Review: current international research into cellulose nanofibres and nanocomposites

This paper provides an overview of recent progress made in the area of cellulose nanofibre-based nanocomposites. An introduction into the methods used to isolate cellulose nanofibres (nanowhiskers, nanofibrils) is given, with details of their structure. Following this, the article is split into sections dealing with processing and characterisation of cellulose nanocomposites and new developments in the area, with particular emphasis on applications. The types of cellulose nanofibres covered are those extracted from plants by acid hydrolysis (nanowhiskers), mechanical treatment and those that occur naturally (tunicate nanowhiskers) or under culturing conditions (bacterial cellulose nanofibrils). Research highlighted in the article are the use of cellulose nanowhiskers for shape memory nanocomposites, analysis of the interfacial properties of cellulose nanowhisker and nanofibril-based composites using Raman spectroscopy, switchable interfaces that mimic sea cucumbers, polymerisation from the surface of cellulose nanowhiskers by atom transfer radical polymerisation and ring opening polymerisation, and methods to analyse the dispersion of nanowhiskers. The applications and new advances covered in this review are the use of cellulose nanofibres to reinforce adhesives, to make optically transparent paper for electronic displays, to create DNA-hybrid materials, to generate hierarchical composites and for use in foams, aerogels and starch nanocomposites and the use of all-cellulose nanocomposites for enhanced coupling between matrix and fibre. A comprehensive coverage of the literature is given and some suggestions on where the field is likely to advance in the future are discussed.     

Exhaust Gas Recirculation Cooler Fouling in Diesel Applications: Fundamental Studies of Deposit Properties and Microstructure

This article reports on the results of experimental efforts aimed at improving the understanding of the mechanisms and conditions at play in the fouling of exhaust gas recirculation coolers. An experimental apparatus was constructed to utilize simplified surrogate heat exchanger tubes in lieu of full-size heat exchangers. The use of these surrogate tubes allowed removal of the tubes after exposure to engine exhaust for study of the deposit layer and its properties. The exhaust used for fouling the surrogate tubes was produced using a modern medium-duty diesel engine fueled with both ultra-low-sulfur diesel and biodiesel blends. At long exposure times, no significant difference in the fouling rate was observed between fuel types and hydrocarbons levels. Surface coatings for the tubes were also evaluated to determine their impact on deposit growth. No surface treatment or coating produced a reduction in the fouling rate or any evidence of deposit removal. In addition, microstructural analysis of the fouling layers was performed using optical and electron microscopy in order to better understand the deposition mechanism. The experimental results are consistent with thermophoretic deposition for deposit formation, and van der Waals attraction between the deposit surface and exhaust-borne particulate.     

Poly(vinylidene fluoride)/halloysite nanotubes nanocomposites: The structures,properties, and tensile fracture behaviors

Poly(vinylidene fluoride)/halloysite nanotubes (HNTs) nanocomposites with good dispersion were prepared. The effect of HNTs on the crystalline structure, dynamic rheological properties, dynamic mechanical properties, and tensile properties was investigated. Results showed that at low concentration, the effect of HNTs on the modulus was minor. However, at high concentration, improvement of the modulus can be observed. The tensile fracture behaviors were investigated, which showed that the addition of HNTs changed the fracture mode. When the concentration of HNTs was 20 phr, a fracture mode change from microductility/brittle to brittle/fibrillation occurred. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Flow Visualization in a Pocketed Thrust Washer

The objectives of this study were to experimentally and numerically investigate oil flow in surface-pocketed thrust washers. In order to achieve the experimental aspects of this investigation, a thrust washer test rig was designed and developed to visualize the lubricant flow at the contact interface. A novel approach for creating the pockets was developed to allow optical inspection of the lubricant during thrust washer operation. The thrust washers were fabricated using a glass disk with a thin layer of steel shim stock adhered to the surface. The micrometer-thick shim stock was machined using an Nd:YAG laser to create the circular pocket geometries and then glued to the glass disk. A mirror and camera were placed below the semitransparent washer to observe the lubricant flow in the pocket. The results obtained from this configuration illustrate a cavitation bubble forming on the leading edge of the pocket followed by a sharp transition back to liquid. The size of the cavitation area was found to be a function of rotational speed, nominal bearing pressure (NBP), viscosity, and pocket geometry. The cavitation area ratio (gaseous region divided by the pocket area) increased for greater speeds and higher viscosities and decreased for larger pocket diameters, deeper pockets, and higher NBPs. The friction force for various thrust washer designs was also measured as a function of load, speed, and lubricant. The results showed that shallower, wider pockets provided the lowest friction. It was found that, generally, the conditions that minimize friction also result in a stable cavitation region. ANSYS Fluent computational fluid dynamics software was used to develop a three-dimensional model of the pocketed thrust washer utilizing the full Navier-Stokes equations to investigate the cavitation and pressure distribution occurring at the contact and corroborate the experimental results.     

