Prolong network lifetime and improve efficiency in WSN‐UAV systems using new clustering parameters and CSMA modification

Since unmanned aerial vehicles (UAVs) have been introduced as mobile nodes for data gathering, wireless sensor networks (WSNs) have progressed considerably. The resulting WSN‐UAV systems are employed for emergency applications and also for remote monitoring purposes. WSN‐UAV systems yield an optimum data gathering method using the WSN. In the proposed method, the nodes' data are transferred using a remotely operated vehicle (drone) rather than the conventional data transferring methods like the direct and hop‐to‐hop data transmission approaches. Then, the gathered data are delivered in the pre‐determined destination point. WSN‐UAV systems, in fact, are a special case of the systems with the mobile sink in which the sink path is previously specified and controlled. In this paper, the effects of clustering parameters on the WSNs are studied; then, the network's lifetime is prolonged by applying some parameters. In addition, the network's performance is enhanced to some extent by assigning some changes in the media access control (MAC) layer. Also, the effect of drone's path pattern on the lifetime of the network is studied.     

High‐Performance Graphene‐Fiber‐Based Neural Recording Microelectrodes

Fabrication of flexible and free‐standing graphene‐fiber‐ (GF‐) based microelectrode arrays with a thin platinum coating, acting as a current collector, results in a structure with low impedance, high surface area, and excellent electrochemical properties. This modification results in a strong synergistic effect between these two constituents leading to a robust and superior hybrid material with better performance than either graphene electrodes or Pt electrodes. The low impedance and porous structure of the GF results in an unrivalled charge injection capacity of 10.34 mC cm^?2 with the ability to record and detect neuronal activity. Furthermore, the thin Pt layer transfers the collected signals along the microelectrode efficiently. In vivo studies show that microelectrodes implanted in the rat cerebral cortex can detect neuronal activity with remarkably high signal‐to‐noise ratio (SNR) of 9.2 dB in an area as small as an individual neuron.     

Incompressible SPH modeling and analysis of non-Newtonian power-law fluids,mixing in a microchannel with an oscillating stirrer

In the present study, a robust Incompressible smoothed particle hydrodynamics (ISPH) method, based on an advanced Smoothed particle hydrodynamics (SPH) discretization, is introduced to study the effects of the non-Newtonian power-law index and stirrer frequency on fluid mixing in an active micromixer that uses an oscillating stir-bar. Two Reynolds numbers (20 and 72) are considered, and more than 70 SPH simulations are carried out, in order to investigate the effects of the power-law index and stirrer frequency on fluid mixing. The results show that this active micromixer is more efficient at the lower power-law indices.     

Combination of In Situ Surfactant-based Solid Phase Extraction and Central Composite Design for Preconcentration and Determination of Manganese in Food and Water Samples

A new kind of solid phase extraction (SPE), which we named in situ surfactant-based solid phase extraction (ISS-SPE), represents a simple, selective and rapid method for preconcentration and determination of manganese from food and water samples. This method has distinct advantages: extraction times are short and recoveries are high; further, we can see formation of fine particles of large specific surface and their good dispersion in the solution. In this work, a small amount of cationic surfactant, n-dodecyltrimethylammonium bromide (DTAB) was injected into the water sample containing Mn ions, which were complexed by 1-(2-pyridylazo)-2-naphthol (PAN). After shaking, a little volume of NaPF₆ as an ion-pairing agent was added into the solution by a microsyringe. After preconcentration, the settled phase was dissolved in a specific volume of ethanol and then aspirated into the flame atomic absorption spectrometer by using a homemade microsample introduction system. The effective parameters such as pH, concentration of surfactant, concentration of chelating agent, concentration of ion-pairing agent and effect of salt concentration were optimized by a fractional factorial design to identify the most important parameters and their interactions, and central composite methodology was used to achieve the optimum point of effective parameters to the response. Under the optimum conditions, preconcentration of 10?ml of the sample solution permitted detection of 0.88???g?l^?1 with enhancement factor of 45.6, and the relative standard deviation (RSD) for five determinations of Mn ions was 3.5%. The developed method was applied to the determination of trace manganese in various real samples with satisfactory results.     

