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排序方式: 共有683条查询结果,搜索用时 15 毫秒
81.
Dr. Masayuki Izumi Akihisa Otsuki Mika Nishihara Dr. Ryo Okamoto Prof. Dr. Yasuhiro Kajihara 《Chembiochem : a European journal of chemical biology》2014,15(17):2503-2507
As a basis for the development of an artificial carbohydrate‐binding lectin, we chemically synthesized a domain of siglec‐7, a well‐characterized sialic‐acid‐binding lectin. The full polypeptide (127 amino acids) was constructed by sequential native chemical ligation (NCL) of five peptide segments. Because of poor cysteine availability for NCL, cysteine residues were introduced at suitable ligation sites; these cysteine residues were alkylated in order to mimic native glutamine or asparagine residues, or converted to an alanine residue by desulfurization after NCL. After folding the full‐length polypeptide, the sialic‐acid‐binding activity of the synthetic siglec‐7 was clearly demonstrated by STD NMR and ELISA experiments. We succeeded in the synthesis of siglec‐7 by installing three extra cysteine residues with side‐chain modifications and found that these modifications did not affect the binding activity. 相似文献
82.
Preparation and properties of CuInS2 thin film prepared from electroplated precursor 总被引:1,自引:1,他引:1
Yoshio Onuma Kenji Takeuchi Sumihiro Ichikawa Yasunari Suzuki Ryo Fukasawa Daisuke Matono Kenji Nakamura Masao Nakazawa Koji Takei 《Solar Energy》2006,80(1):132-138
Thin CuInS2 films were prepared by sulfurization of Cu/In bi-layers. First, the precursor layer was electroplated onto the treated surface of Mo-coated glass. Observation of the cross-section prepared by focused ion beam (FIB) etching revealed that the void-free film was initially formed on the top surface of the precursor layer and continued to grow until the advancing front of the film reached the Mo layer. The nucleation of voids near the bottom of the CuInS2 film followed. To determine whether the condition of the Cu/In alloy influences the CuInS2 quality we investigated the Cu/In alloy state using FIB. We found that the annealed precursor of low Cu/In ratio (1.2) has several voids in the mid position in the layer compared with Cu-rich precursor (1.6). The cross-sectional view of the Cu-rich absorber layer is uniform compared with the low copper absorber layer. Thin film solar cells were fabricated using the CuInS2 film (Cu/In ratio: 1.2) as an optical absorber layer. It was found that the optimization of a sulfurization period is important in order to improve the cell efficiency. We have not yet obtained good results with high Cu-rich absorber because of a blister problem. This blister was found before sulfurization. So, we are going to solve this blister problem before sulfurization. 相似文献
83.
M Kai T Todo M Wada H Ryo C Masutani H Kobayashi H Morioka E Ohtsuka F Hanaoka K Sakaguchi 《Canadian Metallurgical Quarterly》1998,1397(2):180-188
Airborne substances can stimulate both the olfactory and the trigeminal nerve in the nose, giving rise to odor and pungent (irritant) sensations, respectively. Nose, eye, and throat irritation constitute common adverse effects in indoor environments. We measured odor and nasal pungency thresholds for homologous aliphatic aldehydes (butanal through octanal) and carboxylic acids (formic, acetic, butanoic, hexanoic, and octanoic). Nasal pungency was measured in subjects lacking olfaction (i.e., anosmics) to avoid odor biases. Similar to other homologous series, odor and pungency thresholds declined (i.e., sensory potency increased) with increasing carbon chain length. A previously derived quantitative structure-activity relationship (QSAR) based on solvation energies predicted all nasal pungency thresholds, except for acetic acid, implying that a key step in the mechanism for threshold pungency involves transfer of the inhaled substance from the vapor phase to the receptive biological phase. In contrast, acetic acid - with a pungency threshold lower than predicted - is likely to produce threshold pungency through direct chemical reaction with the mucosa. Both in the series studied here and in those studied previously, we reach a member at longer chain-lengths beyond which pungency fades. The evidence suggests a biological cut-off, presumably based upon molecular size, across the various series. 相似文献
84.
