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31.
An oxathiolanone derivative of rutin could be produced in the stomach after the ingestion of rutin containing foods, and the oxathiolanone derivative could be hydrolysed to an oxathiolanone derivative of quercetin (quercetin-oxathiolanone) in the intestine. Quercetin-oxathiolanone as well as quercetin inhibited xanthine oxidase. Approximately 0.05 μM quercetin-oxathiolanone inhibited the activity by 50%, whereas 50% inhibition by quercetin was observed at approximately 0.4 μM. The results suggested that quercetin-oxathiolanone can be used as an effective inhibitor of xanthine oxidase and that the ingestion of rutin-rich foods may be useful to prevent the increase in the blood concentration of uric acid. 相似文献
32.
Ichiro Yamanaka Toshikazu Hashimoto Ryo Ichihashi Kiyoshi Otsuka 《Electrochimica acta》2008,53(14):4824-4832
Direct synthesis of H2O2 acid solutions was studied using a gas-diffusion cathode prepared from activated carbon (AC), vapor-growing-carbon-fiber (VGCF) and poly-tetra-fluoro-ethylene (PTFE) powders, with a new H2/O2 fuel cell reactor. O2 reduction to H2O2 was remarkably enhanced at the three-phase boundary (O2(g)-electrode(s)-acid(l)) at the [AC + VGCF] cathode. Fast diffusion processes of O2 to the active surface and of H2O2 to the bulk acid solutions were essential for H2O2 accumulation. Synergy of AC and VGCF was observed for the H2O2 formation. RRDE and cyclic voltammetry studies indicated that the surface of AC functioned as the active phase for O2 reduction to HO2, and VGCF functioned as an electron conductor and a promoter to convert HO2 to H2O2. A maximum H2O2 concentration of 353 mM (1.2 wt%) was accomplished under short-circuit conditions (current density 12.7 mA cm−2, current efficiency 40.1%, geometric area of cathode 1.3 cm2, reaction time 6 h). 相似文献
33.
Oishi S Masuda R Evans B Ueda S Goto Y Ohno H Hirasawa A Tsujimoto G Wang Z Peiper SC Naito T Kodama E Matsuoka M Fujii N 《Chembiochem : a European journal of chemical biology》2008,9(7):1154-1158
The design, synthesis, and bioevaluation of fluorescence- and biotin-labeled CXCR4 antagonists are described. The modification of D-Lys8 at an epsilon-amino group in the peptide antagonist Ac-TZ14011 derived from polyphemusin II had no significant influence on the potent binding of the peptide to the CXCR4 receptor. The application of the labeled peptides in flow cytometry and confocal microscopy studies demonstrated the selectivity of their binding to the CXCR4 receptor, but not to CXCR7, which was recently reported to be another receptor for stromal cell-derived factor 1 (SDF-1)/CXCL12. 相似文献
34.
Dr. Masayuki Izumi Akihisa Otsuki Mika Nishihara Dr. Ryo Okamoto Prof. Dr. Yasuhiro Kajihara 《Chembiochem : a European journal of chemical biology》2014,15(17):2503-2507
As a basis for the development of an artificial carbohydrate‐binding lectin, we chemically synthesized a domain of siglec‐7, a well‐characterized sialic‐acid‐binding lectin. The full polypeptide (127 amino acids) was constructed by sequential native chemical ligation (NCL) of five peptide segments. Because of poor cysteine availability for NCL, cysteine residues were introduced at suitable ligation sites; these cysteine residues were alkylated in order to mimic native glutamine or asparagine residues, or converted to an alanine residue by desulfurization after NCL. After folding the full‐length polypeptide, the sialic‐acid‐binding activity of the synthetic siglec‐7 was clearly demonstrated by STD NMR and ELISA experiments. We succeeded in the synthesis of siglec‐7 by installing three extra cysteine residues with side‐chain modifications and found that these modifications did not affect the binding activity. 相似文献
35.
A micro‐grooved evaporator is composed of µm‐wide grooves on a heat transfer plate in which the inter‐line regions at the liquid–vapor meniscus of coolant become identifiable. The high‐heat performance of the evaporator is realized by this inter‐line region (ILR) where the liquid thin film reduces the thermal resistance on the heat transfer surface. In this report, we propose a numerical simulation model of heat and mass transfer in a single groove to predict its capillary force and heat flux. The capillary force performance (capillary‐rise length in a groove) of a single groove was measured for samples of varying width, superheat, and inclination. The performance was found to be a maximum at a specific groove width of 200–400 µm, which is in good agreement with the predicted results calculated by the proposed model. For a better prediction of capillary‐rise length, the effective capillary force and the effective flow resistance were considered. © 2009 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20257 相似文献
36.