Viscoelastic nature of calcium silicate hydrate

The origin of the time-dependent response of cement-based materials to applied stress has not been clearly resolved. The role of interlayer water in the mechanical behavior of calcium silicate hydrate (C–S–H) is still debated. In order to better understand the pertinent mechanisms, the stress relaxation tests were conducted on thin rectangular beams of compacted synthetic C–S–H powder and hydrated Portland cement subjected to three-point bending. C–S–H specimens of variable composition (C/S = 0.8, 1.2 and 1.5) were prepared at various moisture content levels from saturation to the dry state. A special drying procedure was applied in order to remove the adsorbed and interlayer water incrementally from C–S–H conditioned at 11%RH. It was shown that a significant part of the relaxation at saturation is attributed to the hydrodynamic component associated with the pore water. It was demonstrated that the viscoelastic performance of C–S–H depends considerably on the presence of interlayer water. It was argued that the results support the validity of the theory of sliding of C–S–H sheets as a time-dependent deformation mechanism responsible for the creep and stress relaxation of cement-based materials. This concept was illustrated in a proposed model for the viscoelastic response of C–S–H.     

Three‐Dimensional Printing of Multifunctional Nanocomposites: Manufacturing Techniques and Applications

The integration of nanotechnology into three‐dimensional printing (3DP) offers huge potential and opportunities for the manufacturing of 3D engineered materials exhibiting optimized properties and multifunctionality. The literature relating to different 3DP techniques used to fabricate 3D structures at the macro‐ and microscale made of nanocomposite materials is reviewed here. The current state‐of‐the‐art fabrication methods, their main characteristics (e.g., resolutions, advantages, limitations), the process parameters, and materials requirements are discussed. A comprehensive review is carried out on the use of metal‐ and carbon‐based nanomaterials incorporated into polymers or hydrogels for the manufacturing of 3D structures, mostly at the microscale, using different 3D‐printing techniques. Several methods, including but not limited to micro‐stereolithography, extrusion‐based direct‐write technologies, inkjet‐printing techniques, and popular powder‐bed technology, are discussed. Various examples of 3D nanocomposite macro‐ and microstructures manufactured using different 3D‐printing technologies for a wide range of domains such as microelectromechanical systems (MEMS), lab‐on‐a‐chip, microfluidics, engineered materials and composites, microelectronics, tissue engineering, and biosystems are reviewed. Parallel advances on materials and techniques are still required in order to employ the full potential of 3D printing of multifunctional nanocomposites.     

Self‐Assembly of Flexible Free‐Standing 3D Porous MoS2‐Reduced Graphene Oxide Structure for High‐Performance Lithium‐Ion Batteries

Flexible freestanding electrodes are highly desired to realize wearable/flexible batteries as required for the design and production of flexible electronic devices. Here, the excellent electrochemical performance and inherent flexibility of atomically thin 2D MoS₂ along with the self‐assembly properties of liquid crystalline graphene oxide (LCGO) dispersion are exploited to fabricate a porous anode for high‐performance lithium ion batteries. Flexible, free‐standing MoS₂–reduced graphene oxide (MG) film with a 3D porous structure is fabricated via a facile spontaneous self‐assembly process and subsequent freeze‐drying. This is the first report of a one‐pot self‐assembly, gelation, and subsequent reduction of MoS₂/LCGO composite to form a flexible, high performance electrode for charge storage. The gelation process occurs directly in the mixed dispersion of MoS₂ and LCGO nanosheets at a low temperature (70 °C) and normal atmosphere (1 atm). The MG film with 75 wt% of MoS₂ exhibits a high reversible capacity of 800 mAh g^?1 at a current density of 100 mA g^?1. It also demonstrates excellent rate capability, and excellent cycling stability with no capacity drop over 500 charge/discharge cycles at a current density of 400 mA g^?1.