The authors have proposed a method of reducing the energy consumption in residential buildings by providing household members with information on energy consumptions in their own houses. An on-line interactive “energy-consumption information system” that displays power consumptions of, at most, 18 different appliances, power and city-gas consumption of the whole house and room temperature, for the purpose of motivating energy-saving activities has been constructed and the effectiveness of the system investigated by installing it in 10 residential buildings. The experiment showed that energy-saving consciousness was raised and energy consumption was in fact reduced by the energy-saving activities of the household members. In this paper, the system is described in detail and the effectiveness of reducing energy-consumption of the whole house and for space heating will be discussed. Also the energy-saving activities in a certain household are shown by using load duration curves. 相似文献
85.
This study examines the performance of “string-of-beads” liquid flow on vertical wires as a novel gas-liquid contact device for gas absorption using a chemically reacting liquid absorbent. The string-of-beads flow is a distinct on-wire liquid-flow pattern consisting of annular thin liquid films sheathing a wire and teardrop-shaped liquid beads alternately aligned on the wire at regular intervals. We have performed experiments of CO2 absorption by an aqueous monoethanolamine solution in string-of-beads flow on a single wire and have developed an analytic gas-absorption model relevant to the experiments. The model well simulates the CO2-absorption characteristics observed in the experiments, thereby suggesting the utility of the model in predicting the chemical gas-absorption performance of multiple-wire gas-liquid contactors. 相似文献
86.
87.
88.
The industrially important yeast Candida utilis is widely used in the production of food and medical materials, but its practical host-vector system has not been well developed. In order to construct a food-grade host-vector system, we isolated the YAP1 homologue, CuYAP1, of C. utilis IAM4264 and evaluated its use as a selection marker in transformation. A DNA probe was obtained by PCR using degenerate primers and the CuYAP1-encoding 438 amino acid protein was isolated by hybridization. Although the amino acid identity of Yap1 and CuYap1 was 28.7% as a whole, the characteristic bZip region and two cysteine-rich domains (CRDs) showed a higher homology. CuYAP1 was inserted in a CuGAP1 expression cassette of the C. utilis ARS vector pRI177, and C. utilis AHU3053 was transformed with this plasmid. A number of transformant colonies grew in the presence of cycloheximide, which indicated that CuGAP1-CuYAP1 is an effective selection marker. The transformant also showed higher resistance to other agents, including cadmium and fluconazole. The overexpression of CuYAP1 in S. cerevisiae also resulted in increased resistance to various types of drugs. 相似文献
89.
Nitrogen and S distribution ratios between CaO-Al2O3-MgO slags and liquid Fe were measured at 1873 K as a function of Al (or Mg, Ca) content in metal, using CaO, MgO, and A12O3 crucibles. Based on the results for the solubility product of MgO, the equilibrium constant,K
Mg
, for the reaction MgO =Mg +O and the first-order interaction parameter,e
O
Mg
(e
Mg
O
), were estimated to be logK
Mg = -7.8 ± 0.2 ande
O
Mg
= -190 ± 60 (e
Mg
O
= -290 ± 90), respectively. The activities of A12O3 at the slag compositions double-saturated with CaO/MgO, MgO/ MgO A12O3, and MgO Al2O3/CaO 2A12O3 components were obtained from the S distribution ratios between slag and metal, coupled with the reported values of sulfide
capacities. Nitride capacities were also estimated from the N distribution ratios and the activities of A12O3. 相似文献
90.
Ryo Watanabe Yasushi Sekine Masahiko Matsukata Eiichi Kikuchi 《Catalysis Letters》2009,131(1-2):54-58
We investigated novel LaMnOx perovskite-oxide (ABO3) catalysts for effective catalytic dehydrogenation of ethylbenzene to produce styrene monomer. Comparison with industrial Fe–K catalyst, our La0.8Ba0.2Mn0.6Fe0.4O3-δ catalyst showed higher activity. Results show that the A-site in perovskite-type oxides affected catalytic dehydrogenation activities and that the B-site affected stability of the activities. 相似文献