全文获取类型
收费全文 | 5374篇 |
免费 | 261篇 |
国内免费 | 8篇 |
专业分类
电工技术 | 41篇 |
综合类 | 7篇 |
化学工业 | 1052篇 |
金属工艺 | 92篇 |
机械仪表 | 111篇 |
建筑科学 | 204篇 |
矿业工程 | 15篇 |
能源动力 | 84篇 |
轻工业 | 541篇 |
水利工程 | 29篇 |
石油天然气 | 2篇 |
无线电 | 345篇 |
一般工业技术 | 942篇 |
冶金工业 | 1479篇 |
原子能技术 | 21篇 |
自动化技术 | 678篇 |
出版年
2023年 | 40篇 |
2022年 | 52篇 |
2021年 | 104篇 |
2020年 | 87篇 |
2019年 | 73篇 |
2018年 | 181篇 |
2017年 | 174篇 |
2016年 | 190篇 |
2015年 | 136篇 |
2014年 | 146篇 |
2013年 | 362篇 |
2012年 | 326篇 |
2011年 | 314篇 |
2010年 | 223篇 |
2009年 | 190篇 |
2008年 | 246篇 |
2007年 | 194篇 |
2006年 | 167篇 |
2005年 | 155篇 |
2004年 | 100篇 |
2003年 | 103篇 |
2002年 | 85篇 |
2001年 | 69篇 |
2000年 | 89篇 |
1999年 | 79篇 |
1998年 | 488篇 |
1997年 | 276篇 |
1996年 | 182篇 |
1995年 | 104篇 |
1994年 | 92篇 |
1993年 | 94篇 |
1992年 | 21篇 |
1991年 | 36篇 |
1990年 | 19篇 |
1989年 | 30篇 |
1988年 | 27篇 |
1987年 | 23篇 |
1986年 | 17篇 |
1985年 | 29篇 |
1984年 | 19篇 |
1983年 | 19篇 |
1982年 | 28篇 |
1981年 | 32篇 |
1980年 | 20篇 |
1979年 | 16篇 |
1978年 | 19篇 |
1977年 | 42篇 |
1976年 | 41篇 |
1975年 | 16篇 |
1973年 | 11篇 |
排序方式: 共有5643条查询结果,搜索用时 15 毫秒
51.
The intact preen wax esters of the red knot Calidris canutus were studied with gas chromatography/mass spectrometry (GC/MS) and GC/MS/MS. In this latter technique, transitions from the
molecular ion to fragment ions representing the fatty acid moiety of the wax esters were measured, providing additional resolution
to the analysis of wax esters. The C21−C32 wax esters are composed of complex mixtures of hundreds of individual isomers. The odd carbon-numbered wax esters are predominantly
composed of even carbon-numbered n-alcohols (C14, C16, and C18) esterified predominantly with odd carbon-numbered 2-methyl fatty acids (C7, C9, C11, and C13), resulting in relatively simple distributions. The even carbon-numbered wax esters show a far more complex distribution
due to a number of factors: (i) Their n-alcohol moieties are not dominated by even carbon-numbered n-alcohol moieties are not dominated by even carbon-numbered n-alcohols esterified with odd carbon-numbered 2-methyl fatty acids, but odd and even carbon-numbered n-alcohols participate in approximately equal amounts; (ii) odd carbon-numbered methyl-branched alcohols participate abundantly
in these wax ester clusters; and (iii) with increasing molecular weight, various isomers of the 2,6-, 2,8-, and 2,10-dimethyl
branched fatty acids also participate in the even carbon-numbered wax esters. The data demonstrate that there is a clear biosynthetic
control on the wax ester composition although the reasons for the complex chemistry of the waxes are not yet understood. 相似文献
52.
