Implication of molecular orientation on charge transport and gas sensing characteristics of cobalt–phthalocyanine thin films

Charge transport and gas sensing characteristics of cobalt phthalocyanine films deposited along (ATB) and perpendicular (PTB) to the natural twin boundaries of (0 0 1) LaAlO₃ substrate have been investigated. The charge carrier mobility of ATB films (∼5 cm² V⁻¹ s⁻¹) is five orders of magnitude higher compared to that of PTB films (∼7 × 10⁻⁵ cm² V⁻¹ s⁻¹), suggesting that twin boundaries acts like a template for ordering of molecules. The ATB films on exposure to ammonia showed a reversible increase of resistance, with fast response and recovery. In contrast PTB films showed same sensitivity, but exhibits base resistance drift along with sluggish response.     

Observation of ZBCP Above T C at Au/Y1Ba2Cu3O7−δ Heterostructure with a Nano Hole: A Possible Evidence for the Cooper Pairs above T C

Fabrication of a nanojunction by making a nano- hole on PMMA layer deposited in between Au and Y₁Ba₂Cu₃O_7?δ (YBCO) films is reported. We have measured the current-voltage characteristics across Au/YBCO nanojunction at different temperatures and studied Andreev Reflection (AR) phenomena. The presence of Zero Bias Conductance Peak (ZBCP) due to AR, which is considered to be the well-known feature of d-wave superconductors, has been noticed at temperatures below and above the transition temperature (T _C ～87 K) up to 130 K. The result obtained indicates the possible- existence of the phase-incoherent Cooper pairs above T _C for Au/YBCO.     

Toughening of Polylactic Acid: An Overview of Research Progress

To overcome the limitations of polylactic acid, alterations are needed to enhance its toughness, to improve handling and for various applications. Extensive studies were reported, mainly in the area of blends with renewable resource polymer blends. Better phase dispersion between the blend materials is achieved either by reactive mixing of the two components or by incorporation of a block copolymer compatibilizer, finally showing highly enhanced property. In this article, the recent research progress of different toughening processes of PLA via blending is reviewed and a detailed understanding about toughening of PLA using biodegradable or renewable polymers has been established.     

First-principles studies of the superconductivity and vibrational properties of transition-metal nitrides TMN (TM = Ti,V, and Cr)

The present paper reports the structural, electronic, phonon and thermodynamical properties of some transition-metal nitrides (TMN: TiN, VN and CrN) by means of first-principles calculations. The computed equilibrium lattice constant and bulk modulus agree well with the available experimental and theoretical data. The electronic band structure and density of states calculations show metallic nature. The phonon frequencies are positive throughout the Brillouin zone for these compounds in rocksalt structure indicating dynamical stability. The calculated electron–phonon coupling constant λ and superconducting transition temperature agree reasonably well with the available experimental data. These compounds behave as a conventional phonon-mediated superconductor. Within the GGA and quasi-harmonic approximation, thermodynamical properties are also investigated.     

Home Security System Using Wireless Sensors Network

Wireless Personal Communications - In this paper, we propose a smart and robust home security system. This is for intrusion detection along with a proprietary Android application. Intruder-Spi...     

Redefined SI Units and Their Implications

Metrology plays the key role as the engine of industrial revolution and growth of any country. It promotes global competence and confidence. With the advent of better quality products through metrological advancement, our industries can compete internationally and to overcome trade barriers/constraints and finally to achieve exports targets. This translates into growth of industries through rapid industrialization, economic growth and societal upliftment. The metrology requires continued and sustained efforts to cater the stakeholders’ demands for advancements in measurement technologies, standards and measurement techniques for more and more precise, reliable, reproducible and accurate measurements with improved measurement uncertainties. In this context, the recent revolutionary changes in redefinition of SI units based on fundamental constants were unanimously voted for adoption by world community during November 16, 2018, at Versailles, France, and implemented world over from May 20, 2019—the World Metrology Day. Therefore, it was considered appropriate to compile a brief status report and apprise the readers about these historical events. The present paper touches glimpse of some of these activities and describes the implications of these changes in our daily life.     

Performance Evaluation of Inversion Mode and Junctionless Dual-Material Double-Surrounding Gate Si Nanotube MOSFET for 5-nm Gate Length

Semiconductors - In this work, drain current ID for 5-nm gate length with dual-material (DM) double-surrounding gate (DSG) inversion mode (IM) and junctionless (JL) silicon nanotube (SiNT) MOSFET...     

Acrylic-ester-polyol based novel two-component polyurethane clear coat: Evaluation of performance characteristics

In the current study, a combination of acrylic polyol (AP) and ester polyol (EP) were synthesized and reacted at variable ratios with hexamethylene diisocyanates and isophorone diisocyanates to prepare a transparent two-component polyurethane (PU) coating formulation. The formations of the polyol system, isocyanate system, and the PU systems were confirmed by ¹H nuclear magnetic resonance and Fourier-transform infrared spectroscopy. Transparency of the coatings was examined using haze, and gloss measurement, which showed acrylic-ester-polyurethane (aePU-5 and aePU-6) have 91.5% and 91.8% transparency and gloss of 90.3 and 90.7 GU respectively. The thermal properties like T_g and the thermal stability of the coatings were verified using differential scanning calorimetry, and thermogravimetric analysis respectively which was found to increase with increasing EP content and decreasing AP content which may be ascribed to improved compatibility of copolymers, and homogeneity in PU along with enhanced crosslinking density. The degree of adhesion of coating with the substrate was validated from lap-shear, and cross-cut tape test which showed improved performance at AP:EP ratio of 60:40. The coatings were found to exhibit resistance toward pencil hardness with aePU-5 and aePU-6 having the optimum resistance of 9H. The surface morphology and topography were observed under scanning electron microscopy, and atomic force microscopy, respectively. The outcome confirms the higher smoothness of the surfaces subjected to the increase in EP content. The PU system with 40 wt% AP content and 60 wt% EP designated as aePU-5 was found to exhibit optimum performance.