Influence of carbon concentration and reaction temperature upon bainite morphology in Fe-C-2 Pct Mn alloys

Isothermal transformation of austenite to bainite was studied by optical, replication, and thin foil transmission electron microscopy (TEM) in both hypo- and hypereutectoid Fe-C-2 wt pct Mn alloys (and a single 3 pct Mn alloy) containing from 0.1 to 1.37 wt pct C in order to characterize and explain the transitions which occur in bainite morphology as a function of carbon content and reaction temperature. A “morphology map” was constructed showing the temperaturecarbon composition(T-x) regions in which four different bainite morphologies predominate: upper bainite, lower bainite, nodular bainite, and inverse bainite. Calculations of the volume free energy changes associated with the nucleation of ferrite, ?G _v ^α , and cementite, ?G _v ^c , and the parabolic rate constant for growth of ferrite, α_α, and cementite, α_c, were performed in order to explain the observed morphological transitions. In hypoeutectoid alloys, where |?G _v ^α | ? |ΔG _v ^c | and α_α ? α _c , the Widmanstätten ferrite-dominated morphologies of upper and lower bainite predominate. The upper-to-lower bainite transition appears to be associated with the emergence of edge-to-face sympathetic nucleation at high values of |ΔG _v ^α |. In hypereutectoid alloys, the ratios ΔG _v ^α /ΔG _v ^c and α_α/α_c are considerably smaller; hence, cementite can compete much more readily with ferrite during both nucleation and growth, resulting in the formation of nodular bainite. With decreasing temperature in the hypereutectoid regime,ΔG _v ^α /ΔG _v ^c , and especially α_ga/α_c, increase, resulting in the replacement of nodular bainite by lower bainite at temperatures below about 250 °C to 275°C.     

A novel technique to measure the group velocity of sound in dispersive media

A technique is proposed for measuring the group velocity of sound by a frequency-modulated (FM) continuous wave (CW) technique. Detailed calculations are presented, showing that V(g)=(deltaomega(m)/deltaphi)d , where V(g), deltaomega(m), deltaphi, and d are, respectively, the group velocity, change of modulation frequency, phase change of the received signal detected by a biphase lock-in amplifier, and the distance traveled by the sound. The approach has the advantage of high resolution compared to the conventional time-of-flight measurement technique.     

Collective modes and sound propagation in a magnetic field in superfluid3He-B

A high-resolution, ultrasonic (12–89 MHz) acoustic impedance technique has been used to investigate the order parameter collective modes in superfluid³He-B over a pressure range of 0–15 bar and in magnetic fields up to 180 mT. In agreement with earlier experiments, theJ=2 real squashing mode has been observed to split into five components in small magnetic fields. However, contrary to earlier theoretical estimates, the Zeeman shifts have been found to become extremely nonlinear as the magnetic field is increased. The extent of this nonlinearity is largest at low pressures and at temperatures close toT _c. In comparison with recent theoretical work, the nonlinear Zeeman shifts may be explained as a result of two effects. First, there is a significant distortion of the B-phase energy gap in large magnetic fields. Second, there is an important coupling between the sameJ _zsubstates of the differentJ modes. In this sense the nonlinear evolution of the real squashing mode constitutes the observation of the Paschen-Back effect in³He-B. A comparison of the observed Zeeman shifts with theoretical expressions has yielded information about particle-particle and particle-hole interaction effects in the superfluid. In the limitT 0 and above a threshold field, the real squashing mode has been found to possess additional structure. TheJ _z=0 substate has been observed to split into a doublet. The separation between the two components of the doublet is of the order of 100–200 kHz and remains independent of the magnetic field. The origin of the doublet may be understood in terms of a recent theory which postulates a texture-dependent collective mode frequency. Further, at extremely small fields the effects due to dispersion of the real squashing modes have been found to be important. The magnitude of the dispersion-induced mode splitting in zero field is found to be consistent with theoretical predictions. TheJ=2 squashing mode has also been studied in the presence of a magnetic field. TheJ _z=0 state of the squashing mode is observed to shift to lower temperatures in a magnetic field. An additional field dependence of the observed acoustic impedance is interpreted as the evolution of theJ _z=–1, –2 states, but appears to be inconsistent with theoretical predictions.     

