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21.
Yaping Liu James D. Livingston Samuel M. Allen 《Metallurgical and Materials Transactions A》1992,23(12):3303-3308
The microstructure within particles of the Laves phase Fe2Zr in a two-phase Fe-10 at. pct Zr alloy after compression was investigated using X-ray diffraction and electron microscopy.
Stressinduced phase transformation between C36 and C15 structures was found to be a major deformation mode for the Laves phase.
Twinning and stacking faults were also found within C15 regions. Phase transformation models based on partial dislocations
are discussed. 相似文献
22.
The formation of a porous polymer monolith (PPM) is influenced by the physico-chemical properties of the wall surface of its container. This influence can have a dramatic effect on the resulting monolith morphology depending on the nature and composition of the wall. Indeed, a dense polymer layer or “sheath”, distinct from the bulk porous material, has been observed at the wall surface of capillaries, and thus a study was undertaken to explore the dependence of this layer on the hydrophobicity of the surface. A range of silanizing reagents were used to modify the surface of the fused silica capillary, including aminopropyl, trimethylsilyl, octadecyl and perfluorooctyl functionalities. Crosslinked butyl acrylate-based PPM was formed in the modified capillaries and extruded. SEM images of the monoliths were used to examine the sheath morphology and thickness, which are discussed with respect to surface hydrophobicity. 相似文献
23.
S.‐C. Lo G.J. Richards J.P.J. Markham E.B. Namdas S. Sharma P.L. Burn I.D.W. Samuel 《Advanced functional materials》2005,15(9):1451-1458
We describe the preparation of a dendrimer that is solution‐processible and contains 2‐ethylhexyloxy surface groups, biphenyl‐based dendrons, and a fac‐tris[2‐(2,4‐difluorophenyl)pyridyl]iridium(III ) core. The homoleptic complex is highly luminescent and the color of emission is similar to the heteroleptic iridium(III ) complex, bis[2‐(2,4‐difluorophenyl)pyridyl]picolinate iridium(III ) (FIrpic). To avoid the change in emission color that would arise from attaching a conjugated dendron to the ligand, the conjugation between the dendron and the ligand is decoupled by separating them with an ethane linkage. Bilayer devices containing a light‐emitting layer comprised of a 30 wt.‐% blend of the dendrimer in 1,3‐bis(N‐carbazolyl)benzene (mCP) and a 1,3,5‐tris(2‐N‐phenylbenzimidazolyl)benzene electron‐transport layer have external quantum and power efficiencies, respectively, of 10.4 % and 11 lm W–1 at 100 cd m–2 and 6.4 V. These efficiencies are higher than those reported for more complex device structures prepared via evaporation that contain FIrpic blended with mCP as the emitting layer, showing the advantage of using a dendritic structure to control processing and intermolecular interactions. The external quantum efficiency of 10.4 % corresponds to the maximum achievable efficiency based on the photoluminescence quantum yield of the emissive film and the standard out‐coupling of light from the device. 相似文献
24.
Knapp Samuel; Gottlieb Michael; Berman Jason; Handelsman Mitchell M. 《Canadian Metallurgical Quarterly》2007,38(1):54
At times the laws under which psychologists function may appear to contradict generally recognized ethical values and/or good clinical care. When these circumstances arise, psychologists must determine if a conflict really exists and, if so, seek solutions that reconcile respect for the law with their ethical values. At times, psychologists may decide to follow the law despite their ethical concerns. At other times, they may determine that a conscientious objection is warranted. The authors recommend options to consider when these situations arise and offer a decision-making process. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
25.
Fabrice Martin Marc-Etienne Jan Samuel Rey-Mermet Brahim Belgacem Dong Su Marco Cantoni Paul Muralt 《IEEE transactions on ultrasonics, ferroelectrics, and frequency control》2006,53(7):1339-1343
Polycrystalline A1N thin films were deposited by RF reactive magnetron sputtering on Pt(111)/Ti electrode films. The substrates were tilted by an angle ranging from 40 degrees to 70 degrees with respect to the target normal. A low deposition temperature and a high sputter gas pressure were found ideal for tilted growth. The resulting grain tilt angle amounts to about half the substrate tilt angle. For coupling evaluation, 5 GHz solidly mounted resonator structures have been realized. The tilted grain A1N films exhibited a permittivity in the 9.5-10.5 range and loss tangent of 0.3%. Two shear modes as well as the longitudinal mode could be clearly identified. The coupling coefficient k2(eff) of the fundamental thickness shear mode (TS0) was found to be about 0.5%, which is compatible with a c-axis tilt of about 6 degrees. 相似文献
26.
