The polymerization reaction of cyclic siloxanes on a hard disk under static conditions

Microsystem Technologies - The reaction behavior of the siloxane on carbon materials was investigated. Under the exposure of the low molecular cyclic siloxane such as D4 (octamethyl...     

Emission of dispersed‐type inorganic EL devices with frequency‐variable high‐voltage oscillation circuit

Dispersed‐type inorganic electroluminescent (EL) devices composed of a transparent electrode, a phosphor, a dielectric, and a back electrode were prepared under various conditions using a zinc sulfide (ZnS)‐based phosphor. Additionally, a voltage/frequency variable circuit was designed. A compact high‐voltage/frequency variable circuit including three modules for boosting, frequency conversion, and voltage conversion was designed. A 140 V_pp voltage and a frequency in the range of 270 Hz to 2.4 kHz can be controlled by this circuit. The emission has begun to be observed at a voltage about 60 V_pp and a frequency of 400 Hz, at a voltage about 40 V_pp and a frequency of 1.4 kHz, 2.4 kHz, respectively. The emission intensity increased with an increase in frequency; emission with a wavelength of 450 nm was strongly influenced by the frequency. The luminescence and the electrical properties were affected by the preparation conditions including device structures, dispersion of ZnS:Cu, and Cl particles because of the current path generated by defects in the EL cell.     

A real‐time algorithm for nonlinear receding horizon control using multiple shooting and continuation/Krylov method

In this paper, we propose a real‐time algorithm for nonlinear receding horizon control using multiple shooting and the continuation/GMRES method. Multiple shooting is expected to improve numerical accuracy in calculations for solving boundary value problems. The continuation method is combined with a Krylov subspace method, GMRES, to update unknown quantities by solving a linear equation. At the same time, we apply condensing, which reduces the size of the linear equation, to speed up numerical calculations. A numerical example shows that both numerical accuracy and computational speed improve using the proposed algorithm by combining multiple shooting with condensing. Copyright © 2008 John Wiley & Sons, Ltd.     

High Ambipolar Mobility in a Neutral Radical Gold Dithiolene Complex

A new anionic gold dithiolene complex NBu₄·[1] is synthesized from the (1‐((1,1‐biphenyl)‐4‐yl‐)‐ethylene‐1,2‐dithiolene ligand 1, and the cis and trans isomers are separated by recrystallization. The trans isomer is oxidized via electrocrystallisation to the neutral gold dithiolene complex 2. Complex 2 crystalizes in 1D chains, held together by short (3.30–3.37 Å) S–S contacts, which are packed in a herringbone arrangement in the ab‐plane. The complex exhibits semiconductor behavior (σ_RT = 1.5 × 10^?4 S cm^?1) at room temperature with a small activation energy (E_a = 0.11 eV), with greater conductivity along the stacking direction. The charge transport behavior of complex 2 is further investigated in single‐crystal field‐effect transistor (FET) measurements, the first such measurements reported for gold dithiolene complexes. Complex 2 shows incredibly balanced ambipolar behavior in the single‐crystal field‐effect transistor (SC‐FET), with high charge‐carrier mobilities of 0.078 cm² V^?1 s^?1, the highest ambipolar mobilities reported for metal dithiolene complexes. This well‐balanced behavior, along with the activated conductivity and band structure calculations, suggests that 2 behaves as a Mott insulator. The magnetic properties are also studied by superconducting quantum interference device (SQUID) magnetometry and solid state ¹H NMR, with evidence of a nonmagnetic ground state at low temperature.     

Frequency translation of light waves by propagation around an optical ring circuit containing a frequency shifter: II. Theoretical analysis

Theoretical aspects of the frequency-translation ring circuit are considered through numerical simulations. We analyze the signal and noise propagation around an optical ring circuit that contains a frequency shifter, an erbium-doped fiber amplifier and a bandpass filter (BPF). The relations between the frequency-translation limit and some important parameters such as the BPF bandwidth and the polarization state are clarified. Numerical results for the frequency-translation limit are compared with reported experiments and a frequency translation of more than 100 GHz is predicted.     

