Observations on the changes in nitrate concentrations along streams in seven upland moorland catchments in Northeast Scotland

River water has been sampled under baseflow conditions in both summer and winter at c. 250-m intervals along the length of each of seven rivers in northeast Scotland, and the nitrate contents have been determined. The resultant data have been examined in the context of the nitrogen saturation hypothesis. Capacity of the catchment soils to retain nitrate was generally minimal in winter. Although biological uptake of nitrate was evident in summer, in the upper part of each catchment substantial nitrate leaching still occurred. The phenomenon was most marked in water draining from hill peats, except where these were conspicuously waterlogged. The results are discussed in the context of possible nitrogen saturation effects on upper catchment slopes.     

Oxygen consumption and activity of the white sucker (Catostomus commersoni), in lethal and nonlethal levels of the organochlorine insecticide, methoxychlor

The survival, oxygen consumption and spontaneous activity of suckers were determined at 15°C in water containing different concentrations of methoxychlor in ethanol, ethanol, and no added substances. A dynamic bioassay was used to estimate the 96 h LC50, which was found to be 0·0345 ppm. Routine oxygen consumption was determined in a continuous-flow respirometer, and the activity was recorded in separate experiments by measuring the water disturbance using silver wire electrodes.After 24 h fish exposed to untreated, ethanol-treated and 0.01 ppm methoxychlor-treated water had oxygen uptake rates which were relatively constant and near standard levels. At 0.10 ppm methoxychlor (lethal to all fish within 85 h), oxygen consumption rates were 2–3.5 × as high as those of control fish. Activity also greatly increased. The fish lost their balance along with the coordination between opercular and locomotor movements. Suckers that died in 0.04 ppm methoxychlor showed oxygen uptake rates and poisoning symptoms similar to 0.10 ppm treated fish, while those that survived this treatment had rates similar to control fish. The increase in ventilation which accompanies this hyperactivity may result in increased uptake of insecticide and thereby explain the irreversible nature of the response.     

Permeability changes in granite with crack growth during immersion in hot water

Permeability tests and observation of induced, as well as inherent, cracks have been carried out to quantitatively explain permeability changes in granite taking place during a weathering test in terms of micro-structure by cracks. To this end, permeability tensors were estimated from observations of crack systems using the Replica Method and of the crack apertures with a scanning electron microscope. The following conclusions were reached: the drastic increase in permeability around an immersion of 1000 d in 90°C water could not be explained by the existence of a percolation threshold because all the specimens were percolative in the sense that the traces of crack tensor were above the critical density for percolation. On the other hand, SEM observation revealed that, with immersion, crack apertures widened and their distribution spread. Permeability estimated using the third (not the first) moment of observed apertures showed the increase in measured permeability well. When evaluating the connectivity parameter λ to give a quantitative accordance between measured and estimated permeability, it had a constant value as low as 0.17, irrespective of the immersion period, in spite of the higher density of micro-cracks than the percolation threshold. It can be said that, in considering the natural three-dimensional crack system, the third moment of physical apertures plays a more important role in predicting the permeability and λ is greatly affected by the spread of crack apertures.     

Boston harbor outfall tunnel: An environmental imperative

In February 1989, the Massachusetts Water Resource Authority (MWRA) began the design and construction of a 15.3-km subsea tunnel and ocean riser system to discharge effluent in conjunction with the design and construction of a large secondary treatment plant. The court-mandated schedule required the tunnel and risers to be completed in July 1995. The paper discusses the project from the viewpoints of management, concept design and construction methods, including the ocean riser system. Key to th success of the project is the accuracy of the location of the risers. The design calls for a final tunnel alignment to be driven within 10 m of the riser shafts, beginning at a distance of 13.1 km from shore.     

Radiocesium in muscle tissue of reindeer and pike from northern Sweden before and after the Chernobyl accident. A retrospective study on tissue samples from the Swedish Environmental Specimen Bank.

After the Chernobyl accident in April 1986, considerable deposition of radionuclides occurred regionally in eastern, central and northwestern Sweden. Locally, the fallout of radiocesium exceeded the remainder from atmospheric nuclear weapons tests by several magnitudes. Since the end of the 1960s samples of organs from various plant and animal species, annually collected at different localities, have been preserved in the Swedish Environmental Specimen Bank (ESB). In this work samples from the ESB have been used for retrospective studies of radioactive pollution. The activities of Cs-134 and Cs-137 in muscle tissues from reindeer, Rangifer tarandus, and pike, Esox lucius, preserved in the ESB, were measured. The samples were collected annually; the reindeer at three localities in northern Sweden and the pike at one of them. In material collected prior to the Chernobyl accident, the levels of Cs-137 were 57-180 Bq/kg in reindeer and 14-24 Bq/kg in pike, fresh weight basis. These levels relate to earlier nuclear bomb tests. A significant decrease was found in pike during the pre-Chernobyl period (1971-86). In post-Chernobyl samples the burden of Cs-137 varied from amounts equal to the former levels in the northernmost locality and up to 80 times higher for the maximum values in the southernmost locality. The highest value recorded was 18,425 Bq/kg in reindeer. The geographic variations in reindeer from Chernobyl fallout were in accordance with the pattern of deposition estimated by aircraft surveys performed in May 1986. The ratio between 'new' and 'old' radiocesium burdens in pike, caught in 1987, approached the corresponding ratio for reindeer grazing in the precipitation area of the lake; 33 and 19, respectively.     

