Simulation of molecular weight distribution and cyclic oligomer formation in the polymerization of nylon 6

The reversible polymerization of nylon 6 including ring opening, polycondensation, polyaddition, and cyclization reactions as well as the reaction with monofunctional acids was simulated for an isothermal batch reactor at 235°C. The cyclic oligomer concentrations, the molecular weight distributions, and its moments have been computed using a chain length-dependent equilibrium constant for the cyclization reaction. Even though the cyclization step does not influence the monomer conversion considerably, it does effect the molecular weight distribution and its moments.     

Process synchronization in high-level languages

This paper examines a concurrent process synchronization technique known as the conditional critical region method and suggests a simple improvement to it. This makes the method very attractive for inclusion in high-level programming languages allowing users to write parallel programs. Next, the paper describes an implementation of the technique and illustrates the use of the technique with the help of some well-known examples in parallel programming.     

Effect of postinduction nutrient feed composition and use of lactose as inducer during production of thermostable xylanase in Escherichia coli glucose-limited fed-batch cultivations

Escherichia coli is a microorganism routinely used in the production of heterologous proteins. The overexpression of a xylanase (Xyn 10 A Delta NC), which originated from the thermophile Rhodothermus marinus cloned under the control of the strong T7/lac promoter in a defined medium (mAT) using a substrate-limited feed strategy, was however shown to impose a significant metabolic burden on host cells. This resulted in a decreased cell growth rate and ultimately also a decreased target protein production. The investigation hence centers on the effect of some selected nutrient feed additives (amino acid [Cys] or TCA-intermediates [citrate, succinate, malate]) used to relieve the metabolic burden imposed during the feeding and postinduction phases of these glucose-limited fed-batch cultivations. The use of either succinic acid or malic acid as feed-additives resulted in an increase in production of approximately 40% of the heterologous thermostable xylanase. Furthermore, use of lactose as an alternative inducer of the T7/lac promoter was also proven to be a suitable strategy that significantly prolonged the heterologous protein production phase as compared with induction using isopropyl beta-D-thiogalactopyranoside (IPTG).     

A coupled photocatalytic-biological process for degradation of 1-amino-8-naphthol-3, 6-disulfonic acid (H-acid)

 There has been growing emphasis on the development of coupled treatment systems (e.g., advanced oxidation–biological) for treating poorly biodegradable wastewater. An attempt has been made in the present study to couple photocatalytic (TiO₂/UV) pretreatment with conventional activated sludge process to achieve improvement in the biodegradation of H-acid. The combination of titanium dioxide and UV light has been known to generate strong oxidants that degrade several organic pollutants into carbon dioxide via the formation of some intermediates. The intermediates formed may undergo biodegradation readily. Accordingly, photodegradation experiments were carried out initially at an optimized TiO₂ dose and the minimum pretreatment time required for transforming H-acid was identified. For this purpose, UV–vis spectrophotometry and high-performance liquid chromatography (HPLC) were extensively used. Subsequently, it was attempted to biodegrade untreated and pretreated H-acid using activated sludge from the textile industry acclimatized to H-acid. It was found that photocatalytic pretreatment of H-acid for 30 min, during which period approximately 8–10% chemical oxygen demand (COD) removal occurred, can be coupled to second-stage biological treatment for achieving enhanced biodegradation of H-acid.     

Simulation of reversible nylon-66 polymerization in homogeneous continuous-flow stirred tank reactors

Experimental data of Ogata¹ has been curve-fitted to obtain the forward and reverse rate constants for nylon-66 polymerization. Its molecular weight distribution (MWD) has been simulated in homogeneous continuous-flow stirred tank reactors (HCSTR) for 11 h of residence time when the reaction mass is very close to equilibrium. The set of algebraic equations have been solved using Brown's algorithm,² which was found to be more efficient compared to the Gauss-Jordon techniques of solution. The MWD thus obtained is compared with our earlier simulation of the molecular weight distribution from batch reactors³ and was found to differ significantly. In HCSTR, the weight fraction distribution does not undergo a maximum and the polydispersity index ρ of the polymer formed is much higher than that obtained from batch reactors. The number and weight average of the polymer formed in HCSTR is found to be significantly lower.     

Use of the least squares criterion in the finite element formulation

This paper presents a new method of formulating the finite element relationships based on the least squares criterion. To overcome the high degree of inter-element continuity, a method of reducing the original governing differential equation to a set of equivalent system of first-order differential equations is proposed. The validity of the method is demonstrated by means of several numerical examples. In particular, application of the method to problems with unknown variational functionals is considered.     

Viscosity-molecular weight concentration relationships beyond the critical region in polymer solutions and melts

A multivariate regression analysis of viscosity-molecular weight-concentration data is presented which is superior to the methods currently used. Four sets of data from the literature are analysed to show the efficacy of the method.     

Surface separation and contact resistance considering sinusoidal elastic–plastic multi-scale rough surface contact

The current work considers the multi-scale nature of surface roughness in a new model that predicts the real area of contact and surface separation as functions of load. This work is based upon a previous rough surface multi-scale contact model which used stacked elastic–plastic spheres to model the multiple scales of roughness. Instead, this work uses stacked 3D sinusoids to represent the asperities in contact at each scale of the surface. By summing the distance between the two surfaces at all scales, a model of surface separation as a function of dimensionless load is obtained. Since the model makes predictions for the real area of contact, it is also able to make predictions for thermal and electrical contact resistance. In accordance with concerns in previous works that the iterative calculation of the real contact area in multi-scale methods does not converge, this work not only tests but also gives conditions required for convergence in these techniques. The results are also compared to other existing rough surface contact models.     

蓝青蛙酒廊与录音棚

Serie建筑师事务所是一个国际化事务所,涉及的领域包括建筑、城市的设计。事务所关注于当代城市中建筑类型的进化和变异以及这些智慧形式在空间解决方案上的应用。类型学式的研究,或者用他们的名词,“连续”（SERIES）的思考和探索（利用建筑类型的累积智慧）是Serie作品的关键。     

An extension to the ordered subcarrier selection algorithm (OSSA)

In this letter, we propose an extension to the ordered subcarrier selection algorithm (OSSA) for orthogonal frequency division multiplexing (OFDM) systems. The result is a simple algorithm for minimizing the bit error rate of the OFDM system at a fixed throughput. The proposed algorithm employs multiple modulations (non-uniform bit loading) within an OFDM symbol. However, unlike existing bit loading algorithms that have a very high computational complexity, the proposed algorithm is based only on the ordered statistics of the subcarrier gains and is consequently very simple. After ordering the subcarriers based on their gains, progressively higher order modulations are used with increasing gains. The key aspect here that greatly simplifies the algorithm is that the modulation used on a subcarrier depends only on the position of its gain in the ordered set and not on the actual values of the gains. We show an analytical approach for determining the parameters of the algorithm.