The effect of resin/crosslinker ratio on the mechanical properties and fungal deterioration of a maxillofacial silicone elastomer

Variation of the crosslinker/resin ratio of a room temperature condensation cure maxillofacial silicone elastomer has caused considerable changes in the mechanical properties and deterioration by Candida albicans. Increasing the crosslinker/resin ratio caused a decrease in the tensile strength and stiffness of the elastomer. However, tear strength appeared to show an optimum value at the recommended crosslinker/resin ratio. These effects were due to the low molar mass silicone polymer that acts as a carrier for the actual crosslinking additive. The general decrease in mechanical properties was accompanied by an increase in the hexane extractables content and an increase in the Si–H content of the elastomer. The unbound polymer (extractable material) content of the elastomer was found to influence the colonization of the material by C. albicans. An increase in the unbound polymer content corresponded to an increasing number of hyphae and blastospores observed penetrating into the elastomer. The data obtained in this study have significant implications concerning the degree of control of elastomer formulation and the deterioration of maxillofacial appliances.     

The effect of sodium sulfate on solidification/stabilization of a synthetic electroplating sludge in cementitious binders

The effect of sodium sulfate on the solidification/stabilization of a large quantity of a synthetic electroplating sludge in cementitious binders was s     

Atomic layer deposition of transition metals

Atomic layer deposition (ALD) is a process for depositing highly uniform and conformal thin films by alternating exposures of a surface to vapours of two chemical reactants. ALD processes have been successfully demonstrated for many metal compounds, but for only very few pure metals. Here we demonstrate processes for the ALD of transition metals including copper, cobalt, iron and nickel. Homoleptic N,N'-dialkylacetamidinato metal compounds and molecular hydrogen gas were used as the reactants. Their surface reactions were found to be complementary and self-limiting, thus providing highly uniform thicknesses and conformal coating of long, narrow holes. We propose that these ALD layers grow by a hydrogenation mechanism that should also operate during the ALD of many other metals. The use of water vapour in place of hydrogen gas gives highly uniform, conformal films of metal oxides, including lanthanum oxide. These processes should permit the improved production of many devices for which the ALD process has previously not been applicable.     

Labour‐intensive and capital‐intensive technology in irrigation development

The need for a rapid expansion in irrigation in India for the purposes of food production is generally accepted. Whether irrigation works can at the same time effectively tackle the country's massive rural unemployment problem is the subject of this paper. Basic planning requirements are outline, and then the complex issues surrounding the choice of labour‐intensive or capital‐intensive technology are discussed. Finally, the kinds of data required before informed decisions can be made are specified.     

The aging effect of the thermoelectric power of thin copper films

The thermoelectricpower, referenced to bulk copper, of thin films of copper about 150 Å thick was measured by preparing a thin film bridge between two copper wires which served as leads. This arrangement produces two junctions between the thin film copper and the bulk copper. The two junctions were maintained at a temperature difference which was measured using a calibrated copper-constantan thermocouple. It was found that the thin film-to-bulk thermoelectric power varies with time and can be fitted to an equation of the form

$\text{S = S}{}_{\mathrm{<mtext>F</mtext>}}\text{(1?}\text{e}{}^{\mathrm{-\lambda t}}\text{)}$

where λ depends on temperature. The constant λ in the equation has values very close to those found from thin film resistance aging measurements, suggesting that the same mechanism is responsible for both aging phenomena. The heated junctions is negative, in agreement with a simple electron diffusion model of thermoelectric power.     

