A thermodynamic model for composition and chemical driving force for nucleation of complex carbonitrides in microalloyed steel

The extent and degree of dispersion of carbonitrides in high strength low alloy (HSLA) steels is controlled by nucleation and growth processes. A thermodynamic model is presented enabling calculation of the composition of the carbonitride embryo as well as the chemical driving force for nucleation (CDF) in the austenite region of a multicomponent microalloyed steel. The analysis made for a Nb-Ti HSLA steel indicates that the critical carbonitride nucleus is richer in N and Ti than the bulk precipitate at equilibrium at a given temperature and the difference increases when the holding temperature decreases. The results also show that the Ti addition has an optimum value defined by the maximum in the ratio of bound Ti and Nb to their total content. The maximum CDF correlated with the minimum Ti content sufficient to form a carbonitride at the austenitizing temperature.     

Calculation of an interruption arc current and time of arc quenching in low-voltage current breakers

For the analytical calculation of an arc current in the process of arc quenching, an average statistical curve of a change of an interruption arc voltage is constructed and mathematically described. This curve is based on experimental data obtained during short-circuit current interruption by nonspeed and selective circuit breakers of different design, in particular, with different volumes of arc chutes. Features of short-circuit current interruption in a three-phase system are considered.     

Development of Alkaline Decomposition of Lepidolite Concentrate by Melting with Calcined Soda and Melt Comprehensive Sulfuric Acid Treatment

Metallurgist - Experimental research is conducted for recovery of lithium from lepidolite. A method is developed for alkaline decomposition of lepidolite based on melting with calcined soda and...     

Erbium zirconium phosphate Er<Subscript>0.33</Subscript>Zr<Subscript>2</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript> of the NaZr<Subscript>2</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript> family. Structure contraction on heating

Erbium zirconium phosphate Er_0.33Zr₂(PO₄)₃, a member of the family of structural analogs of NaZr₂(PO₄)₃ (NZP), was prepared by the sol-gel process and studied by X-ray phase analysis, IR spectroscopy, and differential scanning calorimetry. The behavior of erbium zirconium phosphate on heating in the temperature interval from 25 to 625°C was studied by high-temperature X-ray diffraction. Expansion and contraction along different crystallographic directions and contraction of the structure as a whole were found. The overall contraction is due to higher contribution of the negative axial thermal expansion coefficients α _a and α _b to α_av and hence to the volume expansion of the phosphate. On heating to 900°C, the NZP structure is preserved.     

Phosphorus-containing compounds of pollucite structure and radiochemical problems

New pollucite-like phosphorus-containing compounds with cesium and uni-, bi-, and trivalent cations (Li; Mg, Mn, Co, Ni, Cu, Zn, Cd, Sr, Ba; Al, Cr, Fe), many of which can be present in various combinations in wastes from radiochemical processes, were synthesized. The individual phases obtained were characterized by X-ray phase analysis and IR spectroscopy. The symmetry of the unit cells of the phosphorus-containing compounds decreases relative to the silicon analog (pollucite natural mineral) from Ia3d to I4₁32. The behavior of the compounds on heating to 1000°C, under hydrothermal conditions at 90°C, in aqueous systems (distilled water and seawater) at 25°C, and in a CsCl melt at 680°C was studied. The chemical and phase composition of the samples remained unchanged under all these conditions. The Cs leaching rates varied from 7.1 × 10⁻⁶ to 1.46 × 10⁻⁵ g cm⁻² day⁻¹. The “crystal-chemical modeling” of the new possible compositions of the compounds with the expected pollucite structure was performed.