全文获取类型
收费全文 | 2652篇 |
免费 | 103篇 |
国内免费 | 10篇 |
专业分类
电工技术 | 140篇 |
综合类 | 3篇 |
化学工业 | 771篇 |
金属工艺 | 57篇 |
机械仪表 | 82篇 |
建筑科学 | 76篇 |
能源动力 | 116篇 |
轻工业 | 319篇 |
水利工程 | 12篇 |
石油天然气 | 1篇 |
无线电 | 130篇 |
一般工业技术 | 538篇 |
冶金工业 | 125篇 |
原子能技术 | 119篇 |
自动化技术 | 276篇 |
出版年
2023年 | 24篇 |
2022年 | 44篇 |
2021年 | 81篇 |
2020年 | 25篇 |
2019年 | 37篇 |
2018年 | 85篇 |
2017年 | 54篇 |
2016年 | 106篇 |
2015年 | 52篇 |
2014年 | 100篇 |
2013年 | 180篇 |
2012年 | 161篇 |
2011年 | 194篇 |
2010年 | 139篇 |
2009年 | 160篇 |
2008年 | 178篇 |
2007年 | 124篇 |
2006年 | 105篇 |
2005年 | 101篇 |
2004年 | 86篇 |
2003年 | 76篇 |
2002年 | 84篇 |
2001年 | 53篇 |
2000年 | 34篇 |
1999年 | 50篇 |
1998年 | 68篇 |
1997年 | 47篇 |
1996年 | 42篇 |
1995年 | 23篇 |
1994年 | 36篇 |
1993年 | 26篇 |
1992年 | 12篇 |
1991年 | 12篇 |
1990年 | 9篇 |
1989年 | 16篇 |
1988年 | 10篇 |
1987年 | 13篇 |
1986年 | 16篇 |
1985年 | 18篇 |
1984年 | 9篇 |
1983年 | 15篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1978年 | 8篇 |
1977年 | 10篇 |
1976年 | 8篇 |
1975年 | 3篇 |
1973年 | 2篇 |
排序方式: 共有2765条查询结果,搜索用时 0 毫秒
91.
92.
Satoshi Semboshi Shigeo Sato Mikio Ishikuro Kazuaki Wagatsuma Akihiro Iwase Takayuki Takasugi 《Metallurgical and Materials Transactions A》2014,45(8):3401-3411
We investigated the precipitation processes in Cu-4 mol pct Ti alloy specimens aged at 723 K (450 °C), by means of X-ray diffraction and chemical analyses of the precipitates extracted from the parent alloy specimens. Aging-induced precipitate particles of a spinodally decomposed disorder, α′; those of a metastable order, β′-Cu4Ti; and those of a stable order, β-Cu4Ti, were continuously formed in the aged specimens. The extraction of the precipitate particles from the aged specimens by submergence in a nitric solution allowed for not only the structural analyses of the constituent precipitate phases but also the quantitative evaluation of their chemical compositions and volume fractions. Early during the aging process, the supersaturated Cu solid solution decomposes spinodally in a continuous manner, and an unstable disorder, α′, appears. Then, fine needle-shaped β′-Cu4Ti particles, which have a Ti content of approximately 37.5 mol pct, form in the Cu matrix. During prolonged aging, coarse cellular components composed of the terminal Cu solid solution and stable β-Cu4Ti particles which have a Ti content of 20.5 mol pct nucleate and grow, primarily in the grain boundaries, at the expense of the metastable β′-Cu4Ti particles. The volume fraction of the β′-Cu4Ti particles in the alloy reaches a maximum of approximately 1.7 pct after aging for 24 hours, while that of the β-Cu4Ti particles increases steadily to more than 18 pct after 480 hours. The volume fraction of the fine β′-Cu4Ti particles in the alloy specimens remained constant throughout the age-hardening, indicating that the hardening is primarily owing to the fine dispersion of the β′-Cu4Ti particles and not because of the large volume fraction of coarse β-Cu4Ti particles. 相似文献
93.
In this study, we validated the usefulness of examiners’ forward citations, especially from the viewpoint of the applicants’ self-selection (ASS) decisions during the patent application procedure. We believe that the ASS in an early stage would be decided by a potential-value comparison among patent applications. We focused on six self-selection decision points of the applicants: whether to file patent applications in foreign countries, request for examination, request for accelerated examination, reply to a notification of reasons for refusal, appeal after receiving a decision of refusal, and register after receiving a decision to grant a patent as patent value parameters. We found that application groups that selected “Yes” have a significantly larger number of examiners’ forward citations than groups that selected “No” at all decision points. In addition, we confirmed that applications that were finally granted and those that were renewed for a full term after grant have a significantly large number of examiners’ forward citations. We concluded that the number of examiners’ forward citations would be a useful indicator of the potential value of patent applications in macroscopic analysis. 相似文献
94.
