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Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO)) and Fermi level (or work function) of electrode metals. Dithiafulvene (DTF) is used as substituent group to the oligo(phenylene ethynylene) (OPE) molecular wires and different molecular structures based on OPE3 backbone (with linear to cruciform framework) are achieved, with viable molecular orbitals and HOMO–LUMO energy gaps. OPE3, OPE3–DTF, and OPE3–tetrathiafulvalene (TTF) can form good self‐assembled monolayers (SAMs) on Au substrates. Molecular heterojunctions based on these SAMs are investigated using conducting probe–atomic force microscopy with different tips (Ag, Au, and Pt) and Fermi levels. The calibrated conductance values follow the sequence OPE3–TTF > OPE3–DTF > OPE3 irrespective of the tip metal. Rectification properties (or diode behavior) are observed in case of the Ag tip for which the work function is furthest from the HOMO levels of the OPE3s. Quantum chemical calculations of the transmission qualitatively agree with the experimental data and reproduce the substituent effect of DTF. Zero‐bias conductance, and symmetric or asymmetric couplings to the electrodes are investigated. The results indicate that improved fidelity of molecular transport measurements may be achieved by systematic studies of homologues series of molecular wires applying several different metal electrodes.  相似文献   
23.
Designing a trusted and secure routing solution in an untrustworthy scenario is always a challenging problem. Lack of physical security and low trust levels among nodes in an ad hoc network demands a secure end-to-end route free of any malicious entity. This is particularly challenging when malicious nodes collude with one another to disrupt the network operation. In this paper we have designed a secure routing solution to find an end-to-end route free of malicious nodes with collaborative effort from the neighbors. We have also extended the solution to secure the network against colluding malicious nodes, which, to the best of our knowledge, is the first such solution proposed. We have also proposed a framework for computing and distributing trusts that can be used with out trusted routing protocol. Our proposed framework is unique and different from the other schemes in that it tries to analyze the psychology of the attacker and quantifies the behavior in the computational model. Extensive simulation has been carried out to evaluate the design of our protocol. Partially funded by Department of Defense Award No. H98230-04-C-0460, Department of Transportation Project No. FL-26-7102-00 and National Science Foundation Grant Nos. ANI-0123950 and CCR-0196557. Tirthankar Ghosh is a PhD candidate in the Telecommunications and Information Technology Institute at Florida International University. His area of research is routing security and trust computation in wireless ad hoc and sensor networks. He received his Bachelor of Electrical Engineering from Jadavpur University, India and Masters in Computer Engineering from Florida International University. Dr. Niki Pissinou received her Ph.D. in Computer Science from the University of Southern California, her M.S. in Computer Science from the University of California at Riverside, and her B.S.I.S.E. in Industrial and Systems Engineering from The Ohio State University. She is currently a tenured professor and the director of the Telecommunication & Information Technology Institute at FIU. Previously Dr. Pissinou was a tenured faculty at the Center for Advanced Computer Studies at the University of Louisiana at Lafayette where she was also the director of the Telecommunication & Information & Technology Laboratory partially funded by NASA, and the co-director of the NOMAD: A Wireless and Nomadic Laboratory partially funded by NSF, and the Advanced Network Laboratory. Dr. Pissinou is active in the fields computer networks, information technology and distributed systems. Dr. Kami (Sam) Makki has earned his Ph.D. in Computer Science from the University of Queensland in Brisbane Australia, his Masters degree in Computer Science and Engineering from the University of New South Wales in Sydney Australia, and his Bachelor and Masters Degrees in Civil Engineering from the University of Tehran Iran. Before joining the department of Electrical Engineering and Computer Science at the University of Toledo he has held a number of academic positions and research appointments at the Queensland University of Technology in Brisbane, Royal Melbourne Institution of Technology in Melbourne and at The University of Queensland in Brisbane Australia. He is an active researcher in the fields of distributed systems, databases, mobile and wireless communications, and has more than 30 publications in peerreviewed journals and international proceedings. He has served as a chair and technical program committee member and reviewer for a number of IEEE and ACM sponsored technical conferences and has received a number of achievement awards.  相似文献   
24.