KyoungHou Kim Ryo Aida YoungAh Kang Yutaka Ohkoshi Yasuo Gotoh Masanobu Nagura Hiroshi Urakawa 《Polymer》2009,50(19):4429-4431
The structure development in the continuous laser-heated drawing process of poly(ethylene 2,6-naphthalene dicarboxylate) (PEN) fiber was analyzed by in-situ X-ray diffraction measurement. Because of the rapid and uniform laser heating, and the resultant steady-state nature of the necking-drawing, the structure development after the on-set of necking could be measured in the time resolution of several hundred microseconds. We found for the first time the temporal appearance of meridional (001′) diffraction at several milliseconds after the on-set of necking indicating that the mesophase structure similar to the one reported for poly(ethylene terephthalate) was also formed in the initial stage of fiber structure development of PEN. The d-spacing of the (001′) diffraction 1.230 ± 0.003 nm was shorter than the c-axis lengths of both α and β crystals. 相似文献
37.
An Experimental Study of a Cooperative Positioning System 总被引:3,自引:3,他引:0
Several position identification methods are being used for mobile robots. Dead reckoning is a popular method but due to the error accumulation from wheel slippage, its reliability is low for measurement of long distances especially on uneven surfaces. Another popular method is the landmark method, which estimates current position relative to known landmarks, but the landmark method's limitation is that it cannot be used in an uncharted environment. Thus, this paper proposes a new method called Cooperative Positioning System (CPS) that is able to overcome these shortcomings. The main concept of CPS is to divide the robots into two groups, A and B where group A remains stationary and acts as a landmark while group B moves and then group B stops and acts as a landmark for group A. This process is repeated until the target position is reached. Compared with dead reckoning, CPS has a far lower accumulation of positioning errors, and can also work in three dimensions. Furthermore, CPS employs inherent landmarks and therefore can be used in uncharted environments unlike the landmark method. In this paper, we introduce the basic concept of CPS and its positioning principle. Next, we outline a second prototype CPS machine model (CPS-II) and discuss the method of position estimation using the variance of positioning error and weighted least squares method. Position identification experiments using the CPS-II model give a positioning accuracy of 0.12% for position and 0.32 degree for attitude after the robots traveled a distance of 21.5 m. 相似文献
38.
The effect of the addition of certain low molecular weight compounds to highly crosslinked epoxy resins was investigated. The behavior which is known as antiplasticization, such as increases in modulus and yield strength and the elimination of β-transition, was observed in the highly crosslinked system as well as in the reported cases of thermoplastics—poly(vinyl chloride), bisphenol A polycarbonate, and polysulfone. Chlorinated biphenyl was found to be one of the most effective antiplasticizers examined in the present paper. However, the remarkable reduction in compressive strain at break and impact strength was not recognized for the highly antiplasticized samples. These phenomena have been interpreted on the basis of free volume concept. 相似文献
39.
Piao Y Yamashita M Kawaraichi N Asegawa R Ono H Murooka Y 《Journal of Bioscience and Bioengineering》2004,98(3):167-173
Since the chemical synthesis of vitamin B12 requires more than 70 steps, the production of vitamin B12 has been achieved by microorganism fermentation with additional brief chemical modifications. In an effort to increase the productivity of vitamin B12, we tried to express 10 genes belonging to the hem, cob and cbi gene families involved in the synthesis of vitamin B12 in Propionibacterium freudenreichii, which is a known producer of vitamin B12. In a recombinant P. freudenreichii clone that harbored the expression vector containing a cobA, cbiLF, or cbiEGH, we obtained an increase in vitamin B12 production of 1.7-, 1.9-, and 1.5-fold higher, respectively, than that in the microorganism without any cloned genes in the expression vector pPK705. The cobU and cobS genes caused a slight increase in the production of vitamin B12. Furthermore, we achieved multigene expression in P. freudenreichii. In a recombinant P. freudenreichii clone that harbored an exogenous gene, hemA, from Rhodobacter sphaeroides and endogenous hemB and cobA genes, we successfully achieved the production of about 1.7 mg/l vitamin B12, 2.2-fold higher than that produced by P. freudenreichii harboring pPK705. 相似文献
40.
Ryo Toda Yuki Matsushita Mitsunori Hieda Taku Matsushita Nobuo Wada 《Journal of Low Temperature Physics》2007,148(5-6):785-790
We have measured the heat capacity of 3He adsorbed on three-dimensionally connected nanopores, 2.7 nm in diameter, preplated with about 1.3 atomic layers of 4He. At low coverages of 3He, the 3He heat capacity is roughly constant at the measured temperatures between 0.1 and 1 K. Its molar heat capacity is on the order
of the gas constant R, between 1.1R and 1.8R. This suggests a Boltzmann gas state of the adsorbed 3He. At high coverages, the heat capacity is likely approaching linear in T at low temperatures, which suggests a degenerate state at further lower temperatures. 相似文献