Effect of the fabrication method on the electrical properties of poly(acrylonitrile-co-butadiene-co-styrene)/carbon black composites

Poly(acrylonitrile-co-butadiene-co-styrene) (ABS), an engineering plastic, was combined with carbon black (CB) to increase its conductivity. The ABS/CB composites were prepared using two different methods: dissolution of ABS in Butan-2-one and manual mixing of the constituent materials. These fabrication methods led to different microstructures, which led to vastly different electrical properties. The microstructures were acquired using scanning electron microscopy (SEM) and optical microscopy, while the electrical conductivity was obtained using impedance spectroscopy. The percolation threshold of the composites fabricated using the manual mixing method was found to be much lower (0.0054 vol.% CB) than that of the composites fabricated using the dissolution method (2.7 vol.% CB).     

Securing Threshold Cryptosystems against Chosen Ciphertext Attack

For the most compelling applications of threshold cryptosystems, security against chosen cipher text attack is a requirement. However, prior to the results presented here, there appeared to be no practical threshold cryptosystems in the literature that were provably chosen ciphertext secure, even in the idealized random oracle model. The contribution of this paper is to present two very practical threshold cryptosystems, and to prove that they are secure against chosen ciphertext attack in the random oracle model. Not only are these protocols computationally very efficient, but they are also non-interactive, which means they can be easily run over an asynchronous communication network. Received November 2000 and revised September 2001 Online publication 11 March 2002     

Free fatty acids and oxidative changes of a raw goat milk cheese through maturation

Free fatty acids (FFA) and lipid and protein oxidation changes were studied throughout maturation process of a raw goat milk cheese with protected designation of origin. Cheeses were analyzed at 4 different times of maturation, at 1, 30, 60, and 90 d. All FFA significantly increased during maturation and the relative increase was higher for long-chain than medium- or short-chain FFA. At the end of maturation, oleic (C18:1 n9), butyric (C4:0), and palmitic (C16:0) acids were the most abundant. The higher levels of short-chain fatty acids (SCFA) regarding total FFA obtained at the end of Ibores cheese ripening compared with other raw goat milk cheeses, highlight the notable role of SCFA on the flavor of this cheese owing to their low-odor thresholds. Lipid oxidation values significantly increased during maturation process but low levels of malondialdehyde were reported; however, protein oxidation did not significantly change during ripening.     

Development and experimental validation of a simulation model for open joint ventilated façades

The investigation of the thermal and fluid dynamical behaviour of open joint ventilated façades is a challenging task due to the complex airflows generated inside of the naturally ventilated cavity by the existence of open joints. For this reason, the use of advanced fluid measurement and simulation techniques is highly recommended. This paper focuses in the development and experimental validation of a simulation model for these façade systems. More specifically, different turbulence and radiation models available in the commercial computational fluid dynamic codes have been tested on a three-dimensional model and the results have been compared to particle image velocimetry measurements. The correlation between experimental and numerical data has been used in order to select the simulation procedure for this type of façades. Best fittings have been found when using the RNG k-epsilon turbulence model and the Discrete Ordinate radiation model. Using the selected scheme, parametrical simulations have been performed to investigate the effect of increasing the cavity height, and correspondingly, the number of slabs. Results show that ventilation air flow inside the cavity is enhanced by incident radiation as well as by the height of the façade.     

Interaction between the peptide glutathione and linoleic acid hydroperoxide

Incubation experiments in order to study the influence of some parameters in the fluorescence products formation have been carried out. It has been observed a greater efficiency with the relation linoleic acid hydroperoxide:glutathione, 2:1, and a temperature of 37 °C. The complex formed working with labelled linoleic acid has been separated in two main fractions. The first one (without radioactivity) is fluorescent with excitation and emission maxima at 350 nm and 440 nm, respectively. It has been confirmed that this fraction consists of a complex of glutathione and short chain aldehydes. The fluorescence of the complex did not decrease by treatment with NaBH₄ or with pH. The NH₂ and SH groups take part in the lipid-peptide complex formation. The second, highly radioactive fraction includes free hydroperoxides and short chain hydroxy fatty acids.     

Thermal and viscoelastic behaviour of copolymers of propene and 1-hexene

Summary The thermal and viscoelastic behaviour of several copolymers of propene and 1-hexene have been studied in a wide range of compositions. The samples were prepared with a Ziegler-Natta catalyst with both internal and external donors. A significant amount of crystallinity has been found for the sample with a comonomer content as high as 19 mol %. The dynamic mechanical results show a considerable decrease of the storage modulus in the copolymers in relation to that of iPP. A single relaxation, corresponding to the glass transition, has been found in all the samples. Only the copolymer with the highest hexene content seems to display the beginning of another relaxation at low temperature.     

Prevalence, course, and predictors of multiple problem behaviors among gay and bisexual male adolescents.

Multiple problem behaviors, stress, and personal resources were assessed over 2 yrs among 136 mainly Black and Hispanic gay and bisexual male adolescents (aged 14–19 yrs). Whereas sexual risk acts, substance abuse, conduct problems, and emotional distress were common, the risk acts did not form a multiple problem behavior cluster, compared with previous findings with heterosexual youths. Problem behaviors were stable over time: Only 20–30% of the youths changed their pattern of problem behaviors over 2 yrs. For each individual, the pattern of change in one behavior problem was not related to patterns of change in other problem behaviors over 2 yrs. At baseline, personal resources were associated with less alcohol use and emotional distress, and stress was associated with delinquent behaviors. The pattern of results was similar whether youths labeled themselves as gay or bisexual, suggesting that problem behaviors among mainly Black and Hispanic gay and bisexual youths may follow different developmental pathways than among heterosexual youths. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Synthesis and characterization of vinyl ester networks containing phthalonitrile moieties

A new styrenic monomer, 4-vinylphenoxyphthalonitrile, was synthesized by nucleophilic aromatic substitution of 4-vinylphenolate onto 4-nitrophthalonitrile. The new monomer was reacted with dimethacrylate-styrene resins (so-called vinyl esters) via free radical copolymerization at 90, then 120 °C with benzoyl peroxide as the initiator to form networks. The networks were further post-cured at 220, 240, or 260 °C for 4 h to convert the last portion of the methacrylates, and to partially cross-link the pendent phthalonitrile groups. A dimethacrylate-styrene network containing 30 wt% of the phthalonitrile-functional monomer exhibited a 70% reduction in peak heat release rate by cone calorimetry measured at an incident heat flux of 50 kW m⁻² relative to control vinyl ester networks. This still remains somewhat higher than peak heat release rates exhibited by brominated vinyl ester networks, but the CO/CO₂ ratio in the smoke is much lower for these non-halogenated materials.     

Synthesis,characterization, and degradation of block polyesteramides containing poly(L-lactide) segments

Random multiblock polyesteramides (PEAs) having polyester (PE) content of 20–50 wt % have been prepared by low-temperature polycondensation using sebacoyl chloride, 1,6-diaminohexane, and telechelic oligomers of L-lactide with M_n = 600–1500. The PEAs were characterized by IR and ¹H-NMR spectroscopy, wide-angle X-ray diffraction, and thermal analysis. Only the polyamide segments are able to crystallize, and the crystallinity depends on the composition and architecture of the PEAs. From viscosity and IR measurements it was established that the chain degradation of PEA powders or films suspended in buffer solutions occurs by hydrolysis of the ester linkages. The degradation rate is influenced by pH, PE content, and, to a lesser extent, by crystallinity. © 1992 John Wiley & Sons, Inc.