水介质引孔特性及其对水泥石性能影响研究

协调水泥基材料孔结构与力学性能是制备无机保温材料的关键问题。本实验对比研究了水介质和引气剂作为引孔介质,并与增稠剂羟丙基甲基纤维素HPMC复合方式,探讨了这两种引孔方式对水泥石宏观力学性能、热工性能,以及微观形貌、孔结构等性能的影响。结果表明,当水泥石在相同密度条件下,水介质引孔制备的多孔水泥石抗压强度较引气方式得到的水泥石强度高;水介质引孔对降低水泥石导热系数的效率较引气方式高,相比于水灰比为0.5的水泥石,水灰比为0.9,或者引气剂掺量为0.4%的水泥石降低导热系数的效率分别达58%和50%;水泥石形貌分析结果显示,水介质引入孔隙更均匀,水泥石中产物间的搭接程度降低,且水灰比越大该趋势越明显,而引气剂引入的孔隙分布均匀性较前者差;硬化水泥石孔结构分析表明,水介质引入的孔隙以小于1μm的毛细孔居多,且其中具有墨水瓶结构的孔隙含量明显少于由引气剂引孔时产生的墨水瓶孔含量。引气剂引入的孔隙孔径以大于1μm为主。     

低品位白钨矿选矿技术的研究发展

系统地介绍我国低品位白钨矿选矿技术现状及发展。详细阐述了浮选、非浮选选矿工艺以及选矿联合工艺在低品位白钨矿的选矿中的作用及其进展。重点指出对于品位低、组分复杂、细粒嵌布的白钨矿,单一选矿工艺已经很难解决问题,加大力度研究重、磁、浮、化等选矿工艺之间联系,组成联合工艺,实现各个工艺之间的优劣势互相补充,协同效应最大化,是未来大力度开发利用低品位白钨矿,保持我国钨业持续发展的发展方向。     

Superior temperature‐stable dielectrics for MLCCs based on Bi0.5Na0.5TiO3‐NaNbO3 system modified by CaZrO3

An ultra‐wide temperature stable ceramic system based on (1?x) [0.94(0.75Bi_0.5Na_0.5TiO₃?0.25NaNbO₃)?0.06BaTiO₃]?xCaZrO₃ (CZ100x) is developed for capacitor application in this study. All samples exhibit characteristics of pseudocubic structures in XRD patterns. With CaZrO₃ addition, the coupling effect of polar nanoregions (PNRs) is weakening, leading to greatly improved temperature stability of dielectric properties. Among all samples, the most attractive properties are obtained in the composition of CZ10 at <15% variation in dielectric permittivity spanning from ?55°C to 400°C and lower than 0.02 of dielectric loss of between ?60°C and 300°C, accompanied by high DC resistivity (10⁷ Ω m at 300°C, calculated by fitting Jonscher's power law). Furthermore, tentative multilayer ceramic capacitors (MLCCs) composed of CZ10 dielectric and Ag:Pd (70:30) internal electrode layers were fabricated by tape casting and cofiring processes. Temperature‐stable dielectric property in formation of MLCC was successfully realized, with small ΔC/C_25°C (<15%) and loss factor (≤ 0.02) between ?55°C and 340°C. Meanwhile, CZ10‐based MLCC showed temperature‐insensitive energy storage density of 0.31?0.35 J/cm³ and high‐energy efficiency of above 77% at 120 kV/cm in the range of ?55 to 175°C. All of these exhibit wonderful temperature‐stable dielectric properties and indicate the promising future of CZ10 dielectric as high‐temperature ceramic capacitors.     

