Recent advances in indium metallurgy: A review

The by-products of zinc refineries are used as the primary mineral resources for the commercial production of indium. The discarded LCDs containing adequate amount of indium is rather worth as its secondary resources compared to the by-products of zinc refineries. Mining and recycling rates of indium, respectively from minerals and waste LCDs are in progress to meet its huge demand. Recycling of the LCDs has been dominating over mining, as presently 480t of indium are produced annually from mining, however, that of 650t annually from recycling. Different aspects of the extractive metallurgy of indium are summarized in this review paper.     

Development of real-time reference evapotranspiration at the regional scale using satellite-based observations

Real-time data of reference evapotranspiration (ET₀) at different space-time scales are essential to regional agricultural drought assessment, water accounting at the watershed to basin scale, and provide irrigation advisory to farmers. Here, we present a data-fusion approach that integrates satellite-based insolation product (8 km) from an Indian geostationary satellite (Kalpana-1) sensor (VHRR; Very High Resolution Radiometer) and high-resolution (~ 5 km) short-range weather forecast into an FAO56 model based on the classical Penman–Monteith (P-M) formulation. Five year (2009–2013) mean monthly estimates from the daily ET₀ product over the Indian landmass were found to vary between 10 and 350 mm. It increased from January to May (70–350 mm), followed by a decrease to reach the lowest in November (10–140 mm), thus typically showing unimodal distribution. The comparison of daily space-based and station-based estimates (at six ground stations) produced a root mean square deviation (RMSD) ranging from 21% to 38% for 977 paired data sets with the correlation coefficient (r) varying from 0.32 to 0.82. The error was reduced from 25% to 10% with an increase in ‘r’ from 0.43 to 0.98 for daily to 10 day summation period. Spatial grid-to-grid comparison of monthly ET₀ estimates with Global Data Assimilation System (GDAS) potential evapotranspiration (PET) showed RMSD within a range of 1.4–18.4% for most of the months, except for two. Further ET₀ analysis over normal and drought years showed that it could be used for comprehensive drought assessment with other existing indicators.     

Optimizing microstructure for toughness: the model problem of peeling

We consider the problem of peeling an adhesive thin film from a substrate that has a non-uniform distribution of adhesive. When the length scale of the non-uniformity is small compared to the overall dimensions of the film being peeled, it is possible to describe the overall peeling behavior with an effective adhesive strength. In this paper, we seek to find the distributions of adhesive strength at the microscale that optimize various aspects of the effective adhesive strength at the macroscale. We do so using both analytic bounds and topology optimization. We formulate the problem of peeling as a free boundary problem, and the effective strength as a maximum principle over the trajectory. For topology optimization, we replace the maximum with an integral norm, and use an adjoint method for the sensitivity. The problem of peeling may be viewed as a model problem in fracture mechanics where the crack (peel) front is confined to a plane, and thus our analysis as a first step toward studying the more general problem of optimizing microstructure for toughness.     

Importance of viscosity parameters in electrospinning: Of monolithic and core–shell fibers

Electrospun polymeric fibers are attractive candidates in the development of scaffolds for the tissue engineering and for providing new systems for delivery of bioactive molecules. Co-axial fibers have emerged as an efficient tool to protect the core material from the adverse conditions of electrospinning process, to spin difficult-to-process fluids and to generate fibers with much more control of the delivery of encapsulated bioactive molecules. Currently, there is very little reported work on the optimization of the processing parameters of electrospinning, especially core–shell electrospinning. This study extends the understanding of the role of solution viscosity as a vital material parameter for electrospinning of fibers. The spinning solutions were characterized for viscosity and optical imaging of the compound Taylor cone for spinnability, and the fibers were imaged by Scanning Electron Microscopy (SEM). Our experimental results, using PLGA as the model polymer, confirm that the solution concentration be above the entanglement concentration (C_e) to obtain uniform beadless monolithic fibers; for core–shell fibers, the shell solution must fulfill the above criterion for spinnability and, further, the ratio of the viscosities of core and shell solutions (η_core/η_shell) has to be greater than a threshold value to get a stable compound Taylor cone and therefore to obtain uniform beadless core–shell fibers. Addition of surfactant led to reduction of the threshold η_core/η_shell (from 0.55 to 0.18) for the PVA–PLGA system.     

