An Experimental Investigation on the Copper Recovery from Flotation Tailing Dams by Reflotation

In this study, the possibility of copper recovery from flotation tailing of Mazraeh copper mine was investigated. Magnetic separation method was used for concentration of non-magnetic minerals, especially copper bearing minerals, from iron minerals. As a result, copper grade increased up to 0.18% and its recovery reached 86%. Due to mineral’s oxidized surface, accompanied oxide minerals and large quantities of fine particles (i.e. about 80% and 57% were finer than 37 and 15 μm in the sample, respectively), flotation of copper was very difficult. In this regard, the effects of important factors including solution pH, type and collector dosage, dispersant, impeller speed, type of frother, percent solid and surface sulfurization were studied. It was concluded that copper recovery of 52% and copper grade of 2.7% could be obtained under following conditions: pH: 11, Collector: Z11 with 40 g/t, Impeller speed: 1400 rpm, Frother: A65, percent solid: 10% and surface sulfurization by Na₂S with 1000 g/t. On the other hand, the addition of sodium silicate as a dispersant showed a negative effect on the flotation performance.     

Profiling of hydrophilic proteins from Olea europaea olive pollen by MALDI TOF mass spectrometry

The antigenic profile of Olea europaea pollen from different Mediterranean cultivars was obtained by MALDI mass spectrometry. A simple procedure of chemical fractionation of the whole antigen extract was developed, whereby less complex, or pure, fractions of antigen candidate were obtained prior to mass spectrometric analysis. Some of the features of protein structure and distribution probably depend on cultivar adaptation to the environment. The profilings of pollen proteins thus obtained allow the distinction of the analyzed cultivars into three distinct groups: (i) those characterized by a low Ole e 1 content; (ii) those over-enriched in Ole e 1 and (iii) that containing Ole e 3 and Ole e 7 only. The latter consists of at least four isoforms differing by the degree of glycosilation. These results demonstrate that the proposed experimental procedure, can supply valuable information on the antigens' micro heterogeneity.     

Modeling the free convection heat transfer in a partitioned cavity using ANFIS

In this paper, an adaptive neuro-fuzzy inference system (ANFIS) is used to predict the free convection in a partitioned cavity consisting of an adiabatic partition. The main focus of the present paper is to consider the effects of partition angle and Rayleigh number variation on average heat transfer in the partitioned cavity. The training data for optimizing the ANFIS structure is obtained experimentally. For the best ANFIS structure obtained in this study, the mean relative errors of the train and test data were found to be 0.055% and 1.735% respectively, which shows that ANFIS can predict the experimental results precisely.     

Enhancing Superconductivity in Low-dimensional TlBa2Ca2Cu3O10?δ System

Mg-doped Tl(Ba_2?x Mg _x )Ca₂Cu₃O_10??? (x=0, 0.25, 0.50, 0.75, 1.0, 1.25, 1.5) superconductors are synthesized at the normal pressure and the possible mechanism of superconductivity in these compounds is studied. Tl(Ba_2?x Mg _x )Ca₂Cu₃O_10??? samples have shown an orthorhombic crystal structure and their c-axis length decreases up to Mg-doping of x=0.75 and then increases up to Mg-doping of x=1.50. In these studies we have investigated the role of decreased thickness of charge reservoir layer on the mechanism of superconductivity. The T _c (R=0) in as-prepared Tl(Ba_2?x Mg _x )Ca₂Cu₃O_10??? (x=0, 0.25, 0.5, 0.75, 1.0, 1.25) samples was 100, 98, 101, 102, 100, 96?K and in the oxygen post-annealed samples the T _c (R=0) is observed around 99, 98, 108, 127, 109, 97?K, respectively. The magnitude of the superconductivity after Mg-doping is improved in Tl(Ba_2?x Mg _x )Ca₂Cu₃O_10??? (x=0.25, 0.5, 0.75, 1.0, 1.25) samples. It was observed from the FTIR absorption measurements that the phonon modes related to CuO₂ planar oxygen atoms are hardened with the doping of Mg in the charge reservoir layer. These studies have shown that the thickness of charge reservoir layers decreases with Mg-doping, which most likely makes the charge transfer mechanism more efficient, which increases the magnitude of superconductivity in the final compound.     

Large scale synthesis of single-crystal and polycrystalline boron nitride nanosheets

Boron nitride nanosheets (BNNSs) have an identical crystal structure and similar lattice parameter to those of graphene sheets. However, growing quality BNNSs consisting of only several atomic layers remains a challenge. Here, we report on the synthesis of BNNSs at a temperature of 350 °C using a CO₂ pulsed laser plasma deposition (CO₂-PLD) technique by irradiating a pyrolytic hexagonal boron nitride (h-BN) target. The deposition was performed either in vacuum at a pressure of 0.2 Pa, for which we obtained polycrystalline BN, or in hydrogen (H₂) atmosphere at a pressure of 26 Pa for which we obtained single-crystal BNNSs. The presence of H₂ seems to minimize the side effects of sputtering and the material shows higher purity and better crystallinity. High resolution transmission electron microscopy (HRTEM) showed the sheets to be mostly defect-free and to have the characteristic honeycomb structure of six-membered B₃-N₃ hexagon. HRTEM, electron diffraction, X-ray diffraction, Raman scattering, and Fourier transform infrared spectroscopy clearly identified h-BN.     