Geomechanical model simulation for the varied rock formations of the Kadana dam foundation,Gujarat, India

Bulletin of Engineering Geology and the Environment - Precambrian layered rocks consisting of quartzites, phyllites and metagreywackes of the Aravallis having a large variation in thickness,...     

Dynamic analysis and optimal feedback control synthesis applied to biological waste treatment

The dynamics and optimal feedback control of biological waste treatment processes are examined. Modern feedback control theory is applied and results are obtained for both proportional and proportional plus integral control. A dynamic mathematical model of the system is developed by employing a Monod kinetic model, which is modified to account for endogenous metabolism, and a complete mixing flow model in the growth chamber. The feedback control is implemented via the flow rate so as to maintain desired effluent concentrations. External disturbances which cause changes in substrate concentration and/or cell concentration are considered and optimal control effort is applied. Results are also presented for impulse and step changes in the influent substrate concentration. It is found that by changing the values of the weighting factors in the objective function, it is possible to obtain good control of either the effluent substrate concentration or cell concentration.     

The development of macrolayer thickness of water in the pool boiling regime

ABSTRACT

The main purpose of this study is to analyse the phenomenon of pool boiling in water over a horizontally placed copper tube heater of 28?mm diameter. The experiment has been carried out to observe the bubble growth and departure characteristics for the heat flux range up to 40,000?W/m². The entire process is being recorded by a digital camera at different time intervals. The measured parameters have been used to determine the initial layer thickness, macro layer thickness and critical heat flux and validated with models proposed in the literature.     

Classic and novel brominated flame retardants (BFRs) in common sole (Solea solea L.) from main nursery zones along the French coasts

Brominated flame retardants (BFRs) were investigated in juvenile common sole from nursery zones situated along the French coast in 2007, 2008 and 2009. Extensive identification was performed with regard to PBDEs, novel BFRs 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE) and decabromodiphenylethane (DBDPE), and other non-PBDE BFRs, namely, hexabromobenzene (HBB) and 2,2′,4,4′,5,5′-hexabromobiphenyl (BB-153). Polybrominated diphenyl ether (PBDE) concentrations (Σ 14 congeners) ranged from 0.01 ng/g to 0.16 ng/g wet weight (ww) in muscle, and 0.07 ng/g to 2.8 ng/g ww in liver. Concentrations were in the lower range of those reported in the literature in other European locations. Lower PBDE concentrations, condition indices and lipid contents were observed in the Seine estuary in 2009, possibly in relation to a lower water flow. The PBDE patterns and ratios we observed suggested that juvenile sole have a relative high metabolic degradation capacity. Non-PBDE BFRs were detected at lower levels than PBDEs, i.e., within the < method detection limit - 0.005 ng/g ww range in muscle, and < method detection limit - 0.2 ng/g ww range in liver. The data obtained is of particular interest for the future monitoring of these compounds in the environment.     

Particles and vegetation: implications for the transfer of particle-bound organic contaminants to vegetation

This paper presents a comprehensive review of the mechanisms responsible for the transfer of atmospheric particulate deposition and soil particulate re-suspension onto vegetation. The nature of atmospheric aerosols and dry/wet particulate deposition are reviewed, together with information from the literature on radionuclides as tracers of the air particle/soil particle to vegetation transfer processes. Information from these fields is used to make inferences about the potential significance of these pathways in supplying particle-bound semi-volatile organic chemicals (e.g. polycyclic aromatic hydrocarbons, polychlorinated dibenzo-p-dioxins and dibenzofurans, polychlorinated biphenyls) to vegetation. Retention of compounds on particles brought to the above-ground plant surfaces is discussed. In the absence of definitive field/experimental studies, calculations are made drawing on the literature data to estimate the contributions of atmospheric and soil particle-bound organic contaminants to the plant concentration. These show that depending on the site-specific, species-specific and compound-specific scenarios considered, particulate-bound inputs may be negligible or may dominate the supply of organic contaminants to the above-ground portion of plants. However, field/experimental studies and direct measurements are needed to provide reliable quantitative data on this topic.