2.12 Dielectric dispersion and polarization effects in thin transition metal oxide films

Dielectric properties of thin polycrystalline and amorphous films of NiO, NiO(Li), CoO, CoO(Li), Nb₂O₅ and TiO₂ in the thickness range 0.14–15 ωm were studied as a function of frequency, temperature, applied voltage and dopant concentration in the frequency range 3–10⁸ Hz. These films were prepared either by anodization or thermal oxidation and in some cases by reactive sputtering. Experimental data for the real ?₁ and imaginary ?₂ parts of the dielectric constant, ac conductivity σ(ω) and loss tangent tan δ indicate the existence of several dispersion mechanisms. Cole-Cole plots and the modified Debye relations were used to derive the values for relaxation times at low frequencies. The frequency dependence of σ(ω) in the frequency region 10³–10⁶ Hz where σ(ω)αωⁿ indicates that the dispersion mechanism is due to charge carriers hopping between sites with either correlated or non-correlated potentials. The observed quadratic dependence of σ(ω) on frequency in the frequency region 10⁶–10⁸ Hz is attributed to a Debye type loss resulting from thermally activated hopping. Polarization effects at lower frequencies <10³Hz indicate the existence of Schottky barriers at the metal-insulator interfaces in agreement with Simmons theory of MIM structures.     

Diffraction of shear waves by an edge crack in an elastic wedge

Low frequency diffraction of plane harmonic shear (SH) wave by an edge crack in an elastic wedge of arbitrary vertex angle is studied. Kontorowich-Lebedev transform is used to solve the mixed boundary value problem under consideration. For low frequency case, i.e. wavelength large compared to the length of the crack, the displacement field is obtained by successive approximation of the resulting Wiener-Hopf equation. For the limiting case of an elastic half space the results agree with those obtained by the method of matched asymptotic expansions.     

Frequency invariant classification of ultrasonic weld inspection signals

Automated signal classification systems are finding increasing use in many applications for the analysis and interpretation of large volumes of signals. Such systems show consistency of response and help reduce the effect of variabilities associated with human interpretation. This paper deals with the analysis of ultrasonic NDE signals obtained during weld inspection of piping in boiling water reactors. The overall approach consists of three major steps, namely, frequency invariance, multiresolution analysis, and neural network classification. The data are first preprocessed whereby signals obtained using different transducer center frequencies are transformed to an equivalent reference frequency signal. Discriminatory features are then extracted using a multiresolution analysis technique, namely, the discrete wavelet transform (DWT). The compact feature vector obtained using wavelet analysis is classified using a multilayer perceptron neural network. Two different databases containing weld inspection signals have been used to test the performance of the neural network. Initial results obtained using this approach demonstrate the effectiveness of the frequency invariance processing technique and the DWT analysis method employed for feature extraction.     

Long-pulse narrow-linewidth dispersive solid-state dye-laser oscillator

We report on narrow-linewidth long-pulse laser emission from a dispersive solid-state dye-laser oscillator. Output energy was ~0.4 mJ/pulse at laser linewidths of 650 MHz and pulse lengths of 105 ns FWHM. The solid-state gain medium utilized was Rhodamine 6G dye-doped 2-hydroxyethyl methacrylate:methyl methacrylate.     

All-optical biomolecular parallel logic gates with bacteriorhodopsin

All-optical two input parallel logic gates with bacteriorhodopsin (BR) protein have been designed based on nonlinear intensity-induced excited-state absorption. Amplitude modulation of a continuous wave (CW) probe laser beam transmission at 640 nm corresponding to the peak absorption of O intermediate state through BR, by a modulating CW pump laser beam at 570 nm corresponding to the peak absorption of initial BR state has been analyzed considering all six intermediate states in its photocycle using the rate equation approach. The transmission characteristics have been shown to exhibit a dip, which is sensitive to normalized small-signal absorption coefficient (/spl beta/), rate constants of O and N intermediate states and absorption of the O state at 570 nm. There is an optimum value of /spl beta/ for a given pump intensity range for which maximum modulation can be achieved. It is shown that 100% modulation can be achieved if the initial state of BR does not absorb the probe beam. The results have been used to design low-power all-optical parallel NOT, AND, OR, XNOR, and the universal NAND and NOR logic gates for two cases: 1) only changing the output threshold and 2) considering a common threshold with different /spl beta/ values.