Disclosing the Role of Defect-Engineered Metal–Organic Frameworks in Mixed Matrix Membranes for Efficient CO2 Separation: A Joint Experimental-Computational Exploration

Incorporation of defects in metal–organic frameworks (MOFs) offers new opportunities for manipulating their microporosity and functionalities. The so-called “defect engineering” has great potential to tailor the mass transport properties in MOF/polymer mixed matrix membranes (MMMs) for challenging separation applications, for example, CO₂ capture. This study first investigates the impact of MOF defects on the membrane properties of the resultant MOF/polymer MMMs for CO₂ separation. Highly porous defect-engineered UiO-66 nanoparticles are successfully synthesized and incorporated into a CO₂-philic crosslinked poly(ethylene glycol) diacrylate (PEGDA) matrix. A thorough joint experimental/simulation characterization reveals that defect-engineered UiO-66/PEGDA MMMs exhibit nearly identical filler–matrix interfacial properties regardless of the defect concentrations of their parental UiO-66 filler. In addition, non-equilibrium molecular dynamics simulations in tandem with gas transport studies disclose that the defects in MOFs provide the MMMs with ultrafast transport pathways mainly governed by diffusivity selectivity. Ultimately, MMMs containing the most defective UiO-66 show the most enhanced CO₂/N₂ separation performance—CO₂ permeability = 470 Barrer (four times higher than pure PEGDA) and maintains CO₂/N₂ selectivity = 41—which overcomes the trade-off limitation in pure polymers. The results emphasize that defect engineering in MOFs would mark a new milestone for the future development of optimized MMMs.     

LMS adaptive filters using distributed arithmetic for high throughput

We present a new hardware adaptive filter architecture for very high throughput LMS adaptive filters using distributed arithmetic (DA). DA uses bit-serial operations and look-up tables (LUTs) to implement high throughput filters that use only about one cycle per bit of resolution regardless of filter length. However, building adaptive DA filters requires recalculating the LUTs for each adaptation which can negate any performance advantages of DA filtering. By using an auxiliary LUT with special addressing, the efficiency and throughput of DA adaptive filters can be of the same order as fixed DA filters. In this paper, we discuss a new hardware adaptive filter structure for very high throughput LMS adaptive filters. We describe the development of DA adaptive filters and show that practical implementations of DA adaptive filters have very high throughput relative to multiply and accumulate architectures. We also show that DA adaptive filters have a potential area and power consumption advantage over digital signal processing microprocessor architectures.     

On surface recombination velocity and output intensity limit of pulsed semiconductor lasers

Relationships obtained by F. Kappeler et al. (1982) are utilized to assess the effect of facet passivation on the output intensity limit in terms of surface recombination velocity. The results show a trend that the output intensity limit increases in an exponential manner with decreasing recombination velocity once the velocity is reduced by a factor of 2 from that for an unpassivated laser. They also indicate that the output intensity is not likely to be limited by nonradiative recombination at the facet when the recombination velocity is reduced by a factor of 4.<>     

35 GHz integrated circuit rectifying antenna with 33% efficiency

A 35 GHz integrated circuit rectifying antenna (rectenna) has been developed using a microstrip dipole antenna and beam-lead mixer diode. Greater than 33% conversion efficiency has been achieved. The circuit should have applications in microwave/millimetre-wave power transmission and detection.<>     

MIMO-HFM: A MIMO System with Hyperbolic Frequency Modulation for Underwater Acoustic Communication

Reliable transmission and high data rate over underwater acoustic channels are considerably challenging. In this paper, we propose Multiple-Input and Multiple-Output (MIMO) scheme using a Hyperbolic Frequency Modulation (HFM) waveform. Our proposed system combines the advantages of both systems-special multiplexing of MIMO and immunity against Doppler shift of HFM. To increase the spectral efficiency, we employ M-ray HFM and overlapped sub-channels by leveraging the high temporal resolution characteristic. To verify effectiveness of our system, we have designed a theoretically enhanced acoustic simulator, which especially focuses on the reflection phenomenon by utilizing approved reflection loss models. Based on our acoustic simulator, we could verify that our system is robust against for multipath fading and Doppler shifting while keeping the multiplexing benefit of MIMO, while maintaining a very low complexity and system overhead. In addition, the results provide a useful insight for physical layer design in acoustic communication systems.     