Gilles Barnathan Joseph Mirallès Emile M. Gaydou Nicole Boury-Esnault Jean-Michel Kornprobst 《Lipids》1992,27(10):779-784
The fatty acid composition of phospholipids from the Senegalese spongeCinachyrella alloclada was examined. Two new fatty acids not hitherto found in nature, namely 10,13-octadecadienoic acid and 16-tricosenoic acid,
were identified. 8-Hexadecenoic, 13-nonadecenoic and 5,9,13-trimethyltretradecanoic fatty acids were also found for the first
time in sponges. The latter compound (1.4% of the total fatty acid mixture), an isoprenoid fatty acid, accompanies the major
fatty acid 4,8,12-trimethyltridecanoic acid (19.7%). The monomethyl branched fatty acids (22%) identified include 23-methylpentacosanoic
acid (anteiso-26∶0), not previously observed in sponged. The major long-chain fatty acids encountered were the known 17-tetracosenoic
19-heptacosadienoic and 5,9,23-tricontatrienoic acid. Some sixty fatty acids were identified as methyl esters andN-acyl pyrrolidides by gas chromatography and gas chromatography/mass spectrometry. 相似文献
53.
The ever-increasing amount of solid waste generated by wastewater treatment plants highlights emerging economic and environmental issues. In order to develop new processes producing less sludge, the use of ozone combined with anaerobic digestion was investigated for waste activated sludge treatment. This paper was aimed at evaluating the impact of ozone pretreatment on anaerobic digestion and particularly the enhancement of biogas production. Sludge solubilization was estimated in terms of modification of chemical oxygen demand, solids and nitrogen. Batch anaerobic digestion highlighted the enhancement of ozonated sludge biodegradability. Ozonation led to an increase in biogas production. The ozone dose of 0.15 g O3/g total solids resulted in a considerable increase in the soluble COD ratio from 4% to 37%. This ozone dose achieved the highest increase in biogas production: 2.4 times greater than without chemical pretreatment. 相似文献
54.
Tatjana Rades Chanho Pak Michèle Polisset-Thfoin Ryong Ryoo Jacques Fraissard 《Catalysis Letters》1994,29(1-2):91-103
NaY-supported bimetallic Pt-Pd catalysts have been studied by TEM, TPR and EXAFS. Small, randomly mixed particles are formed in the zeolite cages. When the Pt content is increased, a Pt core structure appears and the dispersion increases. Particle diameters are about 1–2 nm for bimetallic samples. 相似文献
55.
Information diffusion in large-scale networks has been studied to identify the users influence. The influence has been targeted as a key feature either to reach large populations or influencing public opinion. Through the use of micro-blogs, such as Twitter, global influencers have been identified and ranked based on message propagation (retweets). In this paper, a new application is presented, which allows to find first and classify then the local influence on Twitter: who have influenced you and who have been influenced by you. Until now, social structures of tweets’ original authors that have been either retweeted or marked as favourites are unobservable. Throughout this application, these structures can be discovered and they reveal the existence of communities formed by users of similar profile (that are connected among them) interrelated with other similar profile users’ communities. 相似文献
56.
Boris Raymond Gaël Guennebaud Pascal Barla Romain Pacanowski Xavier Granier 《Computer Graphics Forum》2014,33(2):313-321
This paper introduces a system for the direct editing of highlights produced by anisotropic BRDFs, which we call anisotropic highlights. We first provide a comprehensive analysis of the link between the direction of anisotropy and the shape of highlight curves for arbitrary object surfaces. The gained insights provide the required ingredients to infer BRDF orientations from a prescribed highlight tangent field. This amounts to a non‐linear optimization problem, which is solved at interactive framerates during manipulation. Taking inspiration from sculpting software, we provide tools that give the impression of manipulating highlight curves while actually modifying their tangents. Our solver produces desired highlight shapes for a host of lighting environments and anisotropic BRDFs. 相似文献
57.