F. G. Johnson B. L. Olmsted Samuel Chen G. W. Wicks 《Journal of Electronic Materials》1993,22(3):331-334
The composition profile of an (AlAs)1/2(GaAs)1/2 tilted superlattice is characterized for the first time. The tilted superlattice sample is thermally disordered, and the
energy of the direct band gap photoluminescence peak is measured as a function of increasing layer interdiffusion. The shift
in the photoluminescence peak energy after completely disordering the tilted superlattice is 39 meV. A theoretical model is
used to simulate the change in band gap as a function of layer interdiffusion for several composition profiles. The profile
that gives the best fit to the experimental data is chosen. The tilted superlattice composition profile is found to be sinusoidal,
varying from Al0.40Ga0.60As to Al0.60Ga0.40As. 相似文献
27.
The effect of salt addition, in the form of a fluxing agent containing equivalent amounts of NaCl and KCl, on the microstructure and mechanical properties of 359/SiC/10p composite has been investigated. Both microstructure and properties are affected, with the removal of magnesium and strontium and the introduction of sodium and potassium being responsible for the degradation in properties. Thermodynamic calculations have been carried out to account for the effect of salt addition in terms of the surface adsorption of sodium and potassium impurities and the consequent changes in the surface-interface tension of their binary alloys. Mechanisms for the degradation of properties have been discussed. 相似文献
28.
The quality index, Q, defined as Q=UTS + klogE1 was introduced as a means to better interpret tensile test data. However, its use in the case of composite materials is often questioned. The difficulty arises from the fact that the elongations obtained are usually close to, or less than, unity. Based on a heat-treatment study of cast Al-Si-Mg/SiCp composites (359/SiCp) and an analysis of the tensile properties obtained, it is shown that the concept of quality index, as it is commonly applied, is inappropriate in describing the combined effects of UTS and E1, and it is much better, instead, to use the probable yield strength (PYS) for such materials. Respective expressions for Q and PYS have been obtained for the 359, 359/SiC/10p and 359/SiC/20p alloys studied. 相似文献
29.
30.
Eugenia Awuah Boadi Samuel Shin Samuel Yeroushalmi Bok-Eum Choi Peijun Li Bidhan C. Bandyopadhyay 《International journal of molecular sciences》2021,22(6)
Proximal tubular (PT) acidosis, which alkalinizes the urinary filtrate, together with Ca2+ supersaturation in PT can induce luminal calcium phosphate (CaP) crystal formation. While such CaP crystals are known to act as a nidus for CaP/calcium oxalate (CaOx) mixed stone formation, the regulation of PT luminal Ca2+ concentration ([Ca2+]) under elevated pH and/or high [Ca2+] conditions are unknown. Since we found that transient receptor potential canonical 3 (TRPC3) knockout (KO; -/-) mice could produce mild hypercalciuria with CaP urine crystals, we alkalinized the tubular pH in TRPC3-/- mice by oral acetazolamide (0.08%) to develop mixed urinary crystals akin to clinical signs of calcium nephrolithiasis (CaNL). Our ratiometric (λ340/380) intracellular [Ca2+] measurements reveal that such alkalization not only upsurges Ca2+ influx into PT cells, but the mode of Ca2+ entry switches from receptor-operated to store-operated pathway. Electrophysiological experiments show enhanced bicarbonate related current activity in treated PT cells which may determine the stone-forming phenotypes (CaP or CaP/CaOx). Moreover, such alkalization promotes reactive oxygen species generation, and upregulation of calcification, inflammation, fibrosis, and apoptosis in PT cells, which were exacerbated in absence of TRPC3. Altogether, the pH-induced alteration of the Ca2+ signaling signature in PT cells from TRPC3 ablated mice exacerbated the pathophysiology of mixed urinary stone formation, which may aid in uncovering the downstream mechanism of CaNL. 相似文献