Structural/texture evolution of CaO/MCM‐41 nanocatalyst by doping various amounts of cerium for active and stable catalyst: Biodiesel production from waste vegetable cooking oil

In present work, the aim of producing biodiesel from waste cooking oil was pursued by doping the cerium element into the MCM‐41 framework as catalyst with various Si/Ce molar ratio (5, 10, 25, 50, and Ce = 0). The catalytic performance and stability improved by employing the ultrasound irradiation in active phase loading step of catalyst preparation. The physicochemical characteristics of synthesized samples were investigated using various techniques as follows: Brunauer‐Emmett‐Teller (BET), X‐ray powder diffraction (XRD), Fourier transfer infrared (FTIR), energy‐dispersive X‐ray spectroscopy (EDX), transmission electron microscopy (TEM), and field emission scanning electron microscope (FESEM). The XRD patterns along with the results of FTIR and BET analysis revealed the MCM‐41 framework destruction while increasing the Ce content. The FESEM images of the nanocatalysts illustrated a well distribution and uniform morphology for the Ca/CeM (Si/Ce = 25). The particle size and size distribution of the Ca/CeM (Si/Ce = 25) were subsequently determined by TEM and FESEM images. The activity of fabricated nanocatalysts was evaluated by measuring the free acid methyl ester (FAME) content of produced biodiesel. The tests were carried out at constant operational conditions: T = 60°C, catalyst loading = 5 wt%, methanol/oil molar ratio = 9, and 6‐hour reaction time. A superior activity was observed for Ca/CeM (Si/Ce = 25) among other nanocatalysts with 96.8% conversion of triglycerides to biodiesel. The mentioned sample was utilized in five reaction cycles, and at the end of the fifth cycle, the conversion reached to 91.5% which demonstrated its significant stability.     

Theoretical and experimental investigation of a heat pipe heat exchanger for energy recovery of exhaust air

Heat pipes and two-phase thermosyphon systems are passive heat transfer systems that employ a two-phase cycle of a working fluid within a completely sealed system. Consequently, heat exchangers based on heat pipes have low thermal resistance and high effective thermal conductivity, which can reach up to the order of (10⁵ W/(m K)). In energy recovery systems where the two streams should be unmixed, such as air-conditioning systems of biological laboratories and operating rooms in hospitals, heat pipe heat exchangers (HPHEs) are recommended. In this study, an experimental and theoretical study was carried out on the thermal performance of an air-to-air HPHE filled with two refrigerants as working fluids, R22 and R407c. The heat pipe heat exchanger used was composed of two rows of copper heat pipes in a staggered manner, with 11 pipes per row. Tests were conducted at different airflow rates of 0.14, 0.18, and 0.22 m³/h, evaporator inlet-air temperatures of 40, 44, and 50°C, filling ratios of 45%, 70%, and 100%, and ratios of heat capacity rate of the evaporator to condenser sections (C_e/C_c) of 1 and 1.5. For HPHE's steady-state operation, a mathematical model for heat-transfer performance was set and solved using MATLAB. Results illustrated that the heat transfer rate was in direct proportion with the evaporator inlet-air temperature and flow rate. The highest HPHE's effectiveness was obtained at a 100% filling ratio and (C_e/C_c) of 1.5. The predicted and experimental values of condenser outlet-air temperature were in good agreement, with a maximum difference of 3%. HPHE's effectiveness was found to increase with the increase in evaporator inlet-air temperature and number of transfer units (NTU) and with the decrease in airflow rate, up to 33% and 20% for refrigerants R22 and R407c, respectively. Refrigerant R22 was the superior of the two refrigerants investigated.     

Microstructure and Optical Bandgap of Cobalt Selenide Nanofilms

Semiconductors - The purpose of this research is to explore the properties of CoSe nanostructured thin films on glass substrates prepared by a chemical solution deposition method. Special attention...     

Selective properties of polyester and cotton/polyester fabrics gamma radiation grafted with different binary mixtures of vinyl monomers

Radiation graft copolymerization of individual and comonomer mixtures of vinyl monomers onto polyester and cotton/polyester fabrics by the mutual method has been investigated. The effect of factors that may affect the grafting yield, such as solvent composition, comonomer mixture composition and radiation dose, have been examined. Suitable conditions that gives the highest graft yield without altering the original properties of the substrates are reported briefly. An attempt was made to determine the graft yield fraction from each monomer in the final graft copolymer in the case of grafting comonomer mixtures by using elemental analysis of nitrogen. Moreover, the results of elemental analysis were used to determine the reactivity ratios of the vinyl monomers. Some selective properties of the graft copolymers of polyester and cotton/polyester with the individual and comonomer mixtures have been investigated. The studied properties are the dye affinity for various dyestuffs and the mechanical properties in terms of tensile strength, elongation at break and Young's modulus. In general and regardless of the system used, grafting improves the dyeability of polyester and cotton/polyester with basic, vat, acid and disperse dyes. Also, it was found that improvement in dyeing and mechanical properties depends essentially on the composition of the graft copolymer and not on the composition of the feed comonomer solution or the total graft yield. © 1999 Society of Chemical Industry     

A simultaneous planning of production and scheduling operations in flexible flow shops: case study of tile industry

The aim of this paper is to study a simultaneous lot-sizing and scheduling in multi-product, multi-period flexible flow shop environments. A new mixed integer programming (MIP) model is proposed to formulate the problem. The objective function includes the total cost of production, inventory, and external supply. In this study, in case of not meeting the demand of customers, this demand should be met by foreign suppliers in higher price. Due to the high computational complexity of the studied problem, a rolling horizon heuristic (RHH) and particle swarm optimization algorithm (PSO) are implemented to solve the problem. These algorithms find a feasible and near-optimal from production planning and scheduling. Additionally, Taguchi method is conducted to calibrate the parameters of the PSO algorithm and select the optimal levels of the influential factors. The computational results show that the algorithms are capable of achieving results with good quality in a reasonable time and PSO has better objective values in comparison with RHH. Also, the real case study for tile industry with real features is applied. Sensitivity analysis is used to evaluate the performance of the model.     

