Preparation Polyelectrolyte Complexes of Chitosan-Polyacrylic Acid-Modified Iron Sand Leachate for Proton Exchange Membranes

ABSTRACT

Polyelectrolyte complex (PEC) of chitosan (Chi) and poly (acrylic acid) (PAA)-modified iron sand leachate were prepared and considered for applicability as a proton exchange membrane in fuel cells. Chi-PAA-hematite blended in different weight ratios and the resulting membranes were treated to enable the formation of the polyelectrolyte. The membranes of Chi-PAA polyblend were treated using iron sand leachate and reveal high ion exchange capacity (IEC), proton conductivity, water uptake, and good mechanical stability. The result of research indicated that the membrane with 40 wt% of Chi and 60 wt% of PAA blend which its conductivity of 6.10 × 10^?2 S cm^?1 was potentially for a proton exchange membrane in fuel cell applications.     

Obesity: Prevalence,Theories, Medical Consequences,Management, and Research Directions

Obesity and its associated disorders are a growing epidemic across the world. Many genetic, physiological, and behavioral factors play a role in the etiology of obesity. Diet and exercise are known to play a valuable role in the treatment and prevention of obesity and associated disorders such as hypertension, heart disease, and diabetes. Therefore, the purpose of this review is to examine the prevalence, etiology, consequences, and treatment of obesity.     

“中四角”工业废水排放时空格局演变及其重心迁移研究

基于探索性空间分析(ESDA)方法和重心迁移模型研究2006-2017年"中四角"工业废水排放的时空格局演变及其重心迁移轨迹。研究结果表明:2006-2017年"中四角"工业废水排放整体呈下降趋势,并存在明显空间分异特征,呈西南从高到低、中东从低到高的演变规律;总体空间内无明显的空间集聚特征,但局部空间存在明显的集聚特征且以低高集聚状态为主;2006-2017年间"中四角"工业废水排放重心主要在东经114.38°E^114.95°E、北纬29.18°N^29.34°N区域内移动,总体向东北方向移动,移动总距离为107.88 km;"中四角"工业总产值重心总体向西北方向移动,移动总距离为94.39 km,除2011和2012年外其他年份的重心移动距离变化较小。2006-2017年间"中四角"工业总产值重心逐渐偏离几何中心,而工业废水排放重心逐渐向几何中心靠拢且移动速度明显高于工业总产值重心移动速度。     

一种能量均衡的无线传感器网络分簇算法*

为了延长网络的生存时间,提出了一种能量均衡的无线传感器网络分簇算法（EBCA）,该算法优先选择剩余能量较多的节点作为簇首,以平衡节点的能量消耗。仿真实验结果表明：无论同构网还是异构网,该算法都能显著地推迟网络第一个节点的死亡时间,其性能明显优于LEACH算法。     

Epoxidized soybean oil modified using fatty acids as tougheners for thermosetting epoxy resins: Part 2—Effect of curing agent and epoxy molecular weight

A series of bio-rubber (BR) tougheners for thermosetting epoxy resins was prepared by grafting renewable fatty acids with different chain lengths onto epoxidized soybean oil at varying molar ratios. BR-toughened samples were prepared by blending BRs with diglycidyl ether of bisphenol A resins, Epon 828 and Epon 1001F, at different weight fractions and stoichiometrically cured using an amine curing agent, 4, 4′-methylene biscyclohexanamine (PACM). Fracture toughness properties of the unmodified and BR toughened polymer samples—including critical strain energy release rate (G_Ic), and critical stress intensity factor (K_Ic)—were measured to investigate the toughening effect of prepared BRs. It was found that the degree of phase separation and toughening were more controllable relative to similar polymers cured using the aromatic curing agent Epikure W, and the use of higher molecular epoxy resins produces a synergistic effect increasing the toughness much more than similar polymers made with lower molecular weight epoxy resins. Average BR domain sizes ranging from 200 to 900 nm were observed, and formulations with G_Ic, values K_Ic as high as 1.0 kJ/m² and 1.4 MPa m^1/2 were attained respectively for epoxy systems with T_g greater than 130°C.     

Epoxidized soybean oil modified using fatty acids as tougheners for thermosetting epoxy resins: Part 1

A series of bio-rubber (BR) reactive tougheners for thermosetting epoxy resins was prepared by grafting renewable saturated fatty acids of different chain lengths (C6-C14) onto epoxidized soybean oil (ESO) at varying molar ratios. The tunable nature of the BR systems derives from the architecture and functionality of naturally occurring molecules. Control of BR reactivity and molecular weight by varying the degree of grafting and the chain length of the fatty acid was demonstrated. The BR-toughened samples were prepared by blending BRs with diglycidyl ether of bisphenol A (DGEBA), Epon 828, and stoichiometrically curing the mixture using an aromatic amine hardener, diethyl toluene diamine (Epikure W). Fracture surface morphology studies showed that tuning of phase separated particle sizes was possible depending on the BR type and weight fraction. The resulting toughening effect was evaluated by measuring the fracture toughness of control and toughened polymer samples. The use of BRs significantly improved the critical strain energy release rate and critical stress intensity factor values of thermosetting polymer samples without significantly reducing T_g and modulus. In addition to toughening and adding renewable content to petroleum-based thermosetting epoxy systems these new tougheners have low viscosity compared to common alternatives and aid ease of processing.     

小功率整体式电液伺服传动装置的动态性能分析

本文运用古典控制理论，对C335小功率整体式电液伺服传动装置进行了动态性能理论分析，并提出了改进系统动态性能的具体措施。     

一个高速开关阀控液压系统的模糊控制研究

本文设计了一个采用高速开关阀控制的液压缸位置控制系统，该系统便于和微机接口实现数字控制。本系统运用PWM技术和模糊控制技术，实现了系统的精确控制。仿真结果表明，该控制器具有快速响应性和好的稳定性。同时也表明了采用模糊控制方法可以有效的解决一类非线性系统的控制。     

江苏省南水北调受水区水资源配置

在对水资源系统进行模拟分析的基础上,结合江苏省南水北调受水区水文水资源、水利工程等特点,构建流域降雨径流模型、水动力学模型、水量调配模型以及水工程调度模型等子模型,对受水区水资源量、供需水量等进行研究。基于所建模型提出水利工程调度方案,对研究区水资源进行合理配置。分别模拟计算分析研究区内农业、工业、生活、生态和船闸用水户在现状与规划工情下不同水平年的供水、需水、缺水情况,制定水资源配置方案。通过现状与规划方案对比可知,南水北调一期工程建成后供水能力提高,缺水量显著降低。95%、75%和50%保证率下,缺水率分别降低10.3%、8.0%和5.2%。研究成果为南水北调东线水利工程调度提供科学依据,对跨流域调水工程的水资源配置与调度具有一定参考意义。