Performance improvement of TCP in ad hoc networks by mitigating channel contention

In ad hoc networks, the spatial reuse property limits the number of packets which can be spatially transmitted over a path. In standard Transmission Control Protocol (TCP), however, a TCP sender keeps transmitting packets without taking into account this property. This causes heavy contention for the wireless channel, resulting in the performance degradation of TCP flows. Hence, two techniques have been proposed independently in order to reduce the contention. First, a TCP sender utilizes a congestion window limit (CWL), by considering the spatial reuse property. This prevents the TCP sender from transmitting more than CWL number of packets at one time. Second, a delayed ack (DA) strategy is exploited in order to mitigate the contention between the TCP ACK and DATA packets. Recently, although TCP‐DAA (Dynamic Adaptive Acknowledgment) attempts to utilize a CWL‐based DA strategy, TCP‐DAA overlooks a dynamic correlation between these two techniques. This paper, therefore, reveals the dynamic correlation and also proposes a protocol which not only reduces the frequency of the TCP ACK transmissions but also determines a CWL value dynamically, according to network conditions. Simulation studies show that our protocol performs the best in various scenarios, as compared to TCP‐DAA and standard TCP (such as TCP‐NewReno). Copyright © 2009 John Wiley & Sons, Ltd.     

Analysis of adjacent channel interference using distribution function for V2X communication systems in the 5.9‐GHz band for ITS

Many use cases have been presented on providing convenience and safety for vehicles employing wireless access in vehicular environments and long‐term evolution communication technologies. As the 70‐MHz bandwidth in the 5.9‐GHz band is allocated as an intelligent transportation system (ITS) service, there exists the issue that vehicular communication systems should not interfere with each other during their usage. Numerous studies have been conducted on adjacent interfering channels, but there is insufficient research on vehicular communication systems in the ITS band. In this paper, we analyze the interference channel performance between communication systems using distribution functions. Two types of scenarios comprising adjacent channel interference are defined. In each scenario, a combination of an aggressor and victim network is categorized into four test cases. The minimum requirements and conditions to meet a 10% packet error rate are analyzed in terms of outage probability, packet error rate, and throughput for different transmission rates. This paper presents an adjacent channel interference ratio and communication coverage to obtain a satisfactory performance.     

Writing current reduction and total set resistance analysis in PRAM

We evaluated the limit of scaling bottom electrode contact (BEC) heater size and high resistivity heater to reduce writing current. It was found that the resistivity of heater should be increased for reducing writing current below the heater size of about 50 nm without any undesirable increase of resistance of the crystalline state (SET state, Rset). It was shown in the numerical simulations that the dissipated heat loss through BEC during melting GST was decreased in the increase of resistivity of heater. In addition, we analyzed the resistance components contributing to the total set resistance. It was observed that the undesired sharp increase of Rset as the BEC size decreases below 50 nm was attributed to the resistance component of GST–BEC interface. In the case of high resistivity heater, the contributions of both incomplete crystallization and heater itself were enhanced.     

An experimental study on time delay control of actuation system of tilt rotor unmanned aerial vehicle

This paper presents an actuation control system for the Smart Unmanned Aerial Vehicle (SUAV), a tilt rotor aircraft that is being developed by the Korea Aerospace Research Institute. The actuation system, which consists of flaperon, rotor, and nacelle tilt, should be controlled to track the position command sent from the flight controller. However, substantial variations in the aerodynamic load on the actuation system make it difficult to achieve the desired level of control performance. In this study, the actuation system was controlled using the Time Delay Control (TDC) law. The experimental results show that the following control performance specifications are completely satisfied under load variation from 0 to 455 kgf: bandwidth of 4 Hz, overshoot of 2.5%, and steady state error of 1% for flaperon and rotor actuation system. Especially, the accuracy was within the noise level of the steady state position error over broad ranges of the load. In addition, the command filter was applied to the TDC command to mitigate the effects of the phase delay that occurs when a sinusoidal command is applied. Furthermore, an actual flight test was performed, which clearly showed the effectiveness of the proposed control scheme. This promising control performance shows that TDC is an effective alternative for controlling the actuation system of the SUAV with substantial load variation.