Impact of Spatial Data Availability on Climate Change Prediction in the Weyib River Basin in Ethiopia

Impact of spatial data availability on the temperature and precipitation prediction characteristics of Weyib River basin in Ethiopia has been investigated using CMIP5-CanESM2 model for the RCP8.5, RCP4.5 and RCP2.6 scenarios. The objective of the present study is to characterize how future temperatures and precipitation prediction under CMIP5-CanESM2 model output varies against diverse averaged arbitrary spatial weather stations found in the basin. The statistical downscaling model tested and verified using the observed daily data for twelve, six and three averaged arbitrary spatial weather stations as well as for a single weather station was used to predict the future climate scenarios. The results revealed that the mean annual daily maximum and minimum temperature and precipitation for twelve, six and three arbitrary spatial stations have revealed an increasing trend in the upcoming periods until the end of the century. In single station analysis, the trend itself has changed from increasing trend to decreasing trend in case of maximum and minimum temperature. In case of precipitation, no visible trend has been observed in case of single station analysis. Therefore, the variation in amount and distribution of precipitation and temperature among the four averaged spatial stations in the same study area might affect the water resources and agriculture of the basin and also instead of using a single weather station to predict future climate variables for a particular study basin, it is more reliable using averages of numerous spatial weather stations data.     

A numerical study of particle wall-deposition in a turbulent square duct flow

The deposition of dense solid particles in a downward, fully developed turbulent square duct flow at Re_τ = 360, based on the mean friction velocity and the duct width, is studied using large eddy simulations of the fluid flow. The fluid and the particulate phases are treated using Eulerian and Lagrangian approaches, respectively. A finite-volume based, second-order accurate fractional step scheme is used to integrate the incompressible form of the unsteady, three-dimensional, filtered Navier-Stokes equations on an 80 × 80 × 128 grid. A dynamic subgrid kinetic energy model is used to account for the unresolved scales. The Lagrangian particle equation of motion includes the drag, lift, and gravity forces and is integrated using the fourth-order accurate Runge-Kutta scheme. Two values of particle to fluid density ratio (ρ_p/ρ_f = 1000 and 8900) and five values of dimensionless particle diameter (d_p/δ × 10⁶ = 100, 250, 500, 1000 and 2000, δ is the duct width) are studied. Two particle number densities, consisting of 10⁵ and 1.5 × 10⁶ particles initially in the domain, are examined.Variations in the probability distribution function (PDF) of the particle deposition location with dimensionless particle response time, i.e. Stokes number, are presented. The deposition is seen to occur with greater probability near the center of the duct walls, than at the corners. The average streamwise and wall-normal deposition velocities of the particles increase with Stokes number, with their maxima occurring near the center of the duct wall. The computed deposition rates are compared to previously reported results for a circular pipe flow. It is observed that the deposition rates in a square duct are greater than those in a pipe flow, especially for the low Stokes number particles. Also, wall-deposition of the low Stokes number particles increases significantly by including the subgrid velocity fluctuations in computing the fluid forces on the particles. Two-way coupling and, to a greater extent, four-way coupling are seen to increase the deposition rates.     

Synthesis of poly(vinyl propionate) from poly(vinyl alcohol) in nonaqueous medium using ethyl nitrate dimethyl sulfoxide as a catalyst

Poly(vinyl alcohol) (PVA) can be dissolved in a nonaqueous medium in the presence of catalytic concentration of ethyl nitrate dimethyl sulfoxide, C₂H₅ONO₂·DMSO. From the PVA solution, poly(vinyl propionate), PVPR was prepared by the homogeneous esterification of PVA with propionic acid. The ester thus formed contained some unconverted hydroxyl group. The formation of the ester was confirmed by the IR and ¹H‐NMR spectra. The molecular weight of the ester was determined by GPC and intrinsic viscosity (η) was determined by viscometric method. Glass transition temperature, T_g, was obtained from differential scanning calorimetric (DSC) analysis. Thermal stabilities of the ester were checked by thermogravimetric analysis (TGA) and differential thermogravimetric (DTG) analysis. The efficiency of the ester as a flow improver of crude oil was also examined. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5675–5679, 2006     

Dielectric Properties of the "Twinned" 8H-Hexagonal Perovskite Ba8Nb4Ti3O24

The dielectric properties of dense ceramics of the "twinned" 8H-hexagonal perovskite Ba₈Nb₄Ti₃O₂₄ are reported. Single-phase powders were obtained from the mixed-oxide route at 1325°C and ceramics (>92% of the theoretical X-ray density) by sintering in air or flowing O₂ at 1400°–1450°C. The ceramics are dc insulators with a band gap >3.4 eV that resonate at microwave frequencies with relative permittivity, ɛ_r∼44–48, quality factor, Q × f _r∼21 000–23 500 GHz (at f _r∼5.5 GHz) and temperature coefficient of resonant frequency, TC _f,∼+115 ppm/K.     

Rigidity of a simple extended lower triangular matrix

For the all-ones lower triangular matrices, the upper and lower bounds on rigidity are known to match [P. Pudlak, Z. Vavrin, Computation of rigidity of order n²/r for one simple matrix, Comment Math. Univ. Carolin. 32 (2) (1991) 213-218]. In this short note, we apply these techniques to the all-ones extended lower triangular matrices, to obtain upper and lower bounds with a small gap between the two; we show that the rigidity is .