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101.
Martino Di Serio Riccardo Tesser Vincenzo Russo Rosa Turco Rosa Vitiello Yongqiang Sun Wiesław Hreczuch 《Journal of surfactants and detergents》2015,18(5):913-918
The intermediates for the production of nonionic surfactants can be derived from petrochemicals and/or from renewable raw materials. In both, the role of catalysis is fundamental. In this paper the main results reported in the literature related with the catalysis for ethoxylation of fatty esters will be reviewed. The main open challenges for these technologies will be outlined. 相似文献
102.
A new thermoset for separation of polystyrene and naphthalene in preparative chromatography 下载免费PDF全文
Many research groups in recent years have demonstrated the importance of obtaining new materials and reducing environmental impact. In this context, the chemical modification of cellulose and its derivatives has received much attention. This study synthesized cellulose acetate gel (CAMDIH) obtained through the modification of cellulose acetate (CA) with a degree of substitution of 2.5, by crosslinking reactions using 4,4′‐diphenylmethane diisocyanate in homogeneous medium. The formation of crosslinks were observed by the presence of Fourier transform infrared spectroscopy absorption bands at 3046 and 864 cm?1, which correspond to the absorption of aromatic groups associated with the incorporation of 4,4′‐diphenylmethane diisocyanate in the CA structure. The potential applications of the gel as a stationary phase were tested using column chromatography in the fractionation and separation of standard solutions of polystyrene and naphthalene. The findings showed the effectiveness of the gel as a stationary state in the separation of mixture compounds. Furthermore, the study found that CAMDHI is an innovative material when considering its simple synthesis and the low costs involved in the process. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46063. 相似文献
103.
To determine pseudopterosin composition and concentration in colonies of Pseudopterogorgia elisabethae from the islands of San Andres and Providencia, we collected fragments of individual colonies at various sites and depth ranges around the islands. Chromatographic profiles of the polar fraction, particularly those obtained by HPLC-MS analyses, allowed us to recognize two different chemotypes. Chemotype 1 characterized samples from Providencia whereas chemotype 2 characterized samples from San Andres. A complex pseudopterosin mixture (compounds 1-13) characterized chemotype 1. These compounds were isolated by a combination of chromatographic methods and identified by spectroscopic methods (MS, UV, 1H, and 13C NMR). We identified the known pseudopterosins G and K and seco-pseudopterosin A. We also isolated and identified seven new compounds, pseudopterosins P-V, isomers of known pseudopterosins. Pseudopterosins G and K were found at concentrations ranging between 1 and 3% of the animal dry mass. Pseudopterosins Q and U were the major compounds reaching up to 6% of the animal dry mass at some locations. Major metabolites in chemotype 2 had a molecular weight and fragmentation pattern different from that observed in the pseudopterosins, as determined by HPLC-MS. Total pseudopterosin concentration in this chemotype was below 3% dry mass at all sites. Total pseudopterosin concentration was significantly higher in chemotype 1, with concentrations ranging between 4 and 20% dry mass. At most locations on Providencia, however, total pseudopterosin concentration ranged between 11 and 15% dry mass. Concentrations exceed reports from other locations in the Caribbean. Furthermore, pseudopterosin composition in our samples is quite different from those in specimens of P. elisabethae from the Bahamas and Bermuda. Pseudopterosins G, K, and P-V are characteristic of P. elisabethae colonies from the island of Providencia, while pseudopterosins A-D are characteristic of colonies of P. elisabethae from the Bahamas islands, and pseudopterosins E-L have been isolated from P. elisabethae from the Bahamas and Bermuda. The overall morphology of P. elisabethae can be variable, and chemical differences are not correlated to specific morphs. We confirmed the species identity of each colony by morphological and sclerite analysis and found no significant differences in sclerite dimensions among different colonies and chemotypes. 相似文献
104.
Catalysts based in cerium oxide for wet oxidation of acrylic acid in the prevention of environmental risks 总被引:3,自引:0,他引:3
Adrin M. T. Silva Rita R. N. Marques Rosa M. Quinta-Ferreira 《Applied catalysis. B, Environmental》2004,47(4):269-279
Acrylic acid is a refractory compound for the non-catalytic wet oxidation (WO) process and can seriously damage the environment when released in industrial effluents. Oxidation of acrylic acid by catalytic wet oxidation (CWO) was studied in slurry conditions in a high-pressure batch reactor at 200 °C and 15 bar of oxygen partial pressure. Several solid cerium-based catalysts prepared in our laboratory were used (Ag/Ce, Co/Ce, Mn/Ce, CeO, MnO) and evaluated in terms of activity, selectivity and stability. Mn/Ce shows the higher activity in 2 h with 97.7% reduction of total organic carbon (TOC) followed by: MnO(95.5%)>Ag/Ce(85.0%)>Co/Ce(65.1%)>CeO(61.2%). Attempts were also carried out to analyze the influence of different Mn/Ce molar ratios. High percentages of Mn lead to practically total organic carbon concentration (TOC) abatements while low ratios lead to the formation of non-oxidizable compounds. Acrylic acid was readily degraded by all the catalysts pointing out the high importance of using a catalytic process. pH was an indicator of the reaction pathway and acetic acid was found as the major reaction intermediate compound; however it is completely oxidized after 2 h with exception for Co/Ce, CeO and MnO. Carbon adsorption and leaching of metals were poorly found for Mn/Ce indicating high stability. The catalyst microstructure after the reaction was analyzed and formation of whiskers of β-MnO2 (or less probably MnOOH) were observed at the catalyst surface. Therefore, Mn/Ce revealed to be a promising catalyst for the treatment of effluents containing acrylic acid; nevertheless, its commercialization depends on further research. 相似文献
105.
