Ultrahigh Current Density Ion Implantation

A study of several engineering alloys implanted at ultrahigh current densities has revealed that the process induces no change in the bulk microsctructure of the materials. Even though temperatures induced during processing exceed the transformation (tempering and annealing) temperatures, there is insufficient time for nucleation and growth reactions to occur during the temperature excursion associated with typical implantation dose and energy conditions. Substantially lower costs should accompany the shorter duration ultrahigh current density implantation process. Auger electron spectrographs reveal a substantially extended nitrogen range over those observed at low current densities (four-fold increase). This enhanced range appears to be due to radiation enhanced diffusion effects. Deeper penetration could lead to more durable surface layers.     

Variability response functions for effective material properties

The variability response function (VRF) is a well-established concept for efficient evaluation of the variance and sensitivity of the response of stochastic systems where properties are modeled by random fields that circumvents the need for computationally expensive Monte Carlo (MC) simulations. Homogenization of material properties is an important procedure in the analysis of structural mechanics problems in which the material properties fluctuate randomly, yet no method other than MC simulation exists for evaluating the variability of the effective material properties. The concept of a VRF for effective material properties is introduced in this paper based on the equivalence of elastic strain energy in the heterogeneous and equivalent homogeneous bodies. It is shown that such a VRF exists for the effective material properties of statically determinate structures. The VRF for effective material properties can be calculated exactly or by Fast MC simulation and depends on extending the classical displacement VRF to consider the covariance of the response displacement at two points in a statically determinate beam with randomly fluctuating material properties modeled using random fields. Two numerical examples are presented that demonstrate the character of the VRF for effective material properties, the method of calculation, and results that can be obtained from it.     

Processing effects on in-flight particle state and functional coating properties of plasma-sprayed manganese zinc ferrite

Magnetic properties of manganese zinc ferrite (MZF) coatings deposited by atmospheric dc plasma spraying largely depend on zinc and oxygen loss during particle flight. The temperature and velocity of in-flight MZF particles were widely varied by changing plasma spray conditions to examine these chemistry changes and resultant magnetic properties. Zn loss increases with increased particle temperature or decreased particle velocity. Meanwhile, wüstite (FeO) formation, related to the oxygen loss, is more complicated, partly because oxygen, which is lost during flight in the high-temperature zone of the plasma jet, can be recovered at longer spray distances. As a result, the saturation magnetization of MZF coatings decreases and the coercivity increases with increased particle temperature or decreased particle velocity.     

Excitation of spontaneous vibrations in enclosed diffusion flames

The presence of Tollmien-Schlichting waves during the initial stages of the isothermal mixing of two axi-symmetical laminar streams of air has been confirmed by comparing data from hot wire measurements with published two-dimensional theoretical and experimental results for the stability of mixing and for transition in a boundary layer. Hot wire measurements in the flow field of steady or vibrating axi-symmetrical laminar diffusion flames are remarkably similar to those obtained during isothermal mixing. A travelling wave in the mean flow direction has also been established. Data for these flames agree with the results of a higher order stability analysis for natural convection flow past a vertical heated plate. It has been concluded that Tollmien-Schlichting waves are responsible for exciting flame vibrations.     

Ozone Contactor Hydrodynamics

Tracer tests were conducted at the 6,000 pounds of ozone per day Tucson, CAP Water Treatment Plant in Tucson, Arizona. The tests were designed to determine T₁₀ values through the contactors at various operating conditions. The tests were modeled using three techniques. Peclet Number was calculated for each of the runs, which would indicate the hydrodynamic conditions inside the ozone contactor. The results indicated that the increase in water flow rate and the number of cells with gas flow increased Peclet Number. The flow rate of liquid seemed to impact the Peclet Number more than gas flow. The headloss in each cell appeared to be important in controlling the distribution of liquid and gas through the cell. A correlation was developed between the product of gas and liquid phase Reynolds Number and Peclet Number.     

Integrated Study of APS YSZ Coatings with Different Spray Angle

Spray parameters play an important role on the microstructure and properties of plasma-sprayed coatings. Parameters such as spray distance, plasma gas flow and current, raster speed, and spray angle all can be varied. In this paper, an integrated study to investigate the effects and influences of spray angle on properties of yttria-stabilized zirconia coatings was carried out with spray angles of 60°, 75°, and 90° (to the substrate surface). In situ coating property sensor based on beam curvature measurements was used to measure the evolving stress and elastic moduli of the resultant coatings and combined with other characterization tools for thermo-physical property and microstructure analysis, such as laser flash and scanning electron microscopy. The results indicate that the coating with 60° spray angle had the lowest thermal conductivity and more compliant structure. This study seeks to understand the mechanism for this effect and will provide important insight into parametric sensitivities on complex spray parts.