Naohiro Gotoh Shino Miyake Hiroko Takei Kumi Sasaki Saori Okuda Michitaka Ishinaga Shun Wada 《Food Analytical Methods》2011,4(4):525-530
We developed a simple method for quantification of the peroxide value (PV) in colored lipids on the basis of the reaction
between triphenylphosphine (TPP) and oxidized oil to afford triphenylphosphineoxide (TPPO). Diphenylphosphineoxide (DPPO)
was employed as internal standard. The formed TPPO was analyzed by high-pressure liquid chromatography–UV spectroscopy with
absorption at 260 nm. The conditions that gave the highest correlative calibration curve between the peak area on the chromatogram
and peroxide value were identified: the optimum TPP–oxidized oil mix ratio, reaction temperature, and reaction time were found
to be 2:1, 40 °C, and 30 min, respectively. Linear calibration curves, passing through the origin, were obtained for PV versus
TPPO and TPPO versus DPPO. The quantification limit for this method was 2.01 pmol hydroperoxyl group, which corresponds to
a PV value of 0.2 meq/kg in a 10-mg oil sample. This method was used to measure the PV in colored fats and oils or lipids
extracted from dark meat and processed food containing a coloring agent. Though the official method could not measure the
PVs in the colored lipids, the method proposed here, which uses an inexpensive chemical reagent and machine, could. The developed
method could play an important role for food quality control. 相似文献
95.
We evaluated the effects of seven mushroom extracts (Grifola frondosa, Pholiota nameko, Panellus serotinus, Hypsizygus marmoreus, Pleurotus cornucopiae, Armillaria mellea, and Flammulina velutipes) on cytotoxic activity and cytokine production of lamina propria leukocytes (LPLs) isolated from rat small (S) and large (L) intestinal mucosa. Boiling water extracts from seven species of mushrooms showed no direct cytotoxicity against the YAC-1 target cells. However, prominent increases of cytotoxicity were observed in S- and L-LPLs co-cultured with P. serotinus extract. Cytokine production (TNFα, IFNγ, IL-12 p70, and IL-4) of S- and L-LPLs was stimulated in response to P. cornucopiae extract. Mushroom extracts contributed to target cell adhesion and/or cytokine production in the effector cells. The promotion of cytotoxic activity in S- and L-LPLs was not necessarily related to β-glucan content of the mushroom. 相似文献
96.
Effects of extrusion ratio (ER) during extruding on mechanical properties of poly(lactic acid) (PLA) screws were investigated in terms of shear and twist strength. Shear strength increased by drawing, while twist strength decreased. This might be due to orientation of molecular chains during drawing. In order to evaluate orientation of molecular chains, orientation function in extruded billets was measured as a function of ER. Since orientation function increased with ER, drawing is effective method to improve shear strength of screw, where fibrous structure which was formed during extruding resisted shear stress in cross-section perpendicular to screw axis. Although orientation functions for billet extruded at ER 1.3–4 were equivalent, both strengths changed for the screw extruded at the range of this ER. Infrared spectra suggested transforming from α to β crystal for the billet extruded at the range of this ER. This result suggested that mechanical properties of screw also depended on the crystal forms. 相似文献
97.
98.
99.
Satoshi?KameokaEmail author Satoru?Wakabayashi Eiji?Abe An?Pang?Tsai 《Catalysis Letters》2016,146(7):1309-1316
100.
The Role of a Nonribosomal Peptide Synthetase in l‐Lysine Lactamization During Capuramycin Biosynthesis 下载免费PDF全文
Dr. Xiaodong Liu Yuanyuan Jin Zheng Cui Dr. Koichi Nonaka Satoshi Baba Dr. Masanori Funabashi Dr. Zhaoyong Yang Dr. Steven G. Van Lanen 《Chembiochem : a European journal of chemical biology》2016,17(9):804-810
Capuramycins are one of several known classes of natural products that contain an l ‐Lys‐derived l ‐α‐amino‐?‐caprolactam (l ‐ACL) unit. The α‐amino group of l ‐ACL in a capuramycin is linked to an unsaturated hexuronic acid component through an amide bond that was previously shown to originate by an ATP‐independent enzymatic route. With the aid of a combined in vivo and in vitro approach, a predicted tridomain nonribosomal peptide synthetase CapU is functionally characterized here as the ATP‐dependent amide‐bond‐forming catalyst responsible for the biosynthesis of the remaining amide bond present in l ‐ACL. The results are consistent with the adenylation domain of CapU as the essential catalytic component for l ‐Lys activation and thioesterification of the adjacent thiolation domain. However, in contrast to expectations, lactamization does not require any additional domains or proteins and is likely a nonenzymatic event. The results set the stage for examining whether a similar NRPS‐mediated mechanism is employed in the biosynthesis of other l ‐ACL‐containing natural products and, just as intriguingly, how spontaneous lactamization is avoided in the numerous NRPS‐derived peptides that contain an unmodified l ‐Lys residue. 相似文献