Acetanilide-loaded injectable hydrogels with enhanced bioactivity and biocompatibility for potential treatment of periodontitis

Chronic periodontitis poses long-term challenges in dentistry, requiring the development of innovative dental composites with biocompatibility, bone regeneration, and antibacterial properties. This study focuses on synthesis of novel injectable thermoresponsive hydrogels composed of chitosan, sodium bicarbonate, bioactive glass (20 and 40% w/w), and acetanilide drug (0.3 and 0.6% w/w). These hydrogels exhibit a sol–gel transition at 37°C, addressing periodontal challenges with reduced gelation time. The smooth flow characteristic was evaluated through 17-22 gauge syringe needles at low temperature. Rheological studies demonstrated pseudoplastic behavior, with viscosity decreasing as shear rate increases. Fourier transform infrared and x-ray diffraction analysis confirmed the bioactivity of hydrogels, forming a bone-like apatite layer in simulated body fluid. The drug-loaded hydrogels demonstrated promising in vitro antibacterial properties against dental pathogens, specifically Staphylococcus aureus and Pseudomonas aeruginosa. Drug dissolution analysis revealed relatively high release rate at 37°C, highlighting its role in rapidly eliminating bacterial colonies at the target site, while the subsequent sustained release contributes to the prevention of infection recurrence. Finally, biocompatibility was assessed with fibroblast, where the cells were observed anchoring into the polymeric chains of hydrogel through extended filopodia.     

Significant improvement of semi-solid microstructure and mechanical properties of A356 alloy by ARB process

Accumulative roll bonding (ARB) process was used in this study as an effective method for manufacturing high-strength, finely-dispersed and highly-uniform A356 alloy. It was found that when the number of ARB cycles was increased, the uniformity of silicon particles in the aluminum matrix improved, the particles became finer and spheroider and therefore, the tensile strength (TS) and ductility of the samples improved. The microstructure of the manufactured A356 alloy after five ARB cycles indicated a totally modified structure such that it's TS and elongation values reached 269 MPa and 5.3% which were 2.6 and 2.5 times greater than those of the as-cast material, respectively. Also, the hardness value increased from 55.4 (for as-cast sample) to 100.2 HV (after the fifth cycle of ARB), and registered 81% increase.     

The dual-edge alignment technique with improved spur reduction effects in ring oscillators

In this paper, the technique of dual-edge phase-alignment and its effects on ring oscillators are presented. This technique provides resetting of the built-up jitter at both rising and falling edges of a clean aligning signal named as the reference. Using signals and systems theory, the effect of the technique on the spurs due to the aligning reference signal is completely analyzed. We show that adding properly the dual-edge aligning feature to phase-aligned ring oscillators cause the spurs in the neighborhood of the carrier to disappear. First, the validity of the results obtained from the derived analytical equations is verified through simulations using MATLAB. Then a complete circuit considering realistic models for its components is simulated in TSMC RF CMOS 0.18um process using ADS for further validation.     

Identification and Field Evaluation of the Sex Pheromone of <Emphasis Type="Italic">Orthaga achatina</Emphasis> (Lepidoptera: Pyralidae)

Orthaga achatina (Lepidoptera: Pyralidae) is the most serious pest in south China of camphor trees, Cinnamomum camphora (L.) Presl, an important urban tree species. Gas chromatography-electroantennographic detection (GC-EAD) of the sex pheromone of O. achatina showed three EAD-active components. Coupled gas chromatography/mass spectrometry analyses identified these as (Z)-11-hexadecenol (Z11–16:OH), (Z)-11-hexadecenyl acetate (Z11–16:OAc), and (3Z,6Z,9Z,12Z,15Z)-tricosapentaene (Z3,Z6,Z9,Z12,Z15–23:H). In field tests using different combinations of the three compounds, male moths were attracted to a mixture of Z11–16:OAc and Z3,Z6,Z9,Z12,Z15–23:H, but less attracted to other blends. Further field tests with different ratios of the two compounds determined the optimal ratio of the binary blend as 500:250. The addition of Z11–16:OH to Z11–16:OAc, or to the binary mixture of Z11–16: OAc and the pentaene did not yield higher catches. This shows that O. achatina uses a mixture of Type I and Type II sex pheromone components. Orthaga achatina is the third Pyraloidea species found to utilize Z3,Z6,Z9,Z12,Z15–23:H as a sex pheromone component.     

Raman calibration of the HT-7 yttrium aluminum garnet Thomson scattering for electron density measurements

A multipulse neodym doped yttrium aluminum garnet laser Thomson scattering system calibrated by the anti-Stokes rotational Raman scattering from nitrogen gas had been developed in the HT-7 superconducting Tokmak. By virtue of this system, measured electron density results of the plasma were obtained. The results showed good repeatability and its total uncertainty was estimated to be +/-18%.