Co-Al基三元系中B2相的溶解度间隙与稳定性

Information on phase equilibria in the Co-Al based systems which are related to some magnetic and heat resistance materials is important for their microstructural control. Recently, it was proposed with a theoretical calculation on electronic band structure that some Heusler-type alloys Co2 XAl (X: Cr and Mn) should be a new type of spinelectronic materials so-called half-metallic ferromagnet. In the case of the Co2CrAl, however, magnetic properties expected from the theoretical work can not been experimentally obtained and the reason has been still unknown. On the other hand, a tunne- ling magnetoresistance (TMR) effect due to the half-metallic properties was reported in Co2 (Cr0.6 Fe0.4 ) Al alloy, but not the Co2CrAl alloy. In the present paper, it is reported that this discrepancy with the theoretical work in the Co2CrAl alloy is bought about by phase separation between A2 and B2 phases, and that the substitution of Fe for Cr can suppress the precipitation of A2 phase in the B2 phase. Such a phase separation is originally due to the miscibility gap between CoAl and Cr formed in the Co-Al-Cr ternary system as well as that reported by Hao et al. in the Ni-Co-Al-Fe system.     

Carbon-supported growth of cross-linked platinum nanowires by surfactant templating and their elecrochemical characterization

Platinum/carbon (Pt/C) composite materials were prepared by the hydrazine reduction of H2PtCl6 confined to a mixed surfactant lytropic liquid crystal (LC)/C mixture with varying amounts of water. The reaction at relatively low water contents successfully yielded cross-linked Pt nanowires with wire-widths of 2-5 nm. The novel Pt nanostructure is believed to be from poorly hydrated hexagonal domains formed together with layered domains by the phase separation of the precursory LC mixture in the presence of carbon. Electrochemical measurements using cyclic volutammetry and membrane electrode assemblies revealed that the cross-linked nanowired Pt/C composite exhibits fairly high electrocatalytic activity for oxygen reduction reaction, as well as a high performance as the cathode material for polymer electrolyte fuel cells.     

A Gate‐Current Model for Advanced MOSFET Technologies Implemented into HiSIM2

A gate leakage current model for advanced MOSFETs has been developed and implemented into the Hiroshima‐university STARC IGFET Model (HiSIM), the first complete surface‐potential‐based model. The model consists of four tunneling mechanisms, the gate to channel/bulk/source/drain, and requires totally 15 model parameters covering all bias conditions. Simulation results reproduce measurement for any device size and temperature without binning. Validity of the model has been tested with circuits that are sensitive to the change of stored charge due to tunneling current. Copyright © 2007 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

Development of a swim-type ROV for narrow space inspection

The swim-type remotely operated vehicle (ROV) for inspection of narrow spaces in nuclear power plants has been developed. Many structures are crowded in a confined space at regular intervals in the bottom area of a reactor. So, the thickness of the ROV shape is an important design point to ensure that the ROV can move in the space. The developed ROV has a three-dimensional swimming mechanism using six thrusters, three cameras for observing the position while moving and for making inspections easily, and a localization system. The localization system combines two elements: a gyroscope to detect the progression direction; and a slit laser that detects the progression distance using the optical cutting method. The localization method is called the modified inertial navigation (MIN) method and it was evaluated in a mock-up examination. The ROV was able to move smoothly using the MIN method and its position could be detected without making a mistake in the route followed.     

Determining factors for anodic polarization curves of typical structural materials of boiling water reactors in high temperature – high purity water

In order to examine the anodic polarization characteristics of typical structural materials of boiling water reactors (BWRs), the anodic polarization curves of type 316L stainless steel (316L SS) and Alloy 182 were measured in deaerated high purity water at 553 K using the previously reported measurement method which was confirmed suitable for high temperature – high purity water. In order to specify which constituent element determines the dissolution characteristics of these materials, the anodic polarization curves of pure iron, pure nickel, and pure chromium were also surveyed. The anodic polarization curve of 316L SS was determined to have active, passive, and transpassive states which were the same as type 304 SS (304 SS) showed. But, Alloy 182 had different polarization characteristics especially near the corrosion potential as it had no active state. From comparison results of the polarization characteristics of these materials and their constituent elements, the corrosion characteristics of these materials were concluded to be mainly determined by the corrosion characteristics of chromium.     

食用沙拉酱对部分血脂指标的影响

目的:通过试食实验,评价沙拉酱对人体部分血脂指标影响的效果。方法:采用自身对照设计的方法。47例18～22岁青年健康男性参与为期70d的试食实验。在不影响试食者饮食习惯的前提下,每日提供15g沙拉酱。分别在实验前及试食过程中的30、60、70d后分别进行检测。并于实验结束后37d再进行一次检测,以观察试食者在食用沙拉酱后血脂指标的变化。结果:试食至30d,试食者低密度脂蛋白胆固醇(LDL-C)含量显著下降(P<0.01)。试食至60d,血清总胆固醇(TC)、甘油三酯(TG)的含量显著上升(P<0.01),LDL-C值显著下降(P<0.01)。试食至70d,TC、TG含量显著上升(P<0.01)、高密度脂蛋白胆固醇(HDL-C)含量显著上升(P<0.01)。结论:在实验所指定的剂量下,沙拉酱未对人体血脂造成不良影响。值得注意的是,试食至50d时,由于节日原因,试食者饮食结构发生突变,饮酒和动物性脂肪摄入较多,导致第60天及第70天检测所得数据中TC和TG等有异常变化,证明饮食结构的变化直接影响血脂指标的变化。本次试食实验的数据表明,沙拉酱对提高HDL-C含量、降低LDL-C含量具有一定的促进作用。     

Measurement of tongue–artificial nipple contact pressure during infant sucking

To clarify the motor function of the infant tongue during sucking, we developed an artificial nipple that contained multiple small built‐in force sensors integrated with a PC‐based system which is capable of measuring tongue–artificial nipple contact pressures in real time. The force sensor is a cantilever structure with a small, thin stainless steel beam where an all‐purpose foil strain gauge is attached to the surface of the beam. An artificial nipple made of an elastomer containing these sensors is connected through an amplifier and an A/D converter to a PC via a USB port. Using this system, measurements were taken in three infants whose oral feeding was well established and in one infant of low birth weight. The results from each force sensor showed a pressure waveform of a nearly simple harmonic motion that indicated a peristalsis‐like movement of the tongue; the sucking frequency was found to be about two times per second. In addition, in the low‐birth‐weight infant, the pressure changed as the infant grew. © 2012 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

Ultrahigh Electrical Resistance of Poly(cyclohexyl methacrylate)/Carbon Nanotube Composites Prepared Using Surface‐Initiated Polymerization

Multiwalled carbon nanotubes on which poly(cyclohexyl methacrylate)s are densely grafted (PCHMA‐CNTs), are synthesized using a modified surface‐initiated atom transfer radical polymerization technique. The electrical resistance of PCHMA‐CNT is systematically characterized under direct current (DC) and alternating current and compared to that of conventional nanocomposites prepared by blending PCHMA with the CNT (PCHMA/CNT). At a comparable volume fraction of CNT, DC volume resistivity of PCHMA‐CNT is 14 orders of magnitude higher than that of PCHMA/CNT. This is because the grafted polymer with a combination of the high molecular weight and the high grafting density isolates individual CNTs at a long distance in the PCHMA‐CNT system. In addition, impedance analysis reveals that the highly insulated PCHMA‐CNT has the same electrical nature as neat PCHMA, i.e., it is a dielectric. Furthermore, dynamic mechanical analysis shows PCHMA‐CNT has a good mechanical properties as well as ultrahigh electrical resistance.