Granite plates as structural slabs in Brazilian buildings: application of reliability concepts

Polished finishing granites are greatly accepted for claddings because of the plates’ shape, design and color variety. The features depend on the geological conditions that occur during the formation process, which include the mineralogy of the stone, the fluids formed during the process, the grain size of the minerals and the way in which the minerals interact with each other. One of the noblest uses of stone plates is in non-adherent covering systems (without mortar), such as ventilated façades and pedestrian paving systems. Currently, the methodology for non-adherent systems uses the allowable stress design criteria. In recent years, the number of papers indicating reliability analysis as an important design tool for natural stones has increased. However, a lack of information concerning the design methodology still happens. Therefore, the structural properties assessed as complementing these studies were: compressive strength, three-point flexural tensile strength, Young’s modulus and Poisson’s ratio. A granite slab design example was also presented. First, the thickness of the plates was determined based on the formulation proposed by Timoshenko [Strength of materials (original language, Portuguese), Volume II. Editora Ao Livro Técnico S. A., Rio de Janeiro, 1977], using the allowable stress design criteria. Next, the reliability analysis was performed by Monte Carlo simulation. Results showed that the Desireé White granitic plate presented a higher reliability index than the Capão Bonito Red granitic plate. This result seems to be paradoxical, owing that the Capão Bonito Red presented a higher value of mean flexural strength than the Desireé White. The minimal safety factors to satisfy the target reliability value of 3.8 as recommended by the standard EN 1990:2002 (Eurocode) were found to be 2.61, 1.98 and 2.72, respectively, for the three stone types.     

Polychlorinated naphthalenes in air and snow in the Norwegian Arctic: a local source or an Eastern Arctic phenomenon?

PCNs were measured in air and snow during separate field campaigns at Ny-Alesund (April 2001) and Troms? (February/March 2003) in the Norwegian Arctic. Air concentrations ranged from 27 to 48 and 9 to 47 pg sigmaPCN m(-3) for Ny-Alesund (n=6) and Troms? (n=10), respectively. These concentrations (including the tri-chlorinated naphthalenes) greatly exceeded concentrations previously measured in the Canadian Arctic, but did fall within the upper range of concentrations observed over the eastern Arctic Ocean and regional seas. Local sources appear to be affecting concentrations observed at both sites, with the presence of several hexa-chlorinated naphthalenes at Troms? probably attributed to local/regional sources. Use of air mass back trajectories at Troms? revealed that background air concentrations in the Norwegian Arctic are likely to range between <9 and 20 pg sigmaPCN m(-3) and that contemporary concentrations derived close to potential sources (i.e. arctic towns) may equal or exceed those of PCBs. The mean concentration in surface snow was 350 and 240 pg sigmaPCN L(-1) (meltwater) (or 0.014 and 0.01 pg g(-1) (snow)) at Ny-Alesund and Troms?, respectively. The wide variation in concentrations observed between fresh snowfalls could be explained by different snow densities (as a surrogate of snow surface area), rather than attributed to varying air concentrations. A statistically significant inverse relationship was found between snow density and concentrations of tri- to penta-chlorinated homologues and compliments similar findings for the polychlorinated biphenyls (PCBs). This suggests that the vapour-sorbed quantity changes rapidly with snow ageing/compaction; with implications for the fate of these chemicals in the Arctic.     

Modelling air pollution for epidemiologic research--part II: predicting temporal variation through land use regression

Over recent years land use regression (LUR) has become a frequently used method in air pollution exposure studies, as it can model intra-urban variation in pollutant concentrations at a fine spatial scale. However, very few studies have used the LUR methodology to also model the temporal variation in air pollution exposure. The aim of this study is to estimate annual mean NO₂ and PM₁₀ concentrations from 1996 to 2008 for Greater Manchester using land use regression models. The results from these models will be used in the Manchester Asthma and Allergy Study (MAAS) birth cohort to determine health effects of air pollution exposure.The Greater Manchester LUR model for 2005 was recalibrated using interpolated and adjusted NO₂ and PM₁₀ concentrations as dependent variables for 1996-2008. In addition, temporally resolved variables were available for traffic intensity and PM₁₀ emissions. To validate the resulting LUR models, they were applied to the locations of automatic monitoring stations and the estimated concentrations were compared against measured concentrations.The 2005 LUR models were successfully recalibrated, providing individual models for each year from 1996 to 2008. When applied to the monitoring stations the mean prediction error (MPE) for NO₂ concentrations for all stations and years was -0.8 μg/m³ and the root mean squared error (RMSE) was 6.7 μg/m³. For PM₁₀ concentrations the MPE was 0.8 μg/m³ and the RMSE was 3.4 μg/m³.These results indicate that it is possible to model temporal variation in air pollution through LUR with relatively small prediction errors. It is likely that most previous LUR studies did not include temporal variation, because they were based on short term monitoring campaigns and did not have historic pollution data. The advantage of this study is that it uses data from an air dispersion model, which provided concentrations for 2005 and 2010, and therefore allowed extrapolation over a longer time period.     

Intrastate differences in residential water demand

To date, the results of studies which attempted to estimate residential water demand models have varied, but the source of these variations is not evident because the studies have applied different methodologies and data bases to different regions. The purpose of this paper is to develop models of residential water demand for watershed regions and test the null hypothesis that a single model is adequate to explain variations for all of the individual regions. Primary data collected from questionnaires and utility company records is used in a regression analysis to estimate a generalized water demand model for the state as well as one for each of the subregions. The null hypothesis is rejected which indicates that there are other factors which influence the demand for water and the use of a single model could result in biased estimates.     