Segmentation of abnormal liver region based on earth mover’s distance between histograms with mapping of the distances by multidimensional scaling

In this paper, we propose using earth mover’s distance (EMD) to obtain the appropriate similarity between each histogram for segmentation of abnormal liver regions with mapping of the distances by multidimensional scaling. Conventionally, the similarity between each histogram is calculated by integrating the difference between each bin of the histograms. However, this similarity is unsuitable for appropriate comparison of the histograms because the number of bins for calculating the local histograms of computed tomography images varies. We used EMD to resolve this problem regarding the difference in bin numbers, and the obtained distances are used for mapping the local histograms by multidimensional scaling to low-dimensional space. In the low-dimensional space, the abnormal liver region was well segmented by support vector machine in the test datasets.     

Microbial conversion of an oil containing α-linolenic acid to an oil containing eicosapentaenoic acid

Mycelia of arachidonic acid-producing fungi belonging to the genusMortierella were found to convert an oil containing α-linolenic acid to an oil containing 5,8,11,14,17-cis-eicosapentaenoic acid (EPA). This conversion was observed when they were grown in a medium containing the oil, glucose and yeast extract at 28 C. On the screening of various oils, linseed oil, in which α-linolenic acid amounts to about 60% of the total fatty acids, was found to be the most suitable for EPA production. Under the optimal culture conditions, a selected strain,Mortierella alpina 20-17, converted 5.1% of the α-linolenic acid in the added oil into EPA, the EPA production reaching 1.35 g/l of culture broth (41.5 mg/g dry mycelia). This value corresponded to 7.1% (by weight) of the total fatty acids in the extracted lipids. The lipid was also found to be rich in arachidonic acid (12.3%). Other major fatty acids in the lipid were palmitic acid (4.4%), stearic acid (3.2%), oleic acid (13.5%), linoleic acid (13.7%), α-linolenic acid (38.5%) and γ-linolenic acid (0.9%).     

Partial oxidation of methane over silica supported molybdenum oxide catalysts

Two kinds of MoO₃/SiO₂ catalysts, MoO₃-I and MoO₃-S, were prepared by impregnation and sol-gel method, respectively. When MoO₃ loading was increased, formation of MoO₃ crystals was observed to begin at a MoO₃ loading of 8 and 16 wt% with MoO₃-I and MoO₃-S, respectively. The highest yield of formaldehyde from methane oxidation was attained also at those critical values of MoO₃ loading of 8 and 16 wt% over MoO₃-I and MoO₃-S, respectively. It is suggested that the active species for formaldehyde formation is well dispersed molybdenum oxide clusters on SiO₂ support: the optimum dispersion of the clusters affords the highest activity for formaldehyde formation.     

Development of 8‐in. oxide‐TFT‐driven flexible AMOLED display using high‐performance red phosphorescent OLED

An 8‐in. flexible active‐matrix organic light‐emitting diode (AMOLED) display driven by oxide thin‐film transistors (TFTs) has been developed. In‐Ga‐Zn‐O (IGZO)‐TFTs used as driving devices were fabricated directly on a plastic film at a low temperature below 200 °C. To form a SiO_x layer for use as the gate insulator of the TFTs, direct current pulse sputtering was used for the deposition at a low temperature. The fabricated TFT shows a good transfer characteristic and enough carrier mobility to drive OLED displays with Video Graphic Array pixels. A solution‐processable photo‐sensitive polymer was also used as a passivation layer of the TFTs. Furthermore, a high‐performance phosphorescent OLED was developed as a red‐light‐emitting device. Both lower power consumption and longer lifetime were achieved in the OLED, which used an efficient energy transfer from the host material to the guest material in the emission layer. By assembling these technologies, a flexible AMOLED display was fabricated on the plastic film. We obtained a clear and uniform moving color image on the display.     

Dual lamellar crystal structure in poly(vinylidene fluoride)/acrylic rubber blends and its biaxial orientation behavior

The miscibility for melt-mixed poly(vinylidene fluoride) (PVDF)/acrylic rubber (ACM) blends and the crystal morphology of PVDF in the blends were investigated over the whole composition ranges by dynamic mechanical analysis (DMA), wide-angle X-ray diffraction (WAXD), small-angle X-ray scattering (SAXS), and transmission electron microscopy (TEM). DMA measurements revealed that PVDF is miscible with ACM in ACM-rich system, and partially miscible in PVDF-rich system. Two kinds of PVDF lamellar structures with different long periods were detected by SAXS and TEM for the partially miscible blends. In the miscible system, only one kind of crystal lamellae with enlarged long period is found. The two kinds of lamellar structures in the blend show different orientation behavior during the uniaxial stretching to result in a biaxial orientation. The lamellae with short long period are oriented vertical to the stretching direction, while those with large long period were found to be oriented parallel to the stretching direction.