The non-cooperative game theory for trades in B2B electronic market

B2B electronic market facilitates the transactions among businesses. It consists of buyers, sellers, and the market owner. But most of these markets could not generate the expected profits for all market participants. In this paper, expected profit for each market participant has been considered in a neutral market with double auction. Based on these profit functions, optimal quantities of bids and offers are determined for buyers and sellers. Then, a model based on game theory is proposed that leads to recognize optimal strategies for game players that include buyers, sellers, and the market owner. Using the optimal strategies will satisfy the game participants and maximize their benefits. Additionally, a numerical example is illustrated to better describe the proposed model.     

Optimal per cent by weight of elements in diagnostic quality radiation shielding materials

By increasing the usage of radiation in all aspects of lives, the human body is becoming more exposed to ionising radiation. The purpose of this study is to find the optimal radiation shielding materials to protect humans from the radiation hazards of radiation. Some elements and compounds such as Ag, Bi, Pb, W, BaSO(4) were chosen on the basis of their attenuation coefficients and other characteristics to produce optimised radiation shielding compounds. Multi-objective non-dominated sorting genetic algorithm-II was used to optimise the weight fraction of the elements in compounds based on the dose equivalent rate, shield weight and cost. Consequently, sets of suitable compounds were obtained depending on various applications for energy 0.06 and 0.15 MeV. In addition, optimised lead free compounds were obtained. The results presented in a series of graphs should enable radiation shield designers to choose an appropriate combination according to their requirements.     

Horizontal nutrient flows and balances in irrigated urban gardens of Khartoum, Sudan

The role of urban agriculture (UA) for the supply of fresh vegetables, fruits and meat for local markets is well known. The periodically flooded Gerif soils on the River Nile banks in the core of Khartoum city harbour vegetable gardens that supply perishable leafy vegetables with a short life cycle. In an effort to assess their sustainability and possible negative environmental impact we used a horizontal balance approach to determine the nutrient use efficiency of four intensively cropped UA gardens. Two of the gardens were located in downstream lowlands (L1 and L2) and the other two belonged to the upstream highlands (H1 and H2). The river sediments contributed on average 873 kg nitrogen (N), 6.5 kg phosphorus (P), 6.8 kg potassium (K) and 8,317 kg carbon (C) per hectare in lowland gardens, while only 289, 1.6, 2.5 and 1,938 kg N, P, K and C ha⁻¹ reached the highlands. The farmers’ management in all four gardens resulted in horizontal N and C surpluses of 75–342 kg N ha⁻¹ year⁻¹ and 798–6,412 kg C ha⁻¹ year⁻¹, in contrast to P and K for which negative balances up to −45 kg P ha⁻¹ year⁻¹ and −583 kg K ha⁻¹ year⁻¹ were recorded. While the River Nile floods as important N and C source contribute significantly to soil fertility maintenance, the negative P and K balances call for a better integration of UA gardening with livestock husbandry and the regular addition of animal manure in these cropping systems.     

Electrochemical synthesis and in situ spectroelectrochemistry of conducting polymer nanocomposites. I. polyaniline/TiO2, polyaniline/ZnO,and polyaniline/TiO2+ZnO

The polyaniline (PAn), polyaniline/titanium dioxide (PAn/TiO₂), polyaniline/zinc oxide (PAn/ZnO), and a novel conducting polymer nanocomposites, polyaniline/titanium dioxide + zinc oxide (PAn/TiO₂+ZnO), were synthesized by in situ electropolymerization and potential cycling on gold electrode. The PAn and nanocomposite films were characterized by cyclic voltammetry, Fourier transform infra‐red (FTIR) spectroscopy, in situ resistivity measurements, in situ UV–Visible, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The differences between cathodic and anodic peaks of three redox couples were obtained for PAn and polymeric nanocomposite films. During cathodic and anodic scans, the shift of potential was observed for polymer nanocomposite films. The characteristic FTIR peaks of PAn were found to shift to lower wavelengthsin polymer nanocomposite films. These observed effects have been attributed to interaction of TiO₂, ZnO, and TiO₂+ZnO particles with PAn molecular chains. Significant differences from in situ resistivity of PAn and nanocomposite films were obtained. The resistance of PAn/TiO₂, PAn/ZnO, and PAn/TiO₂+ZnO films were found to be smaller than the PAn film. The in situ UV–Visible spectra for Pan and polymer nanocomposite films were studied. The results show the intermediate spectroscopic properties between PAn and polymer nanocomposite films. The morphological analyses of PAn and nanocomposite films have been investigated. The nanocomposites SEM and TEM micrographs suggest that the inorganic semiconductor particles were incorporated in organic conducting polymer, which consequently modifies the morphology of the films significantly. POLYM. COMPOS., 35:351–363, 2014. © 2013 Society of Plastics Engineers     

Dynamic analysis of charge transport in fluidized bed electrodes: Impedance techniques for electroactive beds

Impedance techniques are used to investigate the average dynamic behaviour of a fluidized bed of gold-coated beads in potassium ferri-ferrocyanide/NaOH solution. A transmission line is used as a model. The main features of the fluidized bed are correctly interpreted, especially the capacitive high frequency impedance related to the intermittent contacts between the particles. The use of a nonuniform transmission line is attempted in order to study the influence of a distance dependent charge transfer mechanism in the bulk of the fluidized bed.