Earthquake-induced net section fracture in brace connections — experiments and simulations

Results from six tests, finite element simulations and a synthesis of previous test programs on slotted end bracing connections are presented. The main objective of the research is to examine the deformation capacity of these connections, with the ultimate objective of minimizing the requirement for net section reinforcement that is often inconvenient from the perspective of fabrication. The experiments and simulations feature commonly used pipe specimens and end details. The main parameters investigated include the gusset plate thickness, the slot length and introduction of a wrap-around weld that eliminates the reduced section at the edge of the gusset plate. The results indicate that even without reinforcement, the connections offer adequate to excellent deformation capacity if they are provided with the wrap-around weld or if the net section strength is larger than the gross yield strength. This may be achieved in situations where shear lag in the connection is minimal, and where the area reduction due to the slot is small relative to the gross area. Design considerations are presented along with limitations of the study.     

Effects of copper, pH and hardness on the critical swimming performance of rainbow trout (Salmo gairdneri Richardson)

Critical swimming velocities of Salmo gairdneri at 12°C were determined in different combinations of copper; pH and hardness. Measurements were made after exposure for 0.5, 5, 10, and 30 days. When copper was not applied, hardness, pH and exposure time had no appreciable effect on critical performance. Copper had the greatest effect on swimming performance at 5 days of exposure. At pH 7.5–8.0, recovery from the initial depression was complete after 10 days of exposure, but critical swimming performance did not return to control levels in pH 6.0 treatments. For any given hardness, copper had a greater effect on critical speed at low than at high pH. A given copper treatment had a more pronounced effect at low than at high hardness.No distinction could be made among total, soluble, or extractable copper but predicted concentrations of 6 specific cupric ions varied with pH and hardness. Of these copper species, only Cu²⁺ and CuOH⁺ were found to be related significantly to critical performance.Oxygen consumption of trout was determined in different combinations of copper and pH. In the presence of copper the maximum oxygen consumption decreased and the energy expenditure for a given swimming speed increased.The above observations are discussed in relation to reported toxic actions of copper.     

Human response to blast-induced vibration and air-overpressure: an Indian scenario

Ground vibration (V_max) and air-overpressure/noise (p) are some of the negative effects of blasting. The associated human annoyance and complaints are expected to show an increasing trend in the future as there is no economically viable alternative to blasting in mines in India.A study of the human response to blasting in four mining localities across India has shown that the response is not simply political, as frequently assumed. It has been found that irrespective of those questioned, a basic concern for the safety of property was the main response. There was a greater response from the middle-aged and middle-educated while fewer women than men responded. Assuming that a 100% negative response from the inhabitants will translate into complaints, a methodology is suggested to take account of the human response criteria when considering blasting within 400 m of habitations.     

Spatial patterns of cadmium and lead deposition on and adjacent to National Park Service lands in the vicinity of Red Dog Mine, Alaska

Heavy metal escapement associated with ore trucks is known to occur along the DeLong Mountain Regional Transportation System (DMTS) haul road corridor in Cape Krusenstern National Monument, northwest Alaska. Heavy metal concentrations in Hylocomium splendens moss (n = 226) were used in geostatistical models to predict the extent and pattern of atmospheric deposition of Cd and Pb on Monument lands. A stratified grid-based sample design was used with more intensive sampling near mine-related activity areas. Spatial predictions were used to produce maps of concentration patterns, and to estimate the total area in 10 moss concentration categories. Heavy metal levels in moss were highest immediately adjacent to the DMTS haul road (Cd > 24 mg/kg dw; Pb > 900 mg/kg dw). Spatial regression analyses indicated that heavy metal deposition decreased with the log of distance from the DMTS haul road and the DMTS port site. Analysis of subsurface soil suggested that observed patterns of heavy metal deposition reflected in moss were not attributable to subsurface lithology at the sample points. Further, moss Pb concentrations throughout the northern half of the study area were high relative to concentrations previously reported from other Arctic Alaska sites. Collectively, these findings indicate the presence of mine-related heavy metal deposition throughout the northern portion of Cape Krusenstern National Monument. Geospatial analyses suggest that the Pb depositional area extends 25 km north of the haul road to the Kisimilot/Iyikrok hills, and possibly beyond. More study is needed to determine whether higher moss heavy metal concentrations in the northernmost portion of the study area reflect deposition from mining-related activities, weathering from mineralized Pb/Zn outcrops in the broader region, or a combination of the two. South of the DMTS haul road, airborne deposition appears to be constrained by the Tahinichok Mountains. Heavy metal levels continue to diminish south of the mountains, reaching a minimum in the southernmost portion of the study area near the Igichuk Hills (45 km from the haul road). The influence of the mine site was not studied.     

Bioaccumulation potential of polycyclic aromatic hydrocarbons in Daphnia pulex

The bioaccumulation potentials by aquatic biota from aqueous solution were determined for seven polycyclic aromatic hydrocarbons (PAH). The PAH were tested usingDaphnia pulex and consisted of the following compounds: naphthalene, anthracene, phenanthrene, pyrene, 9-methylanthracene, benz(a)anthracene and perylene. Bioaccumulation kinetics were described as a first order approach to equilibrium in a two-compartment model (water and Daphnia), using a two-stage technique to estimate uptake and elimination rates, while accounting for decreasing aqueous concentrations. Estimates of equilibrium concentration factors were obtained by two methods: (1) evaluating the kinetic model as t tends to infinity and (2) direct measurement of concentration factor at t =24 h.Estimations of equilibrium concentration factors obtained by the two methods were in good agreement, and increased dramatically with increasing molecular weight within the series of compounds. The calculated n-octanol-water partition coefficient was shown to be a good predictor of bioaccumulation potential of PAH in Daphnia. PAH were concentrated from a high of about 10,000-fold for benz(a)anthracene to a low of about 100-fold for naphthalene.