Effect of Alloy Composition on Carburizing Performance of Steel

This paper investigates the effect of alloy composition on the gas carburizing performance of AISI 1018, 4820, 5120, and 8620 steels. The mass-transfer coefficients and carbon diffusivities were calculated from experimental measurements using direct flux integration. Although steels with high concentration of austenite-stabilizing elements (Si, Ni) increased carbon diffusivity in austenite, they significantly reduced the kinetics of carbon transfer from the atmosphere to the steel surface and resulted in lower weight gain. Despite lowering the carbon diffusivities, steels alloyed with carbide-forming elements (Cr, Mo) significantly increased the mass-transfer coefficient in the atmosphere and enhanced the rate of carbon profile evolution. The experimentally determined carbon diffusivities were in good agreement with the carbon diffusivities obtained from the thermodynamic and kinetic databases in DICTRA. Overall, using the concentration dependent mass-transfer coefficient and carbon diffusivity in various alloy steels helped explain the experimentally observed variations in the carbon concentration profiles and the effective case depths. Recommendations are made to help achieve better case depth uniformity within a carburizing workload.     

Enclosure size and hormonal state affect timing of nest return in female meadow voles (Microtus pennsylvanicus).

We investigated 2 aspects of the hormonal regulation of maternal behavior in meadow voles (Microtus pennsylvanicus): (a) when the transition in maternal responsiveness from primarily hormonal control to regulation by pup cues occurs; and (b) the effect of housing enclosure size on maternal nest attendance in voles injected with a prolactin suppressant, cysteamine hydrochloride (150 mg/kg) on Postnatal Day 2. In Experiment 1, meadow voles required 96 hr of pup contact to finish the transition from hormonal to pup-mediated maternal behavior; a period longer than found in other rodents. In Experiment 2, females housed in larger enclosures spent less time with pups after drug injection, primarily because they increased the amount of time they stayed away from the nest each time they left. In contrast, drug-treated females in standard cages showed no change in their patterns of nest attendance, possibly due to the presence of salient cues from nearby pups. Under naturalistic conditions, a female vole’s hormonal state may regulate nest approach, and help establish the necessary alternation between leaving the nest (e.g., to forage) and attending pups. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

A complete temporal relational algebra

Various temporal extensions to the relational model have been proposed. All of these, however, deviate significantly from the original relational model. This paper presents a temporal extension of the relational algebra that is not significantly different from the original relational model, yet is at least as expressive as any of the previous approaches. This algebra employs multidimensional tuple time-stamping to capture the complete temporal behavior of data. The basic relational operations are redefined as consistent extensions of the existing operations in a manner that preserves the basic algebraic equivalences of the snapshot (i.e., conventional static) algebra. A new operation, namely temporal projection, is introduced. The complete update semantics are formally specified and aggregate functions are defined. The algebra is closed, and reduces to the snapshot algebra. It is also shown to be at least as expressive as the calculus-based temporal query language TQuel. In order to assess the algebra, it is evaluated using a set of twenty-six criteria proposed in the literature, and compared to existing temporal relational algebras. The proposed algebra appears to satisfy more criteria than any other existing algebra. Edited by Wesley Chu. Received February 1993 / Accepted April 1995     

Use of Zebrafish Embryo Assay to Evaluate Toxicity and Safety of Bioreactor-Grown Exopolysaccharides and Endopolysaccharides from European Ganoderma applanatum Mycelium for Future Aquaculture Applications

Natural mycelial exopolysaccharide (EPS) and endopolysaccharide (ENS) extracted from bioreactor-cultivated European Ganoderma applanatum mushrooms are of potential high commercial value for both food and adjacent biopharmaceutical industries. In order to evaluate their potential toxicity for aquaculture application, both EPS (0.01–10 mg/mL) and ENS (0.01–10 mg/mL) extracts were tested for Zebrafish Embryo Toxicity (ZFET); early development effects on Zebrafish Embryos (ZE) were also analyzed between 24 and 120 h post-fertilization (HPF). Both EPS and ENS are considered non-toxic with LC₅₀ of 1.41 mg/mL and 0.87 mg/mL respectively. Both EPS and ENS did not delay hatching and teratogenic defect towards ZE with <1.0 mg/mL, respectively. No significant changes in the ZE heart rate were detected following treatment with the two compounds tested (EPS: 0.01–10 mg/mL: 176.44 ± 0.77 beats/min and ENS: 0.01–10 mg/mL: 148.44 ± 17.75 beats/min) compared to normal ZE (120–180 beats/min). These initial findings support future pre-clinical trials in adult fish models with view to safely using EPS and ENS as potential feed supplements for supplements for development of the aquaculture industry.     

Partial mediation of strange-male-induced pregnancy blocks by sexual activity in mice (Mus musculus).

Novel male house mice (Mus musculus) can disrupt early pregnancy in females. Previous research (e.g., A. E. Storey; see record 1986-16382-001) focused on pheromonal rather than behavioral mediation of this phenomenon. In Experiment 1, novel males were housed with females shortly after insemination. Litter production was negatively correlated with the males' sexual activity. Experiment 2 replicated this finding with a larger sample. In Experiment 3, females were exposed to castrated males. Testosterone-treated males completely blocked pregnancy, whereas untreated males did not. In Experiment 4, castrated testosterone-treated males were presented at intervals after insemination. Pregnancy was totally blocked at Days 3 and 4 and mostly blocked at Days 1 and 2 but was less affected at Days 5 and 6. In Experiment 5, females were exposed through a wire-mesh grid to castrated males. Pregnancies occurred in all conditions, even with testosterone-treated males. These data suggest a role for sexual activity in male-induced pregnancy blocks. (PsycINFO Database Record (c) 2010 APA, all rights reserved)