das IT von Walzprofilen und Berechnung der Schubspannungen

A new formula for the I_T of hot‐rolled I‐sections and the determination of the shear stresses. In this paper a new formula for hot‐rolled I‐sections and the determination of the torsional cross‐section property I_T is presented. The results of the new formula are more precise than the ones specified previously. In addition, a method to determine the maximum shear stresses in hot‐rolled profiles is presented.