Electrochemically Exfoliated High‐Quality 2H‐MoS2 for Multiflake Thin Film Flexible Biosensors

2D molybdenum disulfide (MoS₂) gives a new inspiration for the field of nanoelectronics, photovoltaics, and sensorics. However, the most common processing technology, e.g., liquid‐phase based scalable exfoliation used for device fabrication, leads to the number of shortcomings that impede their large area production and integration. Major challenges are associated with the small size and low concentration of MoS₂ flakes, as well as insufficient control over their physical properties, e.g., internal heterogeneity of the metallic and semiconducting phases. Here it is demonstrated that large semiconducting MoS₂ sheets (with dimensions up to 50 µm) can be obtained by a facile cathodic exfoliation approach in nonaqueous electrolyte. The synthetic process avoids surface oxidation thus preserving the MoS₂ sheets with intact crystalline structure. It is further demonstrated at the proof‐of‐concept level, a solution‐processed large area (60 × 60 µm) flexible Ebola biosensor, based on a MoS₂ thin film (6 µm thickness) fabricated via restacking of the multiple flakes on the polyimide substrate. The experimental results reveal a low detection limit (in femtomolar–picomolar range) of the fabricated sensor devices. The presented exfoliation method opens up new opportunities for fabrication of large arrays of multifunctional biomedical devices based on novel 2D materials.     

The <Emphasis Type=Italic>j</Emphasis>-index: a new bibliometric index and multivariate comparisons between other common indices

A new bibliometric index is proposed, trying to preserve the advantages of the h-index and to overcome its disadvantages. Multivariate comparisons among 18 bibliometric indices are performed by using Hasse Diagram Technique (HDT) and Principal Component Analysis (PCA). The comparisons were performed on some artificial data sets, three of them well known in literature. The obtained results seems to highlight some interesting properties of the new index and also reveals some relevant relationships among the considered bibliometric indices.     

Hybrid nanocomposites for mid-range ballistic protection

This paper focuses on ballistic tests of a new class of composite materials, i.e. hybrid nanocomposites. The two hybrid nanocomposites studied are fiber glass/epoxy/nanoclay and fiber glass/epoxy/nanographite. The fiber glass used is a plain weave 200 g/m², while the nanoclay is an organically modified montmorillonite ceramic (Nanomer I30E). The expandable graphite used to generate the graphene nanosheets was from Graftech (grade 160-80N). Ballistic tests were performed considering two types of ammunition, i.e. 38 caliber and 9 mm full metal jacketed. The results showed that for a 38 revolver projectile a 5 mm thick nanocomposite with additional 5 mm nanoclay layer was able to absorb the energy efficiently. A 9 mm projectile, with speed of 380 m/s, was stopped by a two plates (5 mm each) arrangement with elastic deformation of the second plate less than 18 mm. The energies during the ballistic tests ranged from 316 to 576 J.     

Comparison of four test methods to measure damping properties of materials by using piezoelectric transducers

This article presents the experimental results of damping loss factor and Young’s modulus obtained for stiff and flexible materials through the use of four different methodologies: the Central Impedance Method, the Modified Oberst Method, the Seismic Response Method, and the simply supported beam method. The first three methods are based on the ASTM standard but using different experimental setting and different Frequency Response Functions. The fourth method corresponds to a non-resonant technique used in the characterization of materials at very low frequencies. In this work, the results of damping loss factor and Young’s modulus obtained through these four methods are compared, the variability of results is studied and the sensitivity of each technique when facing controlled temperature variations is verified.     

An np‐control chart for inspection errors and repeated classifications

The np‐control chart has been used to monitor the conforming fraction in process production, and it is assumed that no classification errors occur during the inspection process. Increases in the sample size and/or the number of repeated classifications of the inspected items can reduce the impact of the classification errors. In this paper, an np ‐control chart is proposed, and the monitored statistics are based on the results of independent repeated classifications with classification errors during the inspection process. The aim of the proposed control chart is to have the same performance as a control chart without classification errors. Numerical examples illustrate the proposal. Copyright © 2011 John Wiley & Sons, Ltd.     

Severe accidents in the energy sector: comparative perspective

This paper addresses one of the controversial issues in the current comparative studies of the environmental and health impacts of energy systems, i.e. the treatment of severe accidents. The work covers technical aspects of severe accidents and thus primarily reflects an engineering perspective on the energy-related risk issues, though some social implications are also touched upon. The assessment concerns fossil energy sources (coal, oil and gas), nuclear power and hydro power. The scope is not limited to the power production (conversion) step of these energy chains but, whenever applicable, also includes exploration, extraction, transports, processing, storage and waste disposal. With the exception of the nuclear chain the focus of the work has been on the evaluation of the historical experience of accidents. The basis used for this evaluation is a comprehensive database ENSAD (Energy-related Severe Accident Database), established by the Paul Scherrer Institut (PSI). For hypothetical nuclear accidents the probabilistic technique has also been employed and extended to cover the assessment of economic consequences of such accidents. The broader picture obtained by coverage of full energy chains leads on the world-wide basis to aggregated immediate fatality rates being much higher for the fossil chains than what one would expect if only power plants were considered. Generally, the immediate fatality rates are for all considered energy carriers significantly higher for the non-OECD countries than for OECD countries. In the case of hydro and nuclear the difference is in fact dramatic. The presentation of results is not limited to the aggregated values specific for each energy chain. Also frequency-consequence curves are provided. They reflect implicitly the ranking based on the aggregated values but include also such information as the observed or predicted chain-specific maximum extents of damages. This perspective on severe accidents may lead to different system rankings, depending on the individual risk aversion.     

Layer-oriented simulation tool

The Layer-Oriented Simulation Tool (LOST) is a numerical simulation code developed for analysis of the performance of multiconjugate adaptive optics modules following a layer-oriented approach. The LOST code computes the atmospheric layers in terms of phase screens and then propagates the phase delays introduced in the natural guide stars' wave fronts by using geometrical optics approximations. These wave fronts are combined in an optical or numerical way, including the effects of wave-front sensors on measurements in terms of phase noise. The LOST code is described, and two applications to layer-oriented modules are briefly presented. We have focus on the Multiconjugate adaptive optics demonstrator to be mounted upon the Very Large Telescope and on the Near-IR-Visible Adaptive Interferometer for Astronomy (NIRVANA) interferometric system to be installed on the combined focus of the Large Binocular Telescope.