The effect of CO2 dissolved in a diesel fuel on the jet flame characteristics

This paper is concerned with an experimental study of the jet diffusion flame characteristics of fuel containing CO₂. Using diesel fuel containing dissolved CO₂ gas, experiments were performed under atmospheric conditions with a diesel hole-type nozzle of 0.19 mm orifice diameter at constant injection pressure. In this study, four different CO₂ mass fraction in diesel fuel such as 3.13%, 7.18%, 12.33% and 17.82% were used to study the effect of CO₂ concentration on the jet flame characteristics. Jet flame characteristics were measured by direct photography, meanwhile the image colorimetry is used to assess the qualitative features of jet flame temperature. Experimental results show that the CO₂ gas dilution effect and the atomization effect have a great influence on the flame structure and average temperature. When the injection pressure of diesel fuel increased from 4 MPa to 6 MPa, the low temperature flame length increased from 18.4 cm to 21.7 cm and the full temperature flame length decreased from 147.6 cm to 134.7 cm. With the increase of CO₂ gas dissolved in the diesel fuel, the jet flame full length decreased for the jet atomization being improved greatly meanwhile the low temperature flame length increased for the CO₂ gas dilution effect; with the increase of CO₂ gas dissolved in the diesel fuel, the average temperature of flame increases firstly and then falls. Experimental results validate that higher injection pressure will improve jet atomization and then increased the flame average temperature.     

碳纤维布基聚吡咯修饰电极的制备及性能表征

分别用恒电流、恒电位、循环伏安法、电沉积与恒电流相结合等电化学方法,制备了新型碳纤维布基聚吡咯修饰电极,用扫描电子显微镜( SEM)观察了其表面形貌,研究了吡咯在碳纤维布基上的聚合条件和膜的生长过程,研究了聚吡咯修饰电极对氟离子的电流响应特性.结果表明:用电沉积与恒电流相结合的方法制备的碳纤维布基聚吡咯膜具有致密性好、...     

大白菜施用不同数量腐植酸复混肥试验报告

腐植酸复混肥作为“绿色环保肥料”被广泛应用于农业生产中，成为我国发展最快的化肥品种，本次试验探讨不同含量腐植酸复混肥品种、施用数量与产量之间的关系，为科研、生产、推广提供依据。     

Preparation of heat‐resistant gradient‐index polymer optical fiber rods based on poly(N‐isopropylmaleimide‐co‐methyl methacrylate)

Using the interfacial gel polymerization method, a heat‐resistant gradient‐index polymer optical fiber (GI POF) was developed based on the copolymer of methyl methacrylate (MMA) and N‐isopropylmaleimide (IPMI) as the matrix material and bromobenzene (BB) as dopant. The gradient distribution of IPMI in the GI POF rod was determined by element analysis. IPMI had great advantage in improving glass transition temperature (T_g) and forming a gradient‐index profile. There was a significant enhancement in the heat‐resistant property in comparison with a conventional GI POF rod. The combination of high thermal stability and easy fabrication makes the novel BB–IPMI–MMA system very suitable for heat‐resistant GI POF. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 280–283, 2003     

电感耦合等离子体质谱鉴别潲水油方法研究

通过湿法消解和温水浸提处理样品市售合格食用油和不同来源潲水油样品后,采用电感耦合等离子体质谱检测样品金属元素含量。结果显示：不同来源潲水油和合格食用油Na、Al等金属元素含量检测结果比较差异有统计学意义（p〈0.05）;温水浸提法处理潲水油样品后用ICP-MS法检测Na、Al等金属元素含量,可满足不同来源潲水油样品和样品快速检测需求。     

以专业认证为抓手的化工专业人才培养模式研究与实践

为深入落实本科教育和人才培养的相关要求,实现高等教育内涵式发展,郑州大学化工专业以工程教育专业认证为抓手,践行以学生为中心的核心理念,以学生学习成果为导向,建立了“评价—反馈—改进”闭环和与用人单位协同持续改进的培养机制。教学过程中贯穿专业教育和课外教育,激发学生专业兴趣;坚持“以本为本”,培养卓越化工人才。教改在学生就业、竞赛、外部评价及专业建设等方面取得了较好的成效,提升了专业知名度及专业培养质量。