Much evidence has accumulated that implicates the oxidative modification of low‐density lipoprotein (LDL) in the early stages of atherogenesis. The antioxidant nutrients alpha‐tocopherol, ascorbic acid, and beta‐carotene have been shown to inhibit in vitro LDL oxidation. In addition, they have been shown to increase the resistance of LDL to oxidation when given to animals and humans. Because plasma levels of these nutrients can be increased by dietary supplementation with minimal side effects, they may show promise in the prevention of coronary artery disease.  相似文献   
25.
虽然无线通信技术一直都在不断发展,但当前却处于一个前所未有的变革期,新兴的4G空中接口如WiMAX、LTE、UMB、802.20、WiBRo以及下一代PHS等等都有一个共同的特点:即都是基于正交频分多址接入(OFDMA)、都采用MIMo(多入多出)技术、都具有“扁平化架构”且均基于IP(互联网协议)。  相似文献   
26.
Automotive scenery often contains objects that can be classified by object speed and movement direction. These features can be extracted from video data by linear n-D filters, which have already been analyzed in the past. While soundness of results was convincing, interest in those systems declined due to the reduced computational abilities of contemporary computers. Modern hardware allows realization of velocity filters, if the n-D system is carefully adapted to the analysis problem. The present paper analyzes the premises for application of velocity filters in the domain of automotive driver assistance systems, i.e. with respect to detectability of objects and implementability in a cost effective way. Especially the influence of the frame rate and the temporal violation of the sampling theorem are analyzed. Transfer functions for n-D filters working in a vision-based blind spot collision avoidance system are presented and discussed, and promising approaches for future application fields are proposed.  相似文献   
27.
The ability of Lactobacillus plantarum ATCC 8014 to inhibit Clostridium botulinum toxin production in pea soup was investigated. Soup containing C. botulinum spores (103/g) with and without L. plantarum (106/g) were evaluated. Soup containing only type A spores was toxic on days 1 and 2 when incubated at 35°C and 25°C, respectively. Soup containing only proteolytic type B spores was toxic on days 2 and 5 at 35°C and 25°C, respectively. Soup containing only type E spores was toxic at 25°C, 15°C, and 5°C in 7, 7, and 63 days respectively. No toxin was found in soup containing C. botulinum spores plus L. plantarum at any temperature studied.  相似文献   
28.
The industrial scale application of graphene and other functional materials in the field of electronics has been limited by inherent defects, and the lack of simple deposition methods. A simple spray deposition method is developed that uses a supersonic air jet for a commercially available reduced graphene oxide (r‐GO) suspension. The r‐GO flakes are used as received, which are pre‐annealed and pre‐hydrazine‐treated, and do not undergo any post‐treatment. A part of the considerable kinetic energy of the r‐GO flakes entrained by the supersonic jet is used in stretching the flakes upon impact with the substrate. The resulting “frozen elastic strains” heal the defects (topological defects, namely Stone‐Wales defect and C2 vacancies) in the r‐GO flakes, which is reflected in the reduced ratio of the intensities of the D and G bands in the deposited film. The defects can also be regenerated by annealing.  相似文献   
29.
汽车信息娱乐系统(见图1)时代的到来标志着汽车采甩简单车载收音机(如图2中Mercedes汽车所配备的仪表板)的日子一去不复返了。历史悠久的AM/FM收音机在信息娱乐控制板上仍然保有一席之地,但它与数字音频广播(DAB)、数字和高清晰度电视(HDTV)、卫星无线电、集成蜂窝电话、CD/DVD/MP3播放器、全球定位系统(GPS)导航及视频游戏系统组合在一起。  相似文献   
30.
Fast mode decision algorithms have been widely used in the video encoder implementation to reduce encoding complexity yet without much sacrifice in the coding performance. Optimal stopping theory, which addresses early termination for a generic class of decision problems, is adopted in this paper to achieve fast mode decision for the H.264/Scalable Video Coding standard. A constrained model is developed with optimal stopping, and the solutions to this model are employed to initialize the candidate mode list and predict the early termination. Comprehensive simulation results are conducted to demonstrate that the proposed method strikes a good balance between low encoding complexity and high coding efficiency.  相似文献   
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