D. S. Rosa I. Chiovatto Neto M. R. Calil A. G. Pedroso C. P. Fonseca S. Neves 《应用聚合物科学杂志》2004,91(6):3909-3914
The thermal and mechanical properties of low‐density polyethylene (LDPE), poly(ε‐caprolactone) (PCL), and their blends were evaluated. Differential scanning calorimetry showed that increasing the PCL content of the blend did not change the LDPE melting temperature, but reduced the crystallinity by up to 16.8%. This behavior was related to interactions between the PCL chains and the crystalline phase of LDPE. Tensile strength and elongation at break values for the blends were lower than those for the pure polymers, which suggested an incompatibility between the polymers. The values for Young's modulus under tensile increased when PCL was added to LDPE. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91:3909–3914, 2004 相似文献
106.
Selective hydrogenation of cinnamaldehyde using Pd catalysts supported on Mg/Al mixed oxides: Influence of the Pd incorporation method 下载免费PDF全文
María J. Martínez‐Ortiz Miguel A. de la Rosa‐Guzmán Jorge R. Vargas‐García Jorge L. Flores‐Moreno Nancy Castillo Ariel Guzmán‐Vargas Sara Morandi Rosa M. Pérez‐Gutiérrez 《加拿大化工杂志》2018,96(1):297-306
A series of hydrotalcite‐like compounds was synthesized by varying Mg/Al molar ratio with values of 2, 3, and 4. After thermal treatment at 823 K, the corresponding mixed oxides were obtained and used as catalytic supports. The incorporation of a Pd metallic phase (0.5 g/g loading), was carried out by two methods: 1) in situ vapour phase thermal decomposition, and 2) impregnation by organic method. Fresh and calcined samples were characterized by XRD and N2 sorption experiments. The basic and metal functions were analyzed by CO2‐TPD and H2‐TPR. The Pd‐support interaction was studied by FTIR spectroscopy using CO as a probe molecule while the morphology of Pd nanoparticles on the catalysts was studied by SEM, HRTEM, and theoretical simulation using the Fast Fourier Transform (FFT) method. Finally, the catalytic activity results showed a higher conversion towards hydrocinnamaldehyde in the cinnamaldehyde hydrogenation reaction for the catalysts prepared by vapour phase thermal decomposition, compared with those prepared by organic method, showing the significant dependence on the catalytic activity and the Pd incorporation method. 相似文献
107.
The methanolic extract of the marine sponge Ircinia felix has yielded nine novel fatty acid esters, (7E, 12E, 18R, 20Z)-variabilin (5Z, 9Z)-22-methyltricosadienoate, (7E, 12E, 18R, 20Z)-variabilin (5Z, 9Z)-tetracosadienoate, (7E, 12E, 18R, 20Z)-variabilin hexadecanoate, (7E, 12E, 18R, 20Z)-variabilin 10-methylhexadecanoate, (7E, 12E, 18R, 20Z)-variabilin 15-methylhexadecanoate, (7E, 12E, 18R, 20Z)-variabilin 14-methylhexadecanoate, (7E, 12E, 18R, 20Z)-variabilin 9-octadecenoate, (7E, 12E, 18R, 20Z)-variabilin octadecanoate, and (7E, 12E, 18R, 20Z)-variabilin 2,11-dimethyloctadecanoate, along with the recently described (7E, 12E, 18R, 20Z)-variabilin 11-methyloctadecanoate. The characterization of the new fatty acids (5Z, 9Z)-22-methyltricosadienoic and 2,11-dimethyloctadecanoic acids is also described. The chemical structures were determined by
extensive spectroscopic, chromatographic, and chemical analyses. 相似文献
108.
109.
Natural compounds and vegetable powders improve the stability and antioxidant properties of Brassica napus L. var. oleifera (rapeseed) oil 下载免费PDF全文
110.
Adriana Dillenburg Meinhart Tayse Ferreira Ferreira da Silveira Mateus Henrique Petrarca Leonardo Henrique Silva Maria Rosa de Moraes Cristiano Augusto Ballus Patrícia Oliveira de Souza Thais Cristina Lima de Souza Roger Wagner Helena Maria André Bolini Roy Edward Bruns Helena Teixeira Godoy 《European Journal of Lipid Science and Technology》2017,119(10)