Fifth sustainable development goal gender equality in India: analysis by mathematics of uncertainty and covering of fuzzy graphs

Neural Computing and Applications - In the present situation, the sustainable development goal on “Gender Equality” (SDG 5) is a challenging problem over the entire globe, also in...     

Synthesis of copper-ferrous (CuFe) nanowires via electrochemical method and its investigations as a fluid sensor

The special behaviour of nanowires with respect to electrical conductivity makes them suitable for sensing application. In this paper, we present a copper-ferrous (CuFe) nanowires based sensor for detection of chemicals. CuFe nanowires were synthesized by template-assisted electrochemical method. By optimizing the deposition parameters, continuous nanowires on a copper substrate were synthesized. The morphological and structural studies of the synthesized CuFe nanowires were carried out using scanning electron microscope (SEM) and X-ray diffraction (XRD). Substrates containing CuFe nanowires were moulded to form a capacitor. Different chemicals were used as dielectric in the capacitor which showed that the capacitance was a nonlinear function of the dielectric constant of fluid unlike the linear relation shown by conventional capacitors. This unique property of the nanowires based capacitors may be utilized for developing fluid sensors with improved sensitivity.     

Recent Advances in Microalgal Bioactives for Food,Feed, and Healthcare Products: Commercial Potential,Market Space,and Sustainability

To combat food scarcity as well as to ensure nutritional food supply for sustainable living of increasing population, microalgae are considered as innovative sources for adequate nutrition. Currently, the dried biomass, various carotenoids, phycocyanin, phycoerythrin, omega fatty acids, and enzymes are being used as food additives, food coloring agents, and food supplements. Apart from nutritional importance, microalgae are finding the place in the market as “functional foods.” When compared to the total market size of food and feed products derived from all the possible sources, the market portfolio of microalgae‐based products is still smaller, but increasing steadily. On the other hand, the genetic modification of microalgae for enhanced production of commercially important metabolites holds a great potential. However, the success of commercial application of genetically modified (GM) algae will be defined by their safety to human health and environment. In view of this, the present study attempts to highlight the industrially important microalgal metabolites, their production, and application in food, feed, nutraceuticals, pharmaceuticals, and cosmeceuticals. The current and future market trends for microalgal products have been thoroughly discussed. Importantly, the safety pertaining to microalgae cultivation and consumption, and regulatory issues for GM microalgae have also been covered.     

Variability in rheology of cemented paste backfill with hydration age,binder and superplasticizer dosages

The use of (CPB) material to ameliorate geotechnical stability of underground mine is in nascent stage in India. Rheological properties of CPB change with travelling time as it is transported to underground mine stope through pipeline reticulation. In this paper, rheological properties of CPB based on mill tailings of a carbonate rich mineral processing waste are evaluated for different dosages of polycarboxylate (PC) based (SP). Each CPB sample having 78?wt% solids is mixed separately with 4%, 6% or 8% of binder dosages (ratio of the weight of dry binder to the weight of dry tailings) and, 0%, 0.5%, or 1.0% of SP dosages as weight of dry binder. The paper presents a methodology for determining yield stress, plastic viscosity and thixotropic behaviour of CPB mixture as a function of hydration age, binder and SP dosages. Results from the experimental campaigns indicate that SP content has significant influence on rheological behaviour of CPB and can be suitably exploited to enhance the flow characteristics of the carbonate rich process tailings. The study also develops multivariate linear regression models of yield stress, plastic viscosity and thixotropy of CPB depending on the hydration age, binder and SP dosages.     

Influence of Microstructure on the Mechanical Properties of a Pearlitic Steel

Metallurgical and Materials Transactions A - The effect of austenite grain size on microstructure and mechanical properties was studied for a pearlitic steel. The best combination of ultimate...