Romain Fillières Bouchra Benjelloun-Mlayah Michel Delmas 《Journal of the American Oil Chemists' Society》1995,72(4):427-432
High-performance size-exclusion chromatography (HPSEC) was used to evaluate the influence of different variables affecting
the transesterification of rapeseed oil (RSO) with anhydrous ethanol and sodium ethoxide as catalyst. The effect of temperature,
ethanol/RSO molar ratio, catalyst concentration, and time can be interpreted by observing the variations of the reaction medium
composition. HPSEC has made the quantitation of ethyl esters, mono-, di-, and triglycerides and glycerol possible. The best
results for laboratory-scale reactions were obtained at 80°C with a 6:1 molar ratio of EtOH/RSO and 1% of NaOEt by weight
of RSO. 相似文献
58.
The diastereoselective hydrogenation catalyzed by heterogeneous metallic catalysts uses a covalently bound chiral auxiliary to induce the chirality. It remains an active synthetic methodology in the asymmetric synthesis of chiral products and may proceed with high diastereoselectivity. This review describes recent examples using this method, such as hydrogenation of C=C, C=O, and C=N bonds. The use of a chiral auxiliary group has also been successfully applied to the hydrogenation of aromatic and heteroaromatic rings. The choice of the chiral auxiliary was found to play a key role in the asymmetric hydrogenation. The results could be explained in terms of steric effect, with a preferred conformation of the adduct substrate and the addition occurring from the less bulky side. The catalytic metal, the support and the presence of additives were also found to have a significant influence. 相似文献
59.
Cecilia R. Lederhos Pablo C. L’Argentière Fernando Coloma-Pascual Nora S. Fígoli 《Catalysis Letters》2006,110(1-2):23-28
The 1-heptyne selective hydrogenation carried out at 150 kPa, and at 283 and 303 K using Ru/Al2O3 and Ru/C as catalysts, was studied. Catalysts were prepared by the incipient wetness impregnation technique using RuCl3 as precursor. Ru/Al2O3 was treated in hydrogen at 373 or 573 K and Ru/C only at the last temperature. Catalysts were characterized by hydrogen chemisorption,
TPR and XPS. Ru dispersion after treatment in hydrogen at the highest temperature is similar for both catalysts. Ru is present
as Ru0 in Ru/C, while Ru0 and Ru electron-deficient species are present on the catalysts surface after hydrogen treatment at the two temperatures using
Al2O3 as support. The best catalytic behavior was observed for the highest temperature of hydrogen treatment and for 303 K reaction
temperature. As a consequence of a shape selectivity effect of the C support, the best conversion is obtained with the alumina
supported catalyst. 相似文献
60.
Interaction between dietary protein and fat in triglyceride metabolism in the rat: Effects of soy protein and menhaden oil 总被引:4,自引:0,他引:4
The objective of the present study was to determine the mechanisms by which dietary proteins interact with dietary lipids
in the regulation of triglyceridemia in rats. Male Sprague-Dawley rats (n=56) were subjected to 28-d experimental diets containing different combinations of proteins (20% w/w) and lipid sources (14%
w/w): (i) casein-menhaden oil, (ii) casein-beef tallow, (iii) soy protein-menhaden oil, and (iv) soy protein-beef tallow.
Significant protein-lipid interactions were observed on triglyceridemia and hepatic cholesterol in fasted rats. The combination
of casein and beef tallow was associated with high plasma TG and hepatic cholesterol concentrations, which were reduced by
substitution either of soy for casein or of menhaden oil for beef tallow. Therefore, triglyceridemia and liver cholesterol
remained low with soy protein feeding, independently of the lipid source, as well as with menhaden oil feeding, regardless
of the protein source. The menhaden oil diets reduced plasma cholesterol, hepatic TG, and TG secretion compared with beef
tallow diets independently of the dietary protein source. Modifying the source of dietary proteins and lipids had no effect
on post-heparin plasma lipoprotein lipase activity. These results demonstrate that soy protein can lower rat triglyceridemia
relative to casein when associated with beef tallow consumption, whereas menhaden oil can attenuate hypertriglyceridemia when
rats are fed casein. The data further suggest that part of the hypotriglyceridemic effect of soy protein in the rat may be
mediated by reduced hepatic lipid synthesis, as is the case for menhaden oil. 相似文献