Effects of heating in air and chlorine atmosphere on the crystalline structure of pure Ta2O5 or mixed with carbon

Structure changes undergone by pure amorphous hydrated tantalum oxide mixed with different types of carbon when heated in air or chlorine atmospheres were monitored by X-ray diffraction (XRD) and scanning electronic microscopy (SEM). Heating in air of pure Ta2O5 causes the appearance of the hexagonal structure -Ta2O5 at 973 K and the ortho-rhombic structure -Ta2O5 at 1173 K. Heating in chlorine atmosphere markedly lowers the temperature at which transformation to the orthorhombic phase occurs. This effect is attributed to recrystallization of tantalum oxide from tantalum chloride and oxygen, both in gaseous phase, formed in a previous chlorination step of the amorphous oxide. When the thermal treatment is performed in chlorine atmosphere the presence of carbon permits the detection of the hexagonal form at 753 K; this temperature varies with the type of carbon and the oxide : carbon ration. © 1998 Kluwer Academic Publishers     

A Multidirectional Occlusion Shading Model for Direct Volume Rendering

In this paper, we present a novel technique which simulates directional light scattering for more realistic interactive visualization of volume data. Our method extends the recent directional occlusion shading model by enabling light source positioning with practically no performance penalty. Light transport is approximated using a tilted cone‐shaped function which leaves elliptic footprints in the opacity buffer during slice‐based volume rendering. We perform an incremental blurring operation on the opacity buffer for each slice in front‐to‐back order. This buffer is then used to define the degree of occlusion for the subsequent slice. Our method is capable of generating high‐quality soft shadowing effects, allows interactive modification of all illumination and rendering parameters, and requires no pre‐computation.     

Predictive functional control based on an adaptive fuzzy model of a hybrid semi-batch reactor

In this paper a new approach to the control of a nonlinear, time-varying process is proposed. It is based on a recursive version of the fuzzy identification method and predictive functional control. First, the recursive fuzzy identification method is derived, after which it is used in connection with fuzzy predictive functional control to construct an adaptive fuzzy predictive functional controller. The adaptive FPFC is then tested on a nonlinear, time-varying, semi-batch reactor process and compared with the standard FPFC, which uses non-adaptive fuzzy model. The simulation results are promising; they indicate that the control of time-varying, nonlinear processes with the FPFC can be improved with the use of an adaptive fuzzy model. An improvement in reference tracking and disturbance rejection can be observed, but the main advantage is the reduced number of switchings between hot and cold water. This is an important improvement in the case of real applications.     

An integrated domain analysis approach for teleoperated systems

Teleoperated systems for ship hull maintenance (TOS) are robotic systems for ship maintenance tasks, such as cleaning or painting a ship’s hull. The product line paradigm has recently been applied to TOS, and a TOS reference architecture has thus been designed. However, TOS requirements specifications have not been developed in any rigorous way with reuse in mind. We therefore believe that an opportunity exists to increase the abstraction level at which stakeholders can reason about this product line. This paper reports an experience in which this TOS domain was analyzed, including the lessons learned in the construction and use of the TOS domain model. The experience is based on the application of extensions of well-known domain analysis techniques, together with the use of quality attribute templates traced to a feature model to deal with non-functional issues. A qualitative research method (action research) was used to carry out the experience.     

A multivariable control scheme in a two-stage anaerobic digestion system described by partial differential equations

This paper deals with the design and application of a nonlinear multivariable controller in an anaerobic digestion system (AD) carried out in two interconnected fixed bed bioreactors. The proposed control scheme is derived from a mathematical model of the AD system described by a set of partial differential equations and consists of an estimator and two nonlinear control laws. The first law is developed to regulate the volatile fatty acids in the first bioreactor while the second aims at maintaining the chemical oxygen demand at predetermined set-points in the second bioreactor. The performance of the control algorithm is evaluated via numerical simulations in the face of load disturbances, parameter kinetic uncertainties and set-point changes. Stability and convergence properties of the proposed control scheme are also addressed in this paper.     

Aerodynamic optimization via multi-objective micro-genetic algorithm with range adaptation,knowledge-based reinitialization,crowding and ε-dominance

In this study, an optimization of the airfoil of a sailplane is carried out by a recently developed multi-objective genetic algorithm based on microevolution, containing crowding, range adaptation, knowledge-based reinitialization and ε-dominance. Its efficiency was tested on a set of test problems. The results are encouraging, suggesting that very small populations can be used effectively to solve real-world multi-objective optimization problems in many cases of interest.     

Applying intelligent agents and semantic web services in eGovernment environments

The increasing volume of eGovernment‐related services is demanding new approaches for service integration and interoperability in this domain. Semantic web (SW) technologies and applications can leverage the potential of eGovernment service integration and discovery, thus tackling the problems of semantic heterogeneity characterizing eGovernment information sources and the different levels of interoperability. eGovernment services will therefore be semantically described in the foreseeable future. In an environment with semantically annotated services, software agents are essential as the entities responsible for exploiting the semantic content in order to automate some tasks, and so enhance the user's experience. In this paper, we present a framework that provides a seamless integration of semantic web services and intelligent agents technologies by making use of ontologies to facilitate their interoperation. The proposed framework can assist in the development of powerful and flexible distributed systems in complex, dynamic, heterogeneous, unpredictable and open environments. Our approach is backed up by a proof‐of‐concept implementation, where the breakthrough of integrating disparate eGovernment services has been tested.     

Convergence with a fixed regulator in lattice ordered groups and applications to MV-algebras

A convergence with a fixed regulator v in lattice ordered groups is applied to MV-algebras. For each Archimedean MV-algebra A there exists a v-Cauchy completion A ^* and it is uniquely determined up to isomorphisms over A. The relation between the Dedekind completion A ^∧ of A and A ^* is established. There is solved a question of the existence of the greatest v-Cauchy complete ideal of A.     

Estimation and setting starting values in ARMA algorithms

For the given observations set of the ARMA (autoregressive moving average) process, the likelihood function depends, not only on model parameters, but on the starting values of the input and output. Therefore, it is called theconditional likelihood function. Theunconditional likelihood function can be obtained in two ways. The first is to set the starting values to zero, as is often done, and the second is to set them to the properly estimated values. The difference between these two types of likelihood functions is significant when the given data sequence is short, and any of the zeros of the moving average part is close to the boundary of the unit circle.In this paper the direct method of starting value estimation and its application to two off-line ARMA estimation algorithms, the maximum likelihood (ML) algorithm and the iterative inverse filtering (ITIF) algorithm, is proposed. Experimental results prove both increased efficiency and stability of these algorithms.The importance of setting the starting values properly is also significant when the recursive algorithm, with previously estimated parameters, has to be restarted. The advantage of the proposed reinitialization method is shown on the recursive lattice algorithm working in the block mode.     

Conversion electron Mössbauer spectroscopy of the surface crystallization of the Fe75Co9B16 amorphous alloy

Using a new design of helium-methane gas-flow detector of conversion electrons for Mössbauer spectroscopy, non-uniform nucleation of the primary -Fe-Co phase on both contact and free surfaces of the Ar(+H₂) annealed amorphous Fe₇₅Co₉B₁₆ alloy was observed in its early crystallization stage. In this state the amount of crystalline phase on the contact ribbon side surpasses that on the free one by a factor of three, whereas no traces of volume crystallization were observed in the transmission spectra. By applying ion implantation to both ribbon surfaces, a slight reduction of the crystalline phase contribution was found. Magnetic domain structure observations were performed in order to evaluate the influence of